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NORTH-WEST UNIVERSITY-
YUNIBESITI YA BOKONE-BOPHIRIMA
NOORDWES-UNIVERSITEIT
POTCHEFSTROIMKAMPUS

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Tipe Assessering/ Eksamen 1e geleentheid Kwalifikasie/ BSc
Type of Assessment: Exam 1st opportunity Qualification:
Vraestei/Paper 1
Mod1:1lekode/ CHEM 311 Tydsduur/ 3 uur/ure
Module code: Duration: hour(s)
Module beskrywing/ Analitiese Chemie -Ul Maks/ 100
Module description: Analytical Chemistry-Ill Max:
Eksaminator(e)/ DR JHLJORDAAN Datum/ 0-2/06l201S
Examiner(s): Date:
ME.AFALCH Tyd/ 09:00
Time:
Moderator(s): PROF HCM VOSLOO

Naam van ·student: Universiteitsnommer: .............................. .

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11. All examination answers must be written in black or f1i1.

CHEM 311 1/22

 Vraag 1 Question 1
Gee die faktore wat die keuse van oplosmiddel Give the factors that can influence the choice of
vir UV-analises kan bei"nvloed. solvent for UV analyses. [5]

Vraag 2 Question 2
Neem die beperkings van Beer se Wet vir UV- Name the limitations of Beer's Law for UV-
spektrometrie. spectrometry.. [2]

712
CHEM 311 2/22
 Vraag 3 Question 3

'n 6.23 dpm KMn04-oplossing het 'n UV A 6.23 ppm KMn0 4 solution has a UV
transmittansie van 0.195 in 'n 1.00 em sel by transmittance of 0.195 in a 1.00 em cell at
520- nm. Bereken die mo!E~re absorbeervermoe 520 nm. CalCulate the molar absorbtivity of
van KMn04. KMn0 4. [3]

Vraag 4 Question4

Skets met byskrifte 'n dubbelstraal l:JV- Sketch with captions a double beam UV-
spektrofotometer. spectrophotometer. [5.]

713
CHEM 311 3/22
 Vraag 5 Question 5

Watter faktore sal die energie van 'n vibrasie- Which factors will influence the energy of a

koppeling in IR-spektrometrie be"invloed? vibration coupling in IR spectrometry? [6]

Vraag 6 · Question 6

Wat is die VO.O[dele van 'n FTIR-spektrometer What are the advantages of an FTIR
as dit met 'n. dispersiewe instrument vergelyk spectrometer if it is compared to a dispersive
word? instrument? [5] .

714
CHEM 311 4/22
 Vraag 7 Question 7

Bereken die kragkonstante vir 'n HCI-molekule Calculate the force constant for a HCI molecule
met 'n IR-absorpsieband by 2890 cm- 1. with an IR absorption band at 2890 cm-
1
. [4]

Vraag 8 ·QuestionS

Skets met byskrifte 'n elektronimpakbron van Sketch with captions a·n electron impact-source
'n massaspektrometer. of a mass spectrometer. [6]

715
CHEM 311 5/22
 Vraag 9 Question 9

10.1 Gee die verskil tussen 'n gasagtige- en 10. 1 Give the difference between a gaseous
desorpsie-ionisasie MS-bron. and desorption ionization MS source. [2]
10.2 Wat-is-die voordele van elk? 10.2 What are the advantages of e-ach? [2]

Vraag 10 · Question 10

Bereken die versne!!ings spanning wat nodig Calculate the acceleration voltage that-is-required
sal wees om 'n enkelgelaaide wate!molekuul to-dir-ect a .singly charged water molecule through
deur die uitlaatspleet van 'n MS te laat beweeg, the exit. slit of a MS. if the magnet has a field
indien die magneet 'n veld van 0.240 T en 'n strength of 0. 240 T and a radius of _curvature of
buigingsradius van 12.7 em het. 12.7 em. [3]

716
CHEM 311 6/22
 Vraag 11 Question 11

In watter 8-waardegebied sal u verwag om die In which 8-value region will you expect to observe
KMR-resonanssein van 'n aldehiedproton waar the NMR resonance signal of an aldehyde proton?
te neem? Verduidelik u antwoord. Explain your answer. -[4]

Vraag 12 Question 12

Verduidelik wat u onder die term sluiting van Explain what you understand under the term
die magneetveld van 'n KMR verstaan. locking of the magnetic field of a NMR. [4]

717
CHEM 311 7/22
 Vraag 13 Question 13

Wat is die voor en nade/e van 'n FT-KMR ten ,What are advantages and disadvantages of an
opsigte van 'n CW-KMR? FT-NMR with regards to a CW-NMR? [5]

Vraag 14 Question 14

Hoe sal u te werk gaan om 'n KMR-buis skoon How will you go about cleaning a NMR tube?
te maak? [3]

718
CHEM 311 8/22
 Vraag 15 Question 15

Lei die struktuur van die verbinding met Deduce the structure of the compound with
molekulere formule C4 H80 2 van die gegewe molecular formula C4H8 0 2 from the given spectra.
spektra af. Toon aile afleidings en toekennings Show all deductions and assignments that you
wat u maak. make. [11]

719
CHEM 311 9/22
 Vraag 16 Question 16

Verduidelik die werking van 'n tipiese UV Z- Explain the operation of a typical UV Z-shape
vormige deurvloeisel wat as detektor vir 'n flow-through cell which is used as a detector in a
HPLC-instrument gebruik word. (Toon. aile HPLC instrument. (Show all drawings.) [8]
sketse.)

720
CHEM 311 11/22
 Vraag 17 Question 17

Definieer die volgende chromatgrafiese Define the following chromatographic terms:

terme: [4]
19.1 lsokratiese eluerirrg 19.1 /socratic elution

19.2 Gradienteluering 19.2 -GrarHent elution

19.3 Omgekeerdefase pakking 19.3 ReveFsed-phasapacking

19.4 Growwe-eienskapdetektor 19.4 Bulk property detector

Vraag 18 Question 18

Beskryf die werking van 'n HPLC- Describe the ~orking of a HPLC displacement pump.
. ' [5]
verplasingspomp.

721
CHEM 311 12/22
 Vraag 19 Question 19

Skets met byskrifte 'n hittevloed DSC Sketch with captions a heat-flux DSC
instrument. [5]
instrument.

Vraag 20 Question 20

Verduidelik hoe u· te werk sal gaan om 'n Explain how you will go about calibrating a DSC
instrument. [8]
DSC-instrument te kalibreer.

722
CHEM 311 13/22