1. Which of the following is not a basic thermodynamic equation?

(a) dU = – P dV + T dS
(b) dA = -S dT + P dV
(c) dH = T dS + V dP
(d) dG = - S dT + V dP

2. In a thermodynamic process PV is work done. The correct interpretation for it is

(a) It has two component PdV (mechanical work) and VdP nonmechanical work
(b) VdP is related to chemical reactions and phase transformation
(c) Gibbs work function at constant P and Temperature accounts only VdP
nonmechanical work
(d) All of the statement
 3. The free energy change for water vaporizing at 373 K and 1 atm. pressure is

(a) positive
(b) zero
(c) negative
(d) unpredictable

4. The correct statement about chemical potential (µ) is

(a) Material flow from higher potential to low

(b) Plot of µ vs temperature at constant P is strait line with negative slope
(Sm)
(c) Plot of µ vs P at constant T is strait line with positive slope (Vm)
(d) All
5. For the reaction

Change in enthalpy is-100kJ/mol at300K. The change in internal energy is

(a) -100 kJ/mol

(b) -95.01 kJ/mol
(c) 0kJ/mol
(d)-104.9 kJ/mol

6. 10 mole of an ideal gas expand from 1l to 2l at 27 ºC. Calculate heat change.

(a) 17.29kJ
(b) 57.6J
(c) 0
(d) Insufficient information
7. What should be the entropy change in melting 5 g of ice at 0oC (ΔH =
1440 Cal)

(a) 2.032 Cal K-1

(b) 1.468 Cal K-1
(c) 1.568 Cal K-1
(d) 1.514 Cal K-1

8. Two moles of a perfect gas expanded from a pressure of 20 nm-2 to 1

nm-2 at 300 K. The free energy change of this expansion is

(a) -1.31×104 J
(b) 1.60 ×104 J
(c) 1.59 ×104 J
(d) -1.49 ×104 J
9. A thermodynamic equation that relates the chemical potential to the
composition of a mixture is known as

(a) Gibbs-Helmholtz equation

(b) Gibbs-Duhem equation
(c) Clapeyron Clausius equation
(d) Van’t Hoff Isotherm equation

10. If ΔG° is zero for a reaction, then

(a) ΔH =0
(b) ΔS = 0
(c) K (equilibrium constant) = 0
(d) K=1
1. (b) 2. (d) 3. (b) 4. (d) 5. (b) 6. (a) 7. (b) 8. (d) 9. (b)

10. (d)