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Module 6
Module 6
General Chemistry 2
Quarter 1: Week 6 - Module 6
Thermodynamics
STEM – General Chemistry 2
Grade 11/12 Quarter 3: Week 6 - Module 6: Thermodynamics
First Edition, 2021
Copyright © 2021
La Union Schools Division
Region I
All rights reserved. No part of this module may be reproduced in any form
without written permission from the copyright owners.
Management Team:
Energy exists in many forms, such as heat, light, chemical energy, and
electrical energy. Energy is the ability to bring about change or to do work.
Thermodynamics is the study of energy. Energy exist in nature in many forms,
such as heat, chemical energy, electrical energy, light and this energy brings us the
ability to do work. What does it mean by learning thermodynamics? Yes! We are
learning energy itself. Wondered why heat travels from hotter region to colder
region and not the other way around? Why do the foods we eat gives us energy that
later we can use to do work? As you learn along this module, you will be answering
these questions that is why you must have that high amount to energy to beat the
heat!
In the past lessons you learned how solutions exhibit properties that
depends on the concentration of solute molecules or ions known as Colligative
property. You have learned that Colligative properties include vapor pressure
lowering, boiling point elevation, freezing point depression, and osmotic pressure.
This learning material will provide you with information and activities that
will help you understand procedures in titration, the anchored law in reactions, the
enthalpy and the first law of thermodynamics.
After going through this learning material, you are expected to:
Jumpstart
2. When performing acid-base titration, at what point does the reaction stops?
A. Analyte B. Equivalence C. End D. Titrant
5. Before using the glass equipment in the laboratory, what specific water is
used to clean them?
A. Clean B. Distilled C. Mineral D. Tap
9. What happens to the internal energy of a system if both heat and work have
a sign of negative?
A. Decreases B. Increases C. no effect D. stay the same
10. If the direction of work is “into the system”, what will be the sign for its
internal energy?
A. negative B. positive C. undefined D. zero
11. Who is the scientist that is named after a law in determining indirectly the
enthalpy of substances?
A. Dalton B. Hess C. Rutherford D. Seyhan
12. What happens to the enthalpy of the individual reaction using Hess’ Law if
you reverse the reactants and products?
A. Decrease B. Increase C. Reversed D. The same
13. How are the parts or chemical equations described by the Hess Law in
obtaining the enthalpy?
A. Difference B. Product C. Quotient D. Sum
14. How are you going to describe the movement of heat in an endothermic
reaction?
A. Absorption B. Decrease C. Increase D. Release
Let’s take for example this Laboratory Activity: (YOU DON’T NEED TO PERFORM
THIS EXPERIMENT)
Objectives:
Materials:
• Iron stand
• 10 mL pipette
• Burette clamp
• Base burette
• Aspirator
• One (25 mL or 50 mL) graduated cylinder
• One (50 mL) beaker
• Three (250 mL) Erlenmeyer Flasks or beakers
• Medicine dropper for the indicator
• Phenolphthalein indicator
• 250 mL distilled water
• 50 mL hydrochloric acid (to be obtained from the teacher)
• 50 mL of 0.1 M or mol/L sodium hydroxide in a clean, dry labeled glass
container (to be prepared and standardized by the teacher)
Procedure:
1. Wash the glasswares (Erlenmeyer flasks, beakers, pipette) with dishwashing
liquid. Rinse these thoroughly with tap water, and finally with
distilled water.
2. Invert the glasswares to drain the distilled water. Leave these inverted until use.
Preparing the Burette for Titration
Hint: Close and open the pinchcock alternately to remove air spaces. A
continuously smooth flow of the liquid out of the burette means there is no more
air space.
f. If there is more air space, fill the burette with NaOH standard solution up
to the 50 mL-mark. Make sure that the lower meniscus is at the 50 mL mark
of the burette.
4. Do two to three trials of the titration, Fill the table below with your
results:
Alternatively, we do not need to perform ourselves with the chemicals in the
laboratory, however similar experiments are available online and, in that case,
provided in the following links.
https://www.youtube.com/watch?v=sFpFCPTDv2w
https://www.youtube.com/watch?v=2z4mlE6MK0U
Questions:
1. What are the notable laboratory procedures that is shown in the experiment
or (video)? (YOU CAN USE SEPARATE PAPER)
___________________________________________________________________________
_________________________________________________________________________________.
2. What are the reactants of the reaction (experiment/video)? _________________
3. What are the products of the reaction (experiment/video)? __________________
4. Describe what would have happened in one of your titrations if you had
forgotten to add phenolphthalein to the sample flask.
ΔE = q + w
This law says that there are two kinds of processes, heat and work, that can
lead to a change in the internal energy of a system. Since both heat and work can
be measured and quantified, this is the same as saying that any change in the
energy of a system must result in a corresponding change in the energy of the
surroundings outside the system. In other words, energy cannot be created or
destroyed.
As the equation says, we have two kinds of processes, heat and work, that
defines the change in the internal energy of the system. Since both heat and work
can be measured and quantified, it is similar in saying that change in the (E)
energy of the system must result in a change in the energy of the surroundings. If
the heat flows into a system or the surroundings do work on it (on the system),
internal energy increases and the values of q and w are positive. On the other
hand, heat flow out of the system or work done by the system (on the
surroundings), the internal energy decreases because q and w are both negative.
HEAT is added to the system → → HEAT is released by the system
(+q) SYSTEM (-q)
WORK is done on the system → → WORK done by the system
(+w) (-w)
SURROUNDINGS
Sample Problem: Calculate ΔE if 100 kJ of heat energy is absorbed by the
system and 30 kJ of work is done on the surroundings.
Solution: The addition of heat increases the energy of the system by 100 kJ
but doing work decreases the energy of the system by 30 kJ.
Strategy: ΔE = q + w
= 100 kJ + (-30 kJ)
= 70 kJ
Enthalpy of Chemical Reactions
The term enthalpy originates from the Greek word enthalpein that means “to
warm”. Enthalpy is the energy transferred under constant pressure, represented by
the symbol H. Also, it is known as the heat content. Just like (E) internal energy, H
is also a state function which is defined by the change from the final to the initial
state.
ΔH = Hfinal -Hinitial
Enthalpy change, is called heat of reaction which is based on the net energy
change from the breaking and making of bonds. It represents heat absorbed or
released when the reactants are converted intro products, at a constant pressure.
ΔH = Hproducts -Hreactants
ΔH = q (at a constant pressure)
The enthalpy of chemical reactions is composed of the reactants and
products and their corresponding bond energies, the amount of energy to break the
bonds or released in forming the bonds. The sign of ΔH determines the direction of
heat transfer. A positive ΔH means an absorption of heat from the surroundings,
also known as endothermic reaction. A negative value of ΔH indicates an
exothermic reaction, a heat releasing process.
Example: What is the heat of reaction of Carbon Monoxide if the following reaction
are used?
Sample problem: Calculate the standard enthalpy of formation, ΔH° for methane
gas, CH4, produced from graphite and hydrogen gas according to the following
reaction:
C (graphite) + 2H2 (g) → CH4 (g)
Since this reaction that forms methane does not happens as written, ΔH° of
methane is determined indirectly using the following set of reactions whose ΔH°
have been accurately determined and applying Hess Law.
Strategy: In applying Hess Law, equations can be rearranged so that the desired
reactants and products will appear in the overall reaction. If the equation is
reversed, the sign of ΔH° is also reversed. If the equations are multiplied by a factor
to obtain the desired coefficients, the ΔH° values must also be multiplied by the
same number.
Solution:
C(graphite) + O2 (g) → CO2 (g) ΔH° = -393.5 kJ
H2 (g) + ½ O2 (g) → H2O (l) ΔH° = -285.8 kJ
CH4 (g) + 2 O2 (g) → CO2 (g) + 2H2O (l) ΔH° = -890.4 kJ
C (graphite) + 2H2 (g) → CH4 (g) ΔH° = ?
Write the equation as is.
Explore
________8. An exothermic reaction feels cold to the touch because heat is absorbed
by the system.
________9. When the heat energy of product is greater than its reactant, it is
categorized by an endothermic reaction.
________10. Thermochemical equation shows the enthalpy relationships between
reactants and products.
Reactions:
NO(g) + O3 (g) → NO2 (g) + O2 (g) ΔH° = -198.9 kJ
O3 (g) → 3/2 O2 (g) ΔH° = -142.3 kJ
O2 (g) → 2O (g) ΔH° = 495.0 kJ
NO (g) + O (g) → NO2 (g) ΔH° = ?
Deepen
Using the given table below, formulate your own kind of problem; through
providing hypothetical value for individual reactions, and also provide answer using
the steps in getting the ΔH° of the reaction. ONLY condition is the reaction must be
exothermic.
The scoring rubric below will be used in assessing your output. Use a
separate sheet to write your answer.
ClF3(g) + O2 (g) → ½ Cl2O (g) + 3/2OF2 (g) ΔH° =
2ClF(g) + O2 (g) → Cl2O (g) + OF2 (g) ΔH° =
2OF2 (g) → O2 (g) + 2F2 (g) ΔH° =
ClF (g) + F2 (g) → ClF3 (g) ΔH° = ?
Scoring Rubric
Direction: Choose the best answer. Use a separate sheet for your answers.
1. The concentration of the unknown substance in titration is determined by
what measure?
A. molality B. molarity C. ppm D. ppb
4. What is being avoided in cleaning the laboratory tools and equipment before
using?
A. contamination B. errors C. fire D. viruses
5. A burette is used to dispense unknown liquid into the flask. What part of the
burette is responsible in stopping the flow of liquid in it?
A. funnel B. pinchcock C. nozzle D. opening
6. For any chemical reaction carried out in any manner, the quantity of heat
absorbed or evolved by the reaction is determined by the expression
_________.
A. ΔE + w B. ΔE - w C. q D. w
7. What is the internal energy of the system that absorbs 50 J of heat and 15 J
work done by the system?
A. +40 J B. -40 J C. +35 J D. -35 J
8. Calculate the internal energy of the system that absorbs 50 kJ of heat and
65 kJ work done by the system.
A. + 15 J B. -15 kJ C. +20 kJ D. -20 kJ
10. When the heat is released by the system, what will be the value of ΔH?
A. >0 B. <0 C. =0 D. undefined
11. In enthalpy change, which process has met this condition: H products <
Hreactants?
A. endothermic B. exothermic C. heat content D. 4
12. What law is used in calculating the heat of reaction indirectly, via several
steps but with the resulting net reaction being the desired chemical
reaction?
A. Hess’ Law B. Dalton’s Law C. Charles’ Law D. Ideal Gas
For items 13-15, refer to this problem: What is the heat of reaction of Carbon
monoxide if the following reaction are used?
Fe(s) + ½ O2 (g) → FeO (s) ΔH = -272.0 kJ
2 Fe (s) + 3/2 O2 (g) → Fe2O3 (g) ΔH = -825.5 kJ
FeO (s) + ½ O2 (g) → Fe2O3 (g) ΔH = ?
13. What is the value of equation 1 ΔH if two (2) is multiplied in this reversed
equation, FeO (s) → Fe(s) + ½ O2 (g)
A. -272.0 kJ B. +272.0 kJ C. -544 kJ D. +544 kJ
A. FeO B. O2 C. Fe D. Fe2O3
15. What will be the final ΔH of the equation: FeO (s) + ½ O2 (g) → Fe2O3 (g)?
A. -280.5 kJ B. +280.5 kJ C. -281.5 kJ D. +281.5 kJ
Jumptart Gauge
1. D 1. B
2. B 2. D
3. C 3. C
4. A 4. A
5. B 5. B
6. B 6. B
7. C 7. C
8. B 8. B
9. A 9. C
10.B 10.B
11.B 11.B
12.C 12.A
13.D 13.D
14.A 14.C
15.D 15.C
Explore
Enrichment 2
Enrichment 1
NO(g) + O3 (g) → NO2 (g) + O2 (g) ΔH° = -198.9 kJ
1. F O3 (g) → 3/2 O2 (g) ΔH° = -142.3 kJ
2. B O2 (g) → 2O (g) ΔH° = +495.0 kJ
3. B NO (g) + O (g) → NO2 (g) ΔH° = ?
4. F
5. F NO(g) + O3 (g) → NO2 (g) + O2 (g) ΔH° = -198.9 kJ
6. B 3/2 O2 (g) + → O3 (g) ΔH° = +142.3 kJ
7. F ½ ( 2O (g) → O2 (g)) ½ (ΔH° = -495.0 kJ)
8. B
9. F
10.F NO(g) + O3 (g) → NO2 (g) + O2 (g) ΔH° = -198.9 kJ
3/2 O2 (g) + → O3 (g) ΔH° = +142.3 kJ
O (g) → ½ O2 (g) ΔH° = -247.5 kJ
NO (g)
+ O (g) → NO2 (g) ΔH° = -304.1 kJ
Answer Key
References:
Books:
Teaching Guide for Senior High School. General Chemistry 2 Acid-Base Titration.
Ilao, Luciana V., Betty M. Lontoc, Edwehna Elinore S. Paderna-Gayon. General
Chemistry 2: The First Law of Thermodynamics. 1st ed. Manila. Rex Book
Store, Inc. 2016.
Ayson, Marissa F., Rebecca S. De Borja. General Chemistry 2 Textbook: First Law of
Thermodynamics. Quezon City. Vibal Group, Inc. 2016.
Ayson, Marissa F., Rebecca S. De Borja. General Chemistry 2 Textbook: Hess’s Law.
Quezon City. Vibal Group, Inc. 2016.
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