G H RAISONI PUBLIC SCHOOL

WORKSHEET NO.1
Class- XII Subject –Chemistry(043)
Chapter: Solutions Month- July
1 When a non-volatile solid is added to pure water it will-
(a) boil above 100oC and freeze above 0oC.
( b) boil below 100oC and freeze above 0oC.
(c) boil above 100oC and freeze below 0oC.
(d) boil below 100oC and freeze below 0oC.
2 Among the following, which is an example of a solid solution?

(a) Copper dissolved in gold(b) Ethanol dissolved in acetone

(c) Glucose dissolved in water(d) Sodium chloride dissolved in water

3 Which lawexplained solubility of gases in liquid ?

Directions: in the following questions, a statement of Assertion (A) is followed by statement of

Reason(R) mark the correct choice as:
(A) Both (A) and (R) are true, and (R) is the correct explanation of (A).
(B) Both (A) and (R) are true, but (R) is not the correct explanation of (A).
(C) (A) is true, but (R) is false.
(D) A) is false, but (R) is true.

4 Assertion: 1 molal solution is more concentrated than 1 molar solution.

Reason: A molar solution contains one mol of solute in 1000ml of solution.

5 Assertion: Molarity and normality of a solution of monobasic acid is same.

Reason: Mole fraction of 0.5 M HNO3 is different from that of 0.5 N HNO3solution.
6 A solution is heated from 250C to 500C. Will its molarity be same, less or more?

7 Gas A is more soluble in water than gas B, at same temperature. Which one of the two will have
higher value of KH (Henry’s constant) and why?

8 Calculate the mole fraction of benzene in solution containing 30% by mass of it in carbon
tetrachloride.

9 State Henry's law and mention some important applications?

10 Calculate (a) molality, (b) molarity and (c) mole fraction of KI if the density of 20%
(mass/mass) aqueous KI is 1.202 gmL-1.

11 Determine the volume/volume percent solution made by combining 25 mL of ethanol with water
 to produce 200 mL of the solution.

12 What is an ideal solution? What types of solutions are likely to behave as ideal solution?

13 Addition of 1 mol of NaCl to 1 litre of water lowersthe boiling point of water whereas addition of
1 mol of methyl alcohol to 1 litre of water decreases itsboiling point. Explain.

14 Determine the molarity of each of the solutions given below:

(a) 30 g of Co(NO)3. 6H2O (molar mass is 291) in 4.3 L of solution

(b) 30 mL of 0.5 M H2SO4 diluted to 500 mL.

15 A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass.
Calculate the mass percentage of the resulting solution.

16 The vapour pressure of pure liquids A and B are 450 and 700 mm Hg, respectively, at 350 K.
Find out the composition of the liquid mixture if the total vapour pressure is 600 mm Hg. Also,
find the composition of the vapour phase.

17 How much of sucrose is to be added to 500 g of water such that it boils at 100°C if the molar
elevation constant for water is 0.52 K kg mol-1 and the boiling point of water at 750 mm Hg is
99.63°C?

0
18 To lower the melting point of 75 g of acetic acid by 1.5 C, how much mass of ascorbic acid is
needed to be dissolved in the solution where Kt = 3.9 K kg

19 If a solution is prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water
at 37°C, calculate the osmotic pressure in Pascal exerted by it.

–3
20 The partial pressure of ethane over a solution containing 6.56 × 10 g of ethane is 1 bar. If the
solution contains 5.00 × 10–2 g of ethane, then what shall be the partial pressure of the gas?