Formulation of concentrated oil-in-water-in-oil double emulsions

for fragrance encapsulation

Margot Stassea,b,c, Tiphaine Ribautc, Olivier Anthonyc Valérie Hérogueza*, Véronique

Schmittb*

a
Laboratoire de Chimie des Polymères Organiques, CNRS, UMR 5629, Bordeaux, 16 Avenue

Pey-Berland, F-33607 PESSAC, France

b
Centre de Recherché Paul Pascal, UMR 5031, University of Bordeaux, CNRS, 115 avenue du

Dr Albert Schweitzer, 33600 PESSAC, France

c
Takasago Europe Perfumery Laboratory 12 rue Torricelli 75017 PARIS FRANCE

Supporting informations

S1: Composition of a third fragrance to test the possibility of varying the fragrance without
modifying the rest of the double emulsion composition

Chemical name wt % LogP

1-(5,6,7,8-tetrahydronaphthalen-2-yl)ethanone 5 2.58

2-methyl decanal 2 4.324

3-methylbutyl butanoate 5 3.25

pentyl 2-hydroxybenzoate 5 4.56

2-methyl-3-(4-propan-2-ylphenyl)propanal 10 3.428

phenoxybenzene 10 4.21

ethyl 2-methylbutanoate 2 2.158

ethyl 2-methylpentanoate 5 2.667

hexyl acetate 5 2.87

2-ethoxynaphthalene 15 3.864
 (2-tert-butylcyclohexyl) acetate 26 4.059

2-methoxynaphthalene 10 3.47

S2:

a b

Figure S2: Emulsions obtained without fragrance (φd=0). The oil phase is made of IMP and 10
wt% of PGPR and the aqueous phase contains a) 1wt% of Tween 20 and b) 10% of Tween 20

S3:

Figure S3: Optical micrograph of the double

emulsion with fragrance C. It is made of 75 wt%
of PGPR (10 wt%)-stabilized globules containing
20%wt% de fragrance C droplets and 7.5 wt% of
Tergitol 15-S-12 in the water. Therefore, the
fragrance content is 15 wt% of fragrance with
respect to total sample.