NORTHERN MINDANAO COLLEGES, INC.

Atega Street, Barangay 11 Poblacion, Cabadbaran City

GENERAL CHEMISTRY-2
8th UNIT EXAMINATION
SECOND SEMESTER (S.Y. 2022-2023)

Name: _______________________________ Grade & Section: ________________

Teacher: _______________________________ Score: ________________

I. MULTIPLE CHOICE (15pts)

Direction: Write the letter of the correct answer in each item in the space provided before the number.
Use small/lowercase letters only.
_____1. What happens if the internal energy of the system is increased?
a. change in state of the system is increased      c. the temperature of the system may rise       
b. the chemical reaction may take place d. all of these
_____2.  If the ΔH value is less than zero than reaction will be ________.
a. Exothermic b. endothermic c.  both d.  none of these
_____3.  What is the study about energy of a chemical system?
a. stoichiometry b. thermochemistry c.  thermodynamics d.  chemical kinetics
_____4.  Which of the following refers to the environment in which a system is studied?
a. state function b. surrounding          c. system d.  phase
_____5.  Which of the following is the unit of heat in the SI system?
a. kJ/mol b. Cal c.  J d.  kJ
_____6.  What is the mathematical form of the first law of thermodynamics?
a. ΔH=qp       b. E = q + W                         c.  ΔE = q x v d.  all of the above
_____7.  Which of this reaction involves heat to evolve?
a. endothermic b. spontaneous c.  non-spontaneous d.  exothermic
_____8.  When enthalpy of product is higher than the reactant then the reaction will be _________?
a. endothermic b. spontaneous c.  non-spontaneous d.  exothermic
_____9.  What are the two fundamental ways to transfer energy?
a. pressure and temperature    c.  heat and work
b. pressure and volume d.  heat and volume
_____10.  Enthalpy change can be ______.
a. calculated by Hess Law c.  both a and b
b. can be measured by a calorimeter d.  none of these
_____11.  The first law of thermodynamics states that energy cannot be _______.
a. created only b. destroyed only c.  converted d.  created and destroyed
_____12. The change in the energy between a chemical reaction and the surroundings at constant temperature
is called ________?
a. enthalpy change b. enthalpy c. enthalpy profile d. dynamic enthalpy
_____13.  The application of law of thermodynamics to the enthalpy change was done by _________.
a. Isaac Newton b. Germain Henri Hess c. Aristotle d. Lewis
_____14. The first law of thermodynamics is all about __________.
a. enthalpy b. entropy c.  internal energy d.  temperature
_____15.  Which of the following is not a statement of law of thermodynamics?
a. Energy can neither be created nor be destroyed.
b. The total energy of the universe remains constant.
c. Enthalpy change depends only upon initial and final state.
d. It is impossible to construct a perpetual motion machine.

II. CALCULATION
Direction: Calculate the following thermochemistry problems. Show your complete solution.
No solution means wrong answer!
A. FIRST LAW OF THERMODYNAMICS
ΔHf˚ (kJ/mol)
1. How much work in joules is done when a piston expands from a volume of 13.27 liters to 76.55 liters against a
pressure of 14.89 atm? Fe 2O3(s) -824
Fe3O4(s) -1118
CO(g) -111
CO2(g) -394

2. In a refrigeration system, the refrigerant gas is compressed from a volume of 0.0423 liters to a volume of
1.876 liters while expanding against a constant pressure of 0.278 atmosphere pressure. What is the internal
energy of the system if it loses 21.39 J of energy?

B. ENTHALPY CHANGE (ΔHrxn˚)

Balance the chemical equation and use the ΔHf˚ information provided to calculate the ΔHrxn˚ of the following:
3. Fe2O3(s) + CO(g) → Fe3O4(s) + CO2(g)

ΔHf˚ (kJ/mol)
IF7(g) -941
IF5(g) -840
IF(g) -95.4

4. IF7(g) + I2(g) → IF5(g) + IF(g)

C. ENTHALPY CHANGE (ΔHrxn˚) USING HESS’s LAW

Use the standard reaction enthalpies to determine the ΔHrxn˚ of the following:
5. 2NO(g) + O2(g) → 2NO2(g) ΔHrxn˚ = ?
Given: N2(g) + O2(g) → 2NO(g) ΔHrxn˚ = 183 kJ/mol
½ N2(g) + O2(g) → NO2(g) ΔHrxn˚ = 33 kJ/mol

6. P4(g) + 10Cl2(g) → 4PCl5(s) ΔHrxn˚ = ?

Given: PCl5(s) → PCl3(g) + Cl2(g) ΔHrxn˚ = 157 kJ/mol
 "Honesty is the best policy!
Prepared by: Submitted to: Noted by:

MEA-ANN OSCIANAS, LPT JEVANH A. EUGENIO, MATF HERMIE LIZA D. SASIS, MACDDS
Subject Teacher Senior High Coordinator Basic Education Principal

NORTHERN MINDANAO COLLEGES, INC.

Atega Street, Barangay 11 Poblacion, Cabadbaran City
GENERAL CHEMISTRY-2
8th UNIT EXAMINATION
SECOND SEMESTER (S.Y. 2022-2023)

Name: _______________________________ Grade & Section: ________________

Teacher: _______________________________ Score: ________________

III. MULTIPLE CHOICE (15pts)

Direction: Write the letter of the correct answer in each item in the space provided before the number.
Use small/lowercase letters only.
_____1. What happens if the internal energy of the system is increased?
c. change in state of the system is increased      c. the temperature of the system may rise       
d. the chemical reaction may take place d. all of these
_____2.  If the ΔH value is less than zero than reaction will be ________.
b. Exothermic b. endothermic c.  both d.  none of these
_____3.  What is the study about energy of a chemical system?
a. stoichiometry b. thermochemistry c.  thermodynamics d.  chemical kinetics
_____4.  Which of the following refers to the environment in which a system is studied?
a. state function b. surrounding          c. system d.  phase
_____5.  Which of the following is the unit of heat in the SI system?
a. kJ/mol b. Cal c.  J d.  kJ
_____6.  What is the mathematical form of the first law of thermodynamics?
a. ΔH=qp       b. E = q + W                         c.  ΔE = q x v d.  all of the above
_____7.  Which of this reaction involves heat to evolve?
a. endothermic b. spontaneous c.  non-spontaneous d.  exothermic
_____8.  When enthalpy of product is higher than the reactant then the reaction will be _________?
a. endothermic b. spontaneous c.  non-spontaneous d.  exothermic
_____9.  What are the two fundamental ways to transfer energy?
a. pressure and temperature    c.  heat and work
b. pressure and volume d.  heat and volume
_____10.  Enthalpy change can be ______.
a. calculated by Hess Law c.  both a and b
b. can be measured by a calorimeter d.  none of these
_____11.  The first law of thermodynamics states that energy cannot be _______.
a. created only b. destroyed only c.  converted d.  created and destroyed
_____12. The change in the energy between a chemical reaction and the surroundings at constant temperature
is called ________?
a. enthalpy change b. enthalpy c. enthalpy profile d. dynamic enthalpy
_____13.  The application of law of thermodynamics to the enthalpy change was done by _________.
a. Isaac Newton b. Germain Henri Hess c. Aristotle d. Lewis
_____14. The first law of thermodynamics is all about __________.
a. enthalpy b. entropy c.  internal energy d.  temperature
_____15.  Which of the following is not a statement of law of thermodynamics?
a. Energy can neither be created nor be destroyed.
b. The total energy of the universe remains constant.
c. Enthalpy change depends only upon initial and final state.
d. It is impossible to construct a perpetual motion machine.

IV.CALCULATION
Direction: Calculate the following thermochemistry problems. Show your complete solution.
No solution means wrong answer!
D. FIRST LAW OF THERMODYNAMICS
ΔH ˚ (kJ/
f mol )
7. How much work in joules is done when a piston expands from a volume of 13.27 liters to 76.55 liters against a
Fe2O3(s) -824
pressure of 14.89 atm? (11 points)
Fe3O4(s) -1118
CO(g) -111
CO2(g) -394

8. In a refrigeration system, the refrigerant gas is compressed from a volume of 0.0423 liters to a volume of
1.876 liters while expanding against a constant pressure of 0.278 atmosphere pressure. What is the internal
energy of the system if it loses 21.39 J of energy? (16 points)

E. ENTHALPY CHANGE (ΔHrxn˚)

Balance the chemical equation and use the ΔHf˚ information provided to calculate the ΔHrxn˚ of the following:
9. Fe2O3(s) + CO(g) → Fe3O4(s) + CO2(g) (15 points)

ΔHf˚ (kJ/mol)
IF7(g) -941
IF5(g) -840
IF(g) -95.4

10. IF7(g) + I2(g) → IF5(g) + IF(g) (13 points)

F. ENTHALPY CHANGE (ΔHrxn˚) USING HESS’s AW

Use the standard reaction enthalpies to determine the ΔHrxn˚ of the following:
11. 2NO(g) + O2(g) → 2NO2(g) ΔHrxn˚ = ?
Given: N2(g) + O2(g) → 2NO(g) ΔHrxn˚ = 183 kJ/mol
½ N2(g) + O2(g) → NO2(g) ΔHrxn˚ = 33 kJ/mol
 "Honesty is the best policy!"

Prepared by: Submitted to: Noted by:

MEA-ANN OSCIANAS, LPT JEVANH A. EUGENIO, MATF HERMIE LIZA D. SASIS, MACDDS
Subject Teacher Senior High Coordinator Basic Education Principal