Revision chemistry 2nd terminal examination

1.Geometry and hybridization in BCl3 PCl5 and CH4

2.Lewis structure of H2S , SiCl4 and HCOOH

3.A chemical reaction is an equilibrium when

A) the reactent are completely converted to product

B) rate of Forward reaction is equal to rate of backward reaction

C) formation of product is maximum

D) react product are equal and quantity

3.Kjeldahl method is used for estimation of: ( nitrogen )

4 method is used for the estimation of(nitrogen)

5. In isothermal expansion of ideal gas:(dT=0) and in adiabatic process(dq=0)

6.Which of the following are isoelectronic species

a) Na+ and Mg2+ b Na+ and Ca2+ c) Ar and Mg2+ d) k+ and Ca2+

6 who discovered neutron, electron And proton

a) Chadwick b) JJ Thomson c) goldstein d) Hund

7 Give an example of Lewis acid is

a) MgCl2 b) BCl3 c( NaCl d) SnCl4

Que 2 Fill in the blanks:

1. In C2H4 molecule there are______ Sigma and ______ pie bonds

2.____ is he required to raise the temperature of 1 gram substance by 1°C( specific heat capacity)

3. Enthalpy change for exothermic reaction is______( negative)

4. System in Which heat is exchanged is called __________

5.Henry laws related to the solubility of ________in liquid

6. Those reaction with proceed in wind direction are called ______(Irreversible reaction)

7._______ bond is formed by S-S overlapping .

8 Baeyer's reagent is_______.

9 an acid is a substance which has tendency______ a Proton and a base is a substance which has
tendency to____proton.

10 the equilibrium in which the substance involved are present in different phase is called______
(heterogeneous)

11.. Solution of Acetic Acid and Sodium Acetate is an example of_______ buffer solution

12. relationship between pH and pOH is (pH + pOH=pKw=14)

13. Isotopes have same number of____.

14. Process of evaporation of water is an __________process.

Que 3 Match the column:

[A] [B]

1.Hunds Rule measurement of disorder

2. Magnetic quantum number water

3.CH3COOH immiscible liquid

4 hydrogen bonding orientation of electron

5 Entropy Ethanoic Acid

6. Resonance Dumbell

7 ∆H=Positive. We electrolyte

8. Steam distillation Benzene

9. pH scale Maximum multiplicity

10. Ammonium hydroxide Endothermic reaction

11 electromeric effect temporary effect

12. P orbital Sorenson

Que 4. Answer the following question in one sentence or Word

1. What is de Broglie relationship (formula) and

2. What is the relationship between Kp and Kc

3. What is the charge present on carbon in carbanion and in carboction

4. What is the hybridization state of carbon in CH2 =CH2 and in CH3-CH3

5. Which catalyst is used in friedal craft reaction

6.Catalyst used in hydrogenation of alkenei is (Ni-Pt/Pd)

7. Bond angle in water ( H2O)molecule is:

8. Bond angle in ammonia molecule is

9.What is IUPAC name of CH3-CHBr-CH2-CH3

10. What is Functional group of amide RCONH2

11 which type of isomerism is shown by CHBr =CHBr( geometrical isomerism)

12. Any atmo group of atom possessing and unpaired electron is known as (free radical)

13. Manufacturing of ammonia by have was process works on which principle ( Le Chatelier)

14 what is Teflon polytetrafluoroethalene

Que answer the following question in short

1.. What is Heisenberg uncertainty principle?

2.Write Afbau principle.

3. Explain Hund's Rule

4. What is Planck's Quantum theory

5.What do mean by lone pair of electron?

6.What is Resonance

7. What is hydrogen bonding explain with example

8.What is dipole moment

9.Explain Homologous series with example.

8. Define functional group ?

10.Write isomers of pantane. Write their IUPAC name also

11. Give chemical reaction only

( a) benzene to Toluene and (b)Friedal craft reaction

12 give chemical reaction only hello generation of alkane and oxidation of alkane

13What is Henry's law?

14.What is buffer solution?

15. Define solubility product

16Define internal energy

17Explain Enthalpyand entropy

18Determine the bond order in N2 molecule according to Molecular orbital theory.

19 difference between atomic orbital and Molecular orbital

20 Write two difference between bonding molecular orbital and antimony Molecular orbital

20. Give lUPAC name of the following compound CHCl3 , CH3COCH3,

21 what is IUPAC name of C6H5 OH , C6H5NO2

22.what are the hybridization state of carbon in Benzene (C6H6)molecule