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Articulo Cientifico - Bioetanol - Caña de Azucar
Articulo Cientifico - Bioetanol - Caña de Azucar
Aguilar-Rivera, N.
bioethanol from sugarcane
Advances in Agricultural Research, vol. 11, no. 3, September-December, 2007, pp. 25-39 University of Colima
Colima, Mexico
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Summary Abstract
The search for the viability and development The viability of the Mexican sugar industry
of the sugarcane agro-industry is already an is a political imperative. Sugar is Mexico's largest
imperative policy. The production of cane and agricultural industry. Sugar cane is the first lar
sugar constitute the main agro-industry in the gest cultivated crop, supplying raw material to
country, with a presence in 57 sugar mills, over 57 mills located in 15 states. The current
located in 15 states of the republic. However, inefficiency of the Mexican industry and the
current productive inefficiency, high costs, and advent of increased production, displacing
other causes —such as the entry of lower-cost domestic sugar used in soft drinks; and the
high fructose corn syrup (HFCS)— have displaced government issued a large number of import
domestic consumption of cane sugar, mainly in permits thus allowing large quantities of lower
bottled beverages. All these factors have price world sugar like HFCS to enter the domestic
contributed to the current and protracted crisis market. All together these factors contributed to
in the sugar sector. Therefore, the industry must the crisis of the sector. The industry should be
restructure and reduce sugar production towards restructured and downsized to be competitive
competitiveness, with the alternative of fuel producing ethanol (EtOH), like the easiest ways
ethanol in the search for a future for the sugar to increase the predominant alternate fuel and
industry in Mexico. With the large-scale the opportunity to make the Mexican su gar cane
production of ethanol (EtOH) by sugar mills, it is future a reality. If the ethanol (EtOH) is produced,
possible to visualize a new and future market for it's possible to see a growing role for renewables
the use of renewable energy in Mexico, in the Mexican's energy future, the sugar factories
opportunities for export, and increased must involve them as partners in the continued
environmental and economic benefits through expansion of ethanol production and use in
of its use. The flexibility of the combined Mexico, export opportunities, increase public
production of sugar and ethanol in the mills will awareness of ethanol's benefits and create an
allow the achievement of environmental schemes economic climate for ethanol's expanded use.
and objectives as a nation. For the sugar industry, The flexibility of production of sugar and ethanol
its greatest at the factories will allow a role for ethanol to be used to achieve the nation's cle
The challenge, in this sense, represents reducing Most important opportunity for sugar cane
the current costs of ethanol production through industry is to continue to reduce ethanol
the use of genetic engineering, the use of production costs through genetic engineering,
different raw materials and the entire sugarcane feedstock diver sity using whole sugar cane and
plant and introducing technological improvements. technology improvements.
Keywords Keywords
Sugar industry, biofuels, biomass. Sugar Industry, biofuels, biomass.
Introduction
Ethanol (EtOH) is the most widely used biofuel today in the United States,
Brazil, Japan, Colombia, India, and the European Union; Millions of liters are
added to gasoline each year to improve vehicle performance and reduce air
pollution. Ethanol is an alcohol and most of it is made by converting sugars by
fermentation into ethanol, which is then distilled into its final form.
Ethanol is used to increase the octane number of gasoline and improve the
quality of its emissions, like the E10 blend (10% ethanol and 90% gasoline) but
it can be used in higher concentrations, such as the E85 blend or its pure form.
All automobile manufacturers that trade in the world approve the use of certain
mixtures of ethanol and gasoline. Ethanol fuel blends are successfully used in
all types of vehicles and machines that require gasoline [Cabrera et al., 2000].
Therefore, the objective of this work was to evaluate some scientific-technological,
economic, political and social aspects that the diversification of the sugarcane
agroindustry implies under the premise of ethanol production, from sugarcane
biomass. , by offering a critical evaluation of some of the works published on
sugarcane ethanol and situating them in certain perspectives of
For the 2006-2007 harvest, the sugarcane and sugar agroindustry is going
through a difficult situation. However, the biggest difficulty in the sector is that its
members, although they have already detected their causes, are not united to
analyze the problems and find solutions; This agro-industry is characterized by
enormous technological lags in the fields and factories, obsolete productive
infrastructure, serious problems of contamination and environmental impact,
expensive, insufficient and untimely financing, limited and ambiguous marketing
policies, sugarcane legislation with deep delays, organization of producers with a
vocation paternalistic and little self-management initiative; entrepreneurs with limited
audacity and vision, as well as the absence of an integral and territorial development
project in the short, medium and long term that allow, with order, to consolidate
sustainable development in which all the sectors involved in it participate and are committed. .
In this sense, GEPLACEA [1991], commented more than a decade ago that for
a country that produces sugar cane, like Mexico, two possible alternatives are open:
raising the productivity and effectiveness of production and thus ensuring the
competitiveness of the costs; and on the other hand, to fully diversify, to distribute
risks and be more independent of the physical sugar market.
These alternatives imply a reordering and improvement not only of the
sugarcane and sugar production facilities and areas, but also —and therefore,
integral— of the industries, facilities and support facilities and their labor force
[Viniegra, 2001]. When analyzing the industry, it is observed that it has several
problems or costs that can be improved in the short, medium and long term to
increase its profits without affecting the sugar cane. They are internal situations that
can and must be addressed immediately in order to survive the crisis before it is too late.
To overcome this situation, sugarcane growers can work to increasingly increase
the sugar production of their crops. For their part, the sugar mills have in view the
opportunity to diversify the sector with the option of producing fuel ethanol; This is
the opportunity for a rapprochement between mills and sugar cane growers in the
management and dissemination of information to seek joint solutions. The difficult
situation of the sugar mills can be reversed if they open up to the market for
oxygenating gasoline for automobiles; It is clear that the support of the State is
required through the adoption of more advanced ecological policies, stimuli that
allow the use of cutting-edge industrial and administrative agricultural technology
in the world, only through which it will be possible to obtain competitive and viable
agro-industrial products. to be used as components of reformed gasoline blends [Martínez, 2005].
In 2007, the State promulgated the Law for the Promotion and Development of
Bioenergy and the National Program for the Sugarcane Agroindustry 2007-2012, to
promote and develop the use of bioenergy as key elements.
By 1980, CO emissions were higher than 50 g/km and they were reduced to
less than 5.8 g/km from 1995. One of the disadvantages of using pure ethanol is the
increase in aldehyde emissions when it is used. compared to gasoline or a gasoline/
ethanol blend. As the percentage of ethanol in the mixture continued to increase, a
clear decrease in CO and HC remained constant, while the NOx emission with
respect to pure gasoline increases with the amount of alcohol; As for CO2, emissions
continue to be similar and even slightly higher.
Comparing the emissions of ethanol blends, in proportions greater than 30%,
reductions of 37%, 24% and 20% are observed —on average— in CO, HC and NOx
emissions, respectively (Table 4).
The production of Ethanol (EtOH) from the sugar industry requires the integration
of the distillery with the production of sugar; which enables not only the use of the
final molasses, but also the juices, intermediate molasses and the use of bagasse
and RAC (Agricultural Harvest Residues) as energy sources, avoiding the burning
and re-burning of sugarcane fields.
Other alternatives for raw materials from the sugar process can be used,
such as filter juices that represent advantages in saving honey, decreasing
fuel consumption, increasing sugar quality and greater technological integration
of sugar-derivatives within of the agro-industrial complex.
The biggest problem with the production of alcohol, starting from sugar
cane, is: the environmental pollution created by the liquid waste from distilleries
(vinasse) and the difficulty, under certain conditions, of obtaining a positive
energy balance. However, in a balanced operation in which the sugar factory
and the distillery are integrated, this problem can be minimized. Other
disadvantages are: it has a lower energy density than gasoline; the driver
must fill up the tank more frequently, it is more expensive than gasoline (about
1.5 times under current Mexican conditions), it generates highly evaporative
emissions, it contains two thirds of the energy contained by the same volume
of gasoline, it presents corrosion problems of mechanical parts and seals, it
presents difficulties to ignite in cold climates, the emissions of nitrogen oxides
and aldehydes increase, and problems with cold ignition with E-100 [Westcott,
2007 and Musalem, 2006]. .
Ironically, sugarcane growers may be among the staunchest opponents
of ethanol production. In Mexico, the sugarcane sector has a complicated
history of contentious labor relations, disputes over prices and land use, and
frequent official interventions. The Mexican government has been inclined to
protect sugarcane producers with subsidies and regulations that directly
affect the price of a ton of sugarcane. Dismantling these protections to
encourage the switch to ethanol carries political risks that the government will
not be willing to take.
At the present time, several ethanol production plans can be developed
for each mill in particular, within parameters established by the industrialists
themselves, without significantly affecting sugar production. The use of A or B
molasses and/or cane juice can satisfy the local demand for ethanol while
simultaneously maintaining sugar production levels. The following benefits
could be obtained at the mill level and sugarcane supply area [Enríquez,
2005]: increase in net income for sugarcane growers, workers and suppliers,
which would inject income into the local economy, increase in net income for
process each ton of cane, reduction of the unit cost of production, increase in
the use of existing industrial capacities in the mills and the field, fresh income from
taxes, less dependence on foreign ethanol and gasoline, and sustainable use of
natural resources.
When considering the implementation of a national program based on ethanol
and its use as a fuel, the following should be taken into account [Mesa, 2000;
Enriquez, 2005; Farrel 2006; Guo, 2006 and Viniegra,
2007]: 1. Consider the possibility of starting, in principle, on a small scale with
10% ethanol mixed with gasoline and increasing the proportion according
to the advancement of technological, economic and political developments. nationals.
2. Be cautious in the use of technologies proven in other countries on a
commercial scale, systematically evaluating the particular conditions of
each mill when implementing them.
3. The mills' decision to produce ethanol must be based on a careful evaluation
of the objectives and realistic technical and economic feasibility studies.
Although this analysis does not show the economics of fuel ethanol
production, if an attempt were made to launch an ethanol program under the
current conditions of the sugarcane agro-industry in Mexico, several obstacles
would be faced; Firstly, PEMEX tends to consider ethanol as a competitor
that would affect its percentage share in the energy market; This resistance
is especially relevant because PEMEX also controls the networks of gas
pipelines and service stations, whose storage tanks must be modified before
receiving gasoline mixed with ethanol.
In addition, it can be said that its current high cost, in relation to petroleum
derivatives, constitutes the reason why the political decisions and regulations
of fiscal stimulus, research, technology transfer and others (by the federal
government) that allow in the medium term to promote its intensive use and
for this sector to be competitive on a par with oil. Another important aspect is
the automobile industry, which may also resist the introduction of ethanol.
Although multinational automakers such as Volkswagen, General Motors,
Ford and others openly support ethanol gasoline, their dealerships in
countries like Mexico will face the prejudices that people will have about that
fuel. Many mistakenly believe that even small amounts of ethanol can harm
the engine of their vehicles, for example. Without strong incentives to do so,
car dealers are unlikely to take on the job of educating their customers about
the benefits of ethanol.
Undoubtedly, biofuels are a transition to the future in terms of energy.
In other words, they constitute a kind of bridge between hydrocarbons and
the renewable energies of the future. However, the processes of incorporating
the production, transport, distribution and commercialization of biofuels are
very long term. The introduction of these fuels requires a strict political will
and institutional agreement between government agencies is vital.
Participation and commitment from the private sector are critical to the
success of the program. In addition, the production of biofuels involves a
large amount of local labor, with varying degrees of preparation to cover
agricultural, energy, commercial, technological, quality control needs, etc. [Canizales, 2001].
When producing biofuels, it is essential not to establish competition with
food production, since, due to the current conditions of the field, Mexico is no
longer self-sufficient in almost any type of agricultural product, with the
exception of sugar cane [Musalem, 2006].
Other alternatives for raw materials in the sugar process can be used, such as these:
which represent advantages in saving honey, reducing fuel consumption, increasing the
quality of sugar, and greater technological integration of sugar-derivatives within the agro-
industrial complex. . In a general sense, the options for the production of ethanol (EtOH),
from sugar cane, are the following [Murtagh, 2003]:
For the particular case of hydrolysis of lignocellulosic materials from sugar cane or
breakdown of the molecules in an aqueous medium, its purpose is the transformation of
complex sugars (polysaccharides) into simple carbohydrates. This is accomplished with
sulfuric or hydrochloric acid at high temperatures and short or long operating times; the
acid acts as a catalyst and a mixture of glucose and xylose is obtained with some
degradation products such as acetic acid, furfural and derivatives of lignin breakdown
[Canizalez, 2001; Krishna, 2000].
Distillery stillage can become a source of by-products and an asset if this problem is
addressed systematically and with financial resources.
suitable. Another important factor is the cost of the distillery that depends on
factors such as location, raw material and legislation [Agrawal, 1997].
The separation of dilute aqueous solutions of ethanol (EtOH) (from 96 °GL to
99.99 °GL) has been a well-studied and industrially tested process. However, the
need to obtain dehydrated alcohol in order to be used as an oxygenating additive
for gasoline has imposed a series of challenges on the industry and research
centers, in order to reduce the energy costs of EtOH recovery while complying the
corresponding quality standards. Additionally, the environmental impact of some
traditional separation technologies has made research on alternative and
unconventional schemes much more intense [Sánchez, 2005].
On the other hand, the diversity of technological alternatives for the production
of fuel ethanol has made the analysis of the global process crucial, along with the
design and development of each of the operations that comprise it. Among the
new research and development trends in this area is the integration of the process
with a view to revealing the very complex interactions between the different stages
of the production process [Farell, 2006]. The development of integrated processes
will allow a substantial reduction in production costs and increase the
competitiveness of bioethanol compared to gasoline. On the other hand, the
integration of processes is an essential condition to optimize the ethanol production
process, in such a way that not only the minimization of production costs or the
maximization of different financial indicators are considered as objectives, but also
the improvement of the environmental performance indices of this process [Guo, 2006].
fundamental for the most rational use of this precious resource. The needs of
development require increasing amounts of energy and along with this, the
reduction of greenhouse gas (GHG) emissions.
At present, there are already interesting results on the use of ethanol as fuel
or as an oxygenating agent, developed in CONACyT centers and Mexican
universities that demonstrate the feasibility of this technology; and that also makes
use of renewable resources and presents ecological advantages. Therefore, one
strategy could be to start with a program for the production of ethanol to be used
as an oxygenating agent for the current gasoline and later increase it until it
reaches 100%. There is no doubt that this is a path in which the different actors
must be committed: car manufacturers to develop test models; PEMEX to
oxygenate gasoline with ethanol; the State —by means of laws that regulate its
use and grant incentives for private initiative—; or that the government itself invest
in the development of this technology; researchers, to achieve an economic and
profitable process; society, to ensure that the new alternative does not contaminate
or generate health risks; field workers, to have better yields and characteristics of
the raw material to be used and to organize its collection.
The selection of molasses, guarapo, sugarcane bagasse and RAC, as raw
materials, is due to the fact that they are a source of fermentable sugars and that
it has traditionally been collected and stored in mills that are distributed in 15
states. Even though ethanol is produced in some, it is not anhydrous and the
production capacity is not sufficient for the demand that is expected. Therefore, it
will be necessary to build new plants with new technologies that allow the use of
cheaper raw materials, such as sugarcane bagasse and RAC. Due to its
magnitude, it is an interesting opportunity that would allow solving the economic
difficulties of the present and could supply the national demand for the
pharmaceutical and food industries; and, in fact, a large part of the gasoline
consumed in the country could be oxygenated with ethanol.
It is also important to mention that because they have sugars, the sugarcane
bagasse and the RAC must undergo a hydrolysis process to free the sugar units
that will later be used in fermentation. In this aspect, a significant effort must be
made to acquire or develop a technically and economically viable technology, as
well as in the optimization of energy management; At the same time, the gradual
increase in cultivated area should be planned and support should be given to
improve yields per hectare.
The use of ethanol will bring ecological, economic and social benefits;
therefore, it is important to develop technologies for a production that allows
satisfying the demand at affordable prices. For all of the above, it is necessary to
have tools and criteria that allow our country to make the right decisions and plan a
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