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Themodynamics1 2
Themodynamics1 2
Cylinder
Heat, Q
Figure 1. 1. Piston-Cylinder
Device as a 'Closed System
system. I
·- -------------·
I
I I
Work, We or Wp
p
2
---r---------------------
, • I
I I
I .I
I
:
½ V1 V
Figure 1.3. The p V Diag
The State Postulate ram
1. The First Law of Thermodynamics deals with law of conservation of energy. The
law of conservation of energy states that energy can neither be created nor
d.estroyed, it just transforms into another form.
2. The Second Law of Thermodynamics deals with the direction of fl.ow of heat energy,
that is from the higher-temperature body to lower-temperature body, and the
property known as Entropy.
3. The Third Law of Th.ermodynamics deals with the.restricti'on of all physical systems
to the temperature regime that excludes absolute zero. Th� law states that at
absolute zero, the entropy of a pure substance (in equilibrium at 0 ° K or 0 ° R) in
'·
some perfect crystalline form becomes zero.
4. The Zeroth Law is the law concerning thermal equilibrium -and is the basis for
temperature measurement. The law states that when .two bodies, isolated from
other environment, are in thermal equilibrium with a third body, the two are in
thermal equilibrium with each other.
NEWTON'S SECOND LAW OF MOTION
tion of a particular
• Newton's s cond law of motion states that the accelera
on it and inversely 2.
body is directly proportion I to the resultant force acting
e of velocity of a
proportional to its ma s. Ace I r tion is also the derivativ
body with resp ct t tim .
F m Eq. 1.1
a or
oc -, =k , r =-
m m k
ma
Values of Constant, k, in the equation k =
F
k=�
= (1 kgm) ( 1 m / s2 ) - kg m . m
1
F 1N N. s 2
-
C. Fps System: 1 lb1 accelerates 1 slug m
ass at 1 fps2 .
(1 slug) (1 fps2 )
_ ma --
k --= �-_!___ sug- 1 ft
F 1 lb
1
t - lb f . s2
7
2. Th
80.
b. Mk t . 0 m/ 2
•
=-
m k •m
m_
1k f k f . 2
Fp y t m: 1 lb, 1 I m t ?..174 fp 7
•
2
m (1 I bm ) ( 32. 174 fps ) I b . ft
k=-=-------=32.174 _m_2
F 1 lb t lb t · s
■ At the surface of the earth near sea level, mass and weight are numerically
equal.
Ex. 1.1] The weight of an object is 80 lbr Determine its mass at standard condition.
Solution:
m=
F9 k
_
(801b, )( 32.174 lb m · ft/lb 1 • s2) _
g - 4f / 2
32.17 t s
-BO lb, ans.
Ex. 1.2] Find the weight of a 75-kgm object at standard condition.
Solution:
DENSITY.
• Density is an intensive thermodynamic property that is usually used to determine
the mass of the substance or system. It i� the mass per unit volume of a substance.
m Eq. 1.2
p·=-
Where p = density of the substan·ce,. kg/m 3 , lb/ft3
m = mass of the substance,. kg, lb
V = volume of the substance, m 3 , ft3
SPECIFIC VOLUME
. • Specific volume is the volume of a unit mass substance. It is also defined as the
rec\procal of density.
V=-=-
V 1
. Eq. 1.3
m P
SPECIFIC WEIGHT
Eq. 1. 4
ht of
3
, kgt, lb,
weig the body
Note: If the mass is at the surfac
e of the e arth, near �
equal to k (g � k). ea level, g is num r
Ex. 1.3] Det rmin th- p Ifie w ight of wat r t tandard condition, in kg/m3 •
pg (1000 k / m )( .80
'Y - k - k • m-· --
80 . N/m3 = 1000 kg, /m3 ans.
1 ,2
N
Ex. 1.4] Two liquids of differ nt d n iti (p, 1 00 kg/rn 3 , p 2 - 500 kg/m3 J were po red
together into a 100-liter container, filling it. If th r ulting den ity of the mixture is 800
kg/m3 , find the respective amounts of liquids used. Also, find the weight of the mixt re;
local g = 9.675 m/s2 • (Problem by Faires)
Required:
The mass of each liquid and the weight of the mixture if g = 9.675 m/s2
Solution:
• · lvln f r m 1 nd m2 ,
n11 =
11V, 1 00(0.03) 45kg
ans.
t 12 - p V - 0 (0.07) 3 kg ans.
• r th w i ht of th mixtur ,
m g {45 kg 35 kg)(9.675m / s
2
F = m =
) = 78_93 kg1
k kg•m
g
9.8066 ans.
kg, · s2
Ex. 1.5] A cylinder 6 inches in diameter and 1 0 inches high contains oi� that has a
d nsity of 850 kg/m3 • Determine the weight of the oil, in lb t .
p = 850 kg/m
3
H= 10"
Required:
Solution:
kg 2.205 lbm
850 m 1 n,
g m
y = p = ___ _3----'--"_1_k-=-
gm �3.2-8 ft 32.17 4?
k
----L.. == 53.11 lbft
::.:.._ :..:__
32 .7 1 4� l b ft
3(
- ,
3
lb t . 8 2
l l
Solving f r th w i ht foil,
SP CIFIC GRAVITY
Ex. 1.6] The fuel tank of a car holds 60 liters of gasoline. Assuming that the gasoline
has a specific gravity of 0. 74, determine the weight of the gasoline in the tank, in kg .
t
Required:
Solution:
2
F =mg= (44.4 kgm )(9.8066 m/s ) ans.
g
k kg . = 44 .4 kg1
9.8066 m �
. kgf ·S
12
, n: II I
-y 2 I /t
Soluti
quiri d:
Th tum f tt Ii
olution:
From th qu ti n f if I w I � ,
0 lb PRE
V == Fg = _ , = 1. ft 3 a s.
y 200 lb, I ft 3
E . 1.8] It is proposed by gasoline dealers to sell gasoline by the liter. If gasoline has a
density of 1.3 slugs per cubic feet, what is the weight of 60 liters of gasoline?
Given: Gasoline
y = 1.3 slugs/ft 3 V = 60 liters = 0.060 m 3 = 2.1173 ft3
Required:
The weight of the gasoline
Solution:
Ex. f.9] A household oil tank can hold 275 gallons of oil. If oil has a specific weight of
8800 N/m 3, how many pounds of oil will there be in a full tank?
Solution:
PRESSURE
Standard atmospheric pressure at the surface of the earth, near sea level
1 atmosphere = 29.92" Hg
1 atmosphere = 760 mm Hg
1 atmosphere = 101.325 kPa
1 atmosphere= 14:7 psi
1 atmosphere= 34· ft H2 O
1 atmosphere = 760 Torr
1 a�mosphere = 1.0332 kg/cm 2
1bar=100 Pa=0.10MPa
1 m Hg= 1 Torr
14
ur
Fluid Pr ur
ur th f rce exerted by a
ut r luld u
r unit r
•
) JJllll o(
l·luid
Unit Arc·• A
F9 mg
p=-=- Eq. 1.7
A kA
m = pV = pAh
•
Eq. 1.8
Absolute Pressure
• Absolute pressure is the algebraic sum of the baromet
ric Pr.assure or atmospheric
pressure and the gauge pressure.
Eq . 1. 1 0
I5
Wh r
tm
-
Not : k
n p b elute; and kPag
m
au I r ·s ure '
p& Defined
� Standard
--,,-----t-----'-----.----..!... Atmospheric
Vacuum Pressure line
Absolute Atmospheric
Pressure, - Ps Pressure ' pab Pressure, Patm
Absolute
Pressure
§) V\ Pressure Gauge
'-(Bourdon tube)
System
Ex.
p · ide the atm
ow
t h ric h Giv
ce
m
�Mercury
Ex. 1 10] A 30-m vertical column of fluid, p = 1878 kg/m 3 is located where
g = 9.65 mls 2 • Find the pressure at the base of the column, in kPag. So/
_ p = 1878 kg/m3
g = 9.65 m/s2
Ex.
at
Gi
Required:
Solution:
Solving for th� fluid pressure or the hydrostatic pressure at the base of the fluid, R
p=
(pg)h (1878kg/m3 )(9.65 m/s2 )
T (30m)=543681 N/m2 (gauge)
=
kgm •m
1 2
N-s
p = 543681 Pag = 543.681kPag n.
17
ndard
Ex. 1.11] A vertical column of water will be upported to what height by sta
atmospheric pressure in ft?
Required:
sphere
The height of the water supported by the standard atmo
Solution:
ans.
Ex. 1.12] The pr ssur insid h boil r i .5 g/cm2 • The barometric pressure of the
atmospher is 7 8 m of Hg. Find he absol e pressure in the boiler.
Given: A boil r
pg= 9.5 g/cm2
P tm
= 768 mm Hg
R qui d:
e ·1e
h a pre
>< K I THERMODYNAMICS 1
lull 11'
Req
p Pg
ur in id th b ii r, p
m
rth olut
olvin tn I m',
SOIL
)( ; ��----, )
o 1 1.
(7 mm
)
1
1. Nim ( -�- 1.04 k I m
p Im -( 1 0
/.
ans
Th r for , P 1.04 .)
E . .13 The door of j t lin r h dim n ion f 2.' m / 1.2 m. If the inside pres�ure Ex ..
of the cabin i 98 kPaa, wh t fore i x rt d on th door then the plane flies at a pre
altitude here the outside pressure is 15 kPaa?
e
Pi= 98 kPaa P0 = 15 kPaa
Required:
So
The force exerted on the door
Solution:
d= 7.5 cm
1/
Required:
Solution:
1 ft
2
p = yh = ( 62.4 lbt /ft )(35 ft) ( -. J = 15.17 psig
3
ans.
12 in
Ex. 1.16] A vacuum gauge reads 1 O" Hg when the atmospheric pressure is 30" Hg.
Assuming the density of mercury to be 13595 kg m/m 3 , determine the absolute pressure
in kPaa.
Required:
oluti n:
- 1 .8 1 .4 k an
eb a
. . 7] A pr , p l wh n h bar metAr · at a re re g
ur u indi , t
equi 1 alent to 14.5 p i. Comput th b lut pr ur in p i and ft of mArc, y if e
specific gravity of m rcury is 13.0.
SG Hg = 13.0 o uti
Reqµired:
Solution:
Re
Ex. 1.18] During take off in space, an 80-kg astrona t' Is
u subjected to an acceleration
equal to 5 times the pull of the earth's standard gravity. If the take off is vertical, what
force does he exert on the seat? (Problem By Burghardt)
Given: An astronaut
m = 80 kg
a = Sg
g = 9.8066 m/s 2
Required:
Solution:
For the force exerted on the seat, as shown in the figure above,
F = ma + mg = 5mg + mg = 6 mg
Ex. 1.19] A hiker is carrying a barometer that measures 101.3 kPa at the base of the
mountain. The barometer reads 85 kPa at the top of the mountain. The average air
density is 1.21 kg/m3• Determine the height of the mountain. (Problem by Burghardt)
Given: A hiker
Pt = 85 kPa
p1 = 1.21 kg/m 3
untain
h=?
Required:
Solution:
■ C n Id r th lumn fth tm rf
J
th mount hi, 8 kl
II
r
' ' I I I I
:;::::-,,,:
::;:-:, ' '
l
: : :{\:t,:: h '/
;::::::::::
,,,,,•,•,' .
. ·l r b 101. kJ'H
P w = 1000 kg/m 3
Required:
I ,
The pressure at points A and B
I
\
Atmosphere
635 mm
Water
h, 510 mm
23
Solution:
IOI 325 p,
Solving for pr ur p ,
Pa =Patm +pHg =p tm +pHg9h 1 =101325 (13590)(9.8066){0.5 1)
Ex. 1.21] As illustrated below, a mercury manometer is attached to the side of a nearly
full water tank. The reading of the mercury column is 15.5" Hg gauge. Although air on
the water maintains the pressure, the other 10-inch leg of the manometer is full of
water; for water, p = 62.3 lb/ft3; for Hg, p = 846 lb/ft3 . If the location is at standard gravity
and the temperature of both the water and mercury is 60 °F:
a) what Is the pressure (psia) In the tank at the level where the manometer is
attached?
b) If the tank extends 1 Oft below this level, what is the pressure at this depth?
(Problem by Faires)
t
int .
int .
l
I0
t t
___.,.._-a·
olut,on:
pA = 22.29 psia
f
3
1ft�
Pc =Pe +ywh 3 =21.93psia+(62.31b/ft 3 )(10ft) )
(
144m 2
.
Pc= 26.26 psia ans.
25
mp = 21 kg
p1 = 600 kPaa
p11 = 170 kPaa Pipe
r
0=20
Required:
=
P 1A 1 + P1 1A 1 1 +mpg
Pm
2
Where A I = 1t d 2 = 1t (0.10m) =0.00785m
2
4 4
2
A111 = 7t 0 2 = 1t (0.20m) = 0.031416m2
4 4
A 11 =A Ill -A I =0.031416-0.00785=0.023566m2
tit ti
ipe and i
,. J m-diam ter ,�rtical p
r, and the
1 w r nd .1 ,·mm r ed •in Nate
•
. t·I n 1
r v1t et ration 1s 9. 45 m /s 2 .
i t n t th 6.1-m marr;
em Y
w r n th un r id ., f the p1 tor.. (Probl
F
Giv n: Th figur t)own
T
D = 30 cm
m p = 50 kg Piston
h = 6.1 m
P atm = 100 kPa 6.1 m
g = 9.45 m/s 2
Required:
a. The force F
b. The pressure of water at the underside of the piston
Solution:
a. Solving for the force requir d to hold the piston at 6.1-m m rk, c nsider the
free-body-diagram of th piston and water column, .
'•
. . . . . . . . . . . . .. .. ..
�
"
•
I
•
11
t
•
•
t
•
'I
•
'
•
•
♦
•
' '-
•
27
kin th ],
■Im WP ·Ww
F-W WW • p Ah
s
F=
( 0k 2) (1
I ( .4 ml
')r: yo., 2
mJ (6.1 m)
N 2
F= 47.1 N ans.
F+pA=p t A+W
. am
PatmA
p
WP+ Ww + pA =P atm A +W
· P
F
pA
TEMPERATURE
• As defined by James Clerk Maxwell, The temperature of a body is the body's
thermal state considered with reference to its ability to communicate heat to other
bodies (Faires, 1978).
• Temperature is also defined as the measure of coldness and hotness of a body. It
is an intensive thermodynamic property used to indicate. the amount of ener gy
within the molecules of the substance.
• Two arbitrary scales are commonly used for measuring temperature, namely: the
Fahrenheit scale (after Gabriel Fahrenheit, 1686-1736), and the Celsius scale
(after Anders Celsius, 1701-1744).
• Fahrenheit scale is based on the freezing point of water as 0° F and the boiling
point of water as 212°F at 1 standard atmospheric pressure. This scale is used
for English system of measurement.
• Celsius scale is based on the freezing point of water as 0°C and the boiling point
of water as 100 ° C at 1 standard atmospheric pressure. This scale is used in the
Metric and SI systems of measurement.
LESSE> ·BA
Required:
a)
b} T
Conv r ion of O
t °C Solution:
Eq. 1.12 L
tc (t, -3 .)
-
a. F
c n rsion of °C to 0
Eq.1.13
■ Absolute temperature in K
Eq. 1.14
■ Absolute temperature in R
Eq.1.15
Ex. 1.24] Fahrenheit and Celsius thermometers are both immersed in a fluid and indicate
identical numerical readings.
a) What is the temperature of the fluid expressed as R and K?
b) What is the fluid temperature if the Fahrenheit reading is numerically twice
that of Celsius reading? (Problem by Faires)
Th
lh I u, ,,, 1/1
t111 II I I I I/ I 'I It' I I It,, I
1uti
n: I I 1,
L t
1• u lln ,
'11 It , II lln I
a. For th flui
dt n I t111, It I
t1 • I I
Using Eq. 1.
12, t
( t, ),
9 Re "' 5 Re
- ( ),
4 1
:-4
Re == 160 ==
-40°C ::::
Therefore, the
fluid temp
erature Is
TK = -40 +
273 == 233K
TR =
-40 + 460::: 42 ans.
0R
b. For the fluid ans.
temperature
if RF == 2R .
e
-Re == -160, ➔ R
e == 160°C
Therefore, tC = 160° C
ans.
tF = RF = 2R = 2(16
C 0) = 320°F
ans.
Ah >I 1t Z r
Uifi d:
Solution:
A H= 500-4(373) = -992 °H
a n s.