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Formelsamling Termodynamik
Formelsamling Termodynamik
Q mc ∆T
= ( heat required to change temperature of a certain mass )
Q nC ∆T
= ( heat required to change temperature of a certain number of moles )
dQ T −T
=
H = kA H C ( heat current in conduction)
dt L
𝐴𝐴(𝑇𝑇𝐻𝐻 −𝑇𝑇𝐶𝐶 )
𝐻𝐻 = (heat current in conduction)
𝑅𝑅
𝐿𝐿
𝑅𝑅 = 𝑘𝑘 (relationship between thermal resistance and thermal conductivity)
H net Aeσ (T 4 − Ts 4 )
= (net heat current in radiation)
𝑎𝑎 𝑛𝑛2
�𝑝𝑝 + 𝑉𝑉 2
� (𝑉𝑉 − 𝑛𝑛 𝑏𝑏) = 𝑛𝑛 𝑅𝑅 𝑇𝑇 (van der Waals’ equation)
𝑚𝑚 𝑣𝑣 2 𝑝𝑝2
𝐸𝐸𝑘𝑘𝑘𝑘𝑘𝑘 = = 2𝑚𝑚 (kinetic energy)
2
𝑝𝑝 = 𝑚𝑚 𝑣𝑣 (momentum)
𝐸𝐸𝑝𝑝𝑝𝑝𝑝𝑝 = 𝑚𝑚 𝑔𝑔 ℎ (potential energy near the earth’s surface)
𝑊𝑊 = 𝐹𝐹 𝑠𝑠 (work)
K tr = 3 nRT
2
( average translational kinetic energy of an ideal gas )
1
2
m (υ )
2
av = 3 kT
2
( average translational kinetic energy of a gas molecule )
3kT 3RT
υrms
= (υ=
) 2
av =
m M
( root-mean-square speed of a gas molecule )
CV = 3 R
2
( ideal gas of point particles )
CV = 5 R
2
( diatomic gas, including rotation )
V2
W = ∫ pdV
V1
( work done in a volume change)
= dQ − dW
dU ( first law of thermodynamics, infinitesimal process)
𝑑𝑑𝑑𝑑 = 𝑛𝑛 𝐶𝐶𝑉𝑉 𝑑𝑑𝑑𝑑 (change of inner energy and temperature for ideal gas, all processes)
C=
p CV + R ( molar heat capacities of an ideal gas)
Cp
γ= ( ratio of heat capacities)
CV
QC QC
=
K = ( coefficient of performance of a refrigerator )
W QH − QC
TC TH − TC
1
eCarnot =− = ( efficiency of a Carnot engine)
TH TH
TC
K Carnot = ( coefficient of performance of a Carnot refrigerator )
TH − TC
2 dQ
∆S =∫ ( entropy change in a reversible process)
1 T
Error Propagation:
example: z = x – y + w; Δz = Δx + Δy + Δw