Conceptos Basicos Cronocoulom - PDF - Physics - Electromagnetism

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chronocoulometry
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Electrochemical - Cottrell
Analytical Electrochemistry: The Basic Concepts jayapandis83
b) Chronocoulometry

In a chronocoulometry experiment, the total charge (Q) that passes during the time
following a potential step is measured as a function of time. Q is obtained by integrating the
current, i, during the potential step. For a well behaved system (diffusion only), the charge
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observed following a potential step to a point significantly more negative (for a reduction) of the
Física Electromagnetismo
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0
E ’ is described by the integrated Cottrell equation, known as the Anson equation

1/ 2
2 n F A C0 D0 t1/ 2 Química Física
Q d = 1/ 2

π
The double potential step chronocoulometry experiment is illustrated in Figure 12 for a Física Aplicada e Interdiscipli…
diffusion-only redox system. Potential step programs in chronocoulometry are identical to those
used in chronoamperometry. The most obvious advantage of recording charge rather than
current is that Q increases with time following a potential step, reaching a maximum at the end
of the step, where the most meaningful experimental data generally is observed.
Figure 12 Documento 9 páginas
1408.7043
Farid Ahmad
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Signal-to-noise improvements also result as the integration of the current signal tends to graciousparul
“smooth” the random noise contained in the signal. Hence, chronocoulometry is preferred over Aún no hay calificaciones
chronoamperometry for the measurement of electrode area (A) and diffusion coefficients (D).
The enhanced signal observed in chronocoulometry also makes it the better technique for
measurement of the kinetics of chemical reactions following electron transfer. In the double
E Kapazitaeten
TalalJavaid1

potential step experiment illustrated in the previous figure, the reduced form of the redox couple
still in the vicinity of the electrode following the forward step can be re-oxidized to the original
material during the reverse potential step. As was the case in chronoamperometry, the signal Addition and Subtraction of
observed in the reverse step is less than that seen in the forward step. The charge for a
chemically and electrochemically reversible species on the reverse step is given by Charges
Sahil Sethi
2 n F A C0 D0
1/ 2
Q r = [τ 1/ 2
+ ( t − τ)
1/ 2
−t
1/ 2
]
π1/ 2
The values for charge measured at a time equal to τ/2 after each step (designated Q r and Q f in
the Figure 13) for such a system would yield a charge ratio [Qr (2τ) / Q f (τ)] equal to 0.414. Documento 19 páginas
Chemical reactions coupled to the electron transfer will cause this ratio to deviate from the
theoretical value. For example, if the reduced form of the species produced by the forward L02 Coulomb Post
k
potential step decays to an electro-inactive species (Red 
→ P), the charge observed on the
Joi Lynn Marie Jover
reverse potential step (Q r,2 , in Figure 13, at right ) will be smaller than that for the
Está leyendo una previsualización
uncomplicated case. Values for k, the homogeneous rate constant for the follow-up reaction, Aún no hay calificaciones
can be obtained using working curves derived for varying values of τ.
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Figure 13
Cargue para descargar

O 1-s2.0-0168900290904429-
Qr Qr,2 main
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Q f Aún no hay calificaciones
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As was the case in chronoamperometry, a change in the applied potential of the working shirtquitters
electrode will always be accompanied by a rearrangement of the ions in the double layer, leading
to a contribution to the signal from capacitive current. Since the current is integrated over time Aún no hay calificaciones
in chronocoulometry, the charge due to the capacitive current will still be part of the total at the
end of the step. The fact that it takes a very short amount of time after the potential step to
charge the double layer does, however, allow the user to easily distinguish between the double
layer charge, Qc , and the charge due to diffusion, Qd . If the total charge for the forward step, Qf ,
1/2
equal to (Q d + Q c ), is plotted as a function of t , a straight line is obtained for a kinetically
A General Population
Analysis Preserving the…
Aria Koletsi

1/2
uncomplicated system with an intercept equal to Qc , and a slope of ( 2 n F A C 0 D 01/ 2 / π ). This Documento 85 páginas
is due to the double layer charging being essentially “instantaneous” following the potential step
while the charge arising from diffusion requires time for the electroactive component to reach the
C4
electrode surface and react. Zaharudin Abu Bakar
Perhaps the most important application of the chronocoulometric technique is the
determination of surface concentrations of adsorbed electroactive species, designated Γ 0 . Aún no hay calificaciones
Following a forward potential step of sufficient magnitude, electroactive material that is
adsorbed to the surface is instantaneously electrolyzed. The charge resulting from this reaction,
Q ads , being faradaic in nature is given by
Q ads = n F A Γ 0
2
with Γ 0 having units of mol/cm and other variables their usual meaning. The total charge
observed (forward step) is now given by Castro, Domingo, Ofina
1/ 2
Qt = Q d + Q ads + Qc =
2 n F A C0 D

0
t1/ 2
+ n F A Γ0 + Qc Written Report
1/ 2
π
Está leyendo una previsualización
When adsorbed materials are present, the intercept of the Anson plot becomes the sum of Qads
Marc Castro
and Qc . While it is possible to ascertain a value for Qc , and thus Q ads , by running a “blank” Aún no hay calificaciones
Cargue
electrolyte-only experiment, thesesus documentos
measurements cannot para descargar
accurately account for changes brought
about by adsorption. A more suitable method for the determination of Qads involves double-
potential step chroncoulometry.
1/2

Cargue para descargar
Anson plots are prepared for both the forward and reverse potential steps, with Qf vs. t
being plotted for the forward step and Qr vs [ τ1/ 2 + ( t − τ )1/ 2 − t1/ 2 ] for the reverse. For the case Documento 14 páginas
where the original material (Ox in this example) is adsorbed but the electrode product (Red) is
1-s2.0-002207289185167N-
O directly yields Qads .
not, the difference in the intercepts of the two plots
Figure 14 shows Anson plots for the forward potential step for a non-adsorbed analyte main
(left) and for a double-potential step experiment involving a pre-adsorbed material (right).
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Figure 14 descargar documentos completos. Aún no hay calificaciones
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t1/2días
, ms
Qf Qf
C Documento 13 páginas

µ
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Lecture 20
a r Qads = nFAΓ0
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Qc Qr Aún no hay calificaciones

0
0 t1/2, ms 0 1/ 2 1/ 2 1/ 2
τ + ( t − τ ) − t
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Figure 12 Documento 9 páginas

Cargue para descargar

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C Documento 13 páginas

Qc Qr Aún no hay calificaciones

PHYS1231 solutions Set

En cualquier momento. En cualquier lugar. Cualquier Physics Equations

Sin compromisos. Cancele cuando quiera.

Elect. Charges and Field

APhO2015 Theo Prob1

Paper Cigre - Fast Reactor

lecture 2-e-force field

Electrostatic for Murni

Practical Exam C++

Cavity Meas Byrd

Fluid mechanics Lecture

Studies on the influence of

Libro electrónico 337 páginas

Libro electrónico 304 páginas

Libro electrónico 138 páginas

Libro electrónico 337 páginas

Libro electrónico 124 páginas

Acerca de Ayuda Legal Social Obtén nuestras

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