The Vivekanand School

Shiv Mandir Colony, Narela Delhi-110040

Annual exam
Name: -______________________ Date: - / /2023
Class: -XI______ Time: -3:00 hr
Subject – chemistry M.M: - 70

General Instructions: Read the following instructions carefully.

a) There are 35 questions in this question paper with internal choice.
b) SECTION A consists of 18 multiple-choice questions carrying 1 mark each.
c) SECTION B consists of 7 very short answer questions carrying 2 marks each.
d) SECTION C consists of 5 short answer questions carrying 3 marks each.
e) SECTION D consists of 2 case- based questions carrying 4 marks each.
f) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) All questions are compulsory.
h) Use of log tables and calculators is not allowed
SECTION-A
1. The total number of electrons present in 1.6 g of CH4 are
(a) 6.022 × 1023 electrons (b) 6.022 x1024elecrons
(c) 10 electrons (d) 6.022 x 1025 electrons
2. Which of the following coloured light has highest frequency?
(a) Red (b) Green (c) Violet (d) Blue
3. What must be velocity of electron if its wavelength is 100 Å?
[m=9.1 x 10-31 kg, h=6.63 x 10 34Js]
(a) 7.28 x 104 ms¹ (b) 7.28 x 105 m s s-1
(c) 7.26 x 10° ms¹ (d) 7.25 × 103 m s¹
4. Which of the following statements are correct?
1. Helium has the highest first ionization enthalpy in the periodic table.
II. Chlorine has less negative electron gain enthalpy than fluorine.
III. Mercury and bromine are liquids at room temperature.
iv.In any period, atomic radius of alkali metal is the highest.
(a) I and II (b) II and III
(c) I and III (d) III and IV
5. The number of radial nodes in 3p orbitals are
(a) 0 (b) 1 (c) 2 (d) 3
6. Lyman series belong to
(a) UV region (b) IR region (c) Visible region (d) None of these
7. Which element has highest electron gain enthalpy among halogens?
(a) F (b) Cl (c) Br (d) T
Or
Which of the following has highest electronegativity?
(a) O (b) F (c) CI (d) N
8. What is mass of 5.6 moles of S8 molecules? [S= 32 u]
(a) 1.5 g (b) 1.43 Kg (c) 1.80 g (d) 3.2 g
Or
The mass of 1 mole of electrons is equal to
(a) 9.1 x 10 x 6.022 × 1023 g (b) 9.1 x 10 x 6.022 × 1023 kg
(c) 1 g (d) 9.1 x 10-31 kg
9. 2KCIO3----------- 2KCI + 302 which of the following statements is/are not true?
(a) It is decomposition redox reaction. (b) Cl5+ gaining 6 electrons to form Cl-.
(c) O2- is losing electrons to form O₂ (d) It is not a redox reaction
10. The hydrocarbon (C2H6) which gives one monochloro product on
photochlorination.
(a) Pentane (b) Cyclopentane (c) Pent-1-ene (d) Pent-2-ene
In the following questions (Q. No. 14-18), a statement of assertion followed by a
statement of reason is given. Choose the correct answer out of the following choices.
11. Assertion: KMnO4 reacts with oxalic acid in acidic medium is redox reaction.
Reason: KMnO4 get reduced to Mn+2 and oxalic acid get oxidized to CO2.
12. Assertion: The third ionization energy of Mn is very high.
Reason: After losing 2 electrons Mn has 3d (half field d-orbitals) which is more stable.
13. Assertion: Neon has smaller atomic size than fluorine.
Reason: In noble gases one can measure only van der Waals' radii which are bigger than
covalent radii.
14. Assertion: (HCO 3-) is conjugate acid of CO3-2 .
Reason: Acids are those substance which donate proton.
15. Assertion: 3 0 free radical is more stable than 10free radical.
Reason: 30 free radical is stabilized by resonance.
Or
Assertion: Nitration of benzene is electrophilic substitution reaction.
Reason:NO2- is a nucleophile.
16. (iv) Decrease in Gibb's free energy is measure of
(a) Total work (b) Useful work (c) Work of expansion (d) All of these
Or
CaCO3(s) = CaO(s)+ CO2(g), which of following is correct
(a) Heterogeneous equilibrium (b) Kp = pCO2
(c) Kp=Kc (RT) (d) All of these
17. The equilibrium constant for the reaction
N2 (g) + 3H2 (g) ⇌ 2NH3-(g) is K. How is the equilibrium constant for the reaction
NH3 (g) ⇌ 1/2N2 (g) + 3/2 H2 (g) related to K?
(a) K2 (b) K1/2 (c) 2K (d) K1/2
18. The amount of the heat released when 20 ml 0.5 M NaOH is mixed with 100
ml 0.1 M HCl is x kJ. The heat of neutralization is
(a) -100 × kJ/mol (b) -50 × kJ/mol
(c) 100 × KJ/mol (d) 50 × kJ/mol
SECTION-B
19. (1) An element has atomic number 117. To which group and period does it belong?
(ii) Write the general formula of f block element. What is common name of element
belong to this group Or
 (i) To which series do man-made elements belong?
(ii) Which of the Lanthanoids is man-made element?
20. (i) Arrange the following in order of increasing oxidation number of Mn:
MnCl2, MnO2, Mn(OH)3, KMnO4
(ii) What is What is the oxidation number of Fe in Na4[Fe(CN)6]?
21. Determine the molecular formula of an oxide of iron, in which the mass per cent of
iron and oxygen are 69.9 and 30.1 respectively.
22. Describe the effect of:
(i) addition of H₂ (ii) addition of CH3OH
(iii) removal of CO (iv) removal of CH3OH on the equilibrium of the
reaction
2H2(g) + CO(g)-------CH3OH(g)
Or
Write an expression of Kc for the following reaction:
CaCO3(s) –------ CaO(s) +CO2(g)
What is the effect of increasing concentration of CO2 on direction of reaction?
23. Convert:
(i) Propyne to 2-Propanol. (ii) Acetylene to 1, 1-Dichloroethane
Or
Write the name of

ii.Draw the structures of Dicyclopropyl methane.

24. (i) A photon of wave length 4 × 10-7 m strikes on metal surface, the work
function of the metal being 2.13 eV.
Calculate
(i) the energy of the photon (eV)
(ii)  the kinetic energy of the emission 
25. 27. 27. Which is more stable and why?
(i) C6H5-CH₂+ or C6H11-CH₂+
(ii) (C6H5)2 CH₂* or C6H5-CH₂*
(iii) C6H5-CH2* or CH2=CH-CH*₂
SECTION-C
26. Balance the following reaction
 MnO4–(aq) +I–(aq) ———>Mn02(s) + I2 (s) (in basic medium)
27.i. What are electrophiles and nucleophiles? Explain with examples:
ii. Explain the terms inductive effects. OR Hyper conjunction.
OR
i. Which electron displacement effect explain the following correct orders of acidity of
the carboxylic acids?
(a) Cl3CCOOH > Cl2CHCOOH > ClCH2 COOH
(b) CH3CH2COOH > (CH3)2 CHCOOH > (CH3)3CCOOH
ii. Show the movement of electrons by curved arrows in CH6H5NH2
28. (1) State Heisenberg's uncertainty principle.
(ii) Calculate the uncertainty in the position of an electron if uncertainty in its velocity
is 0.001%. [m=9.1x10-31 kg, C-300 ms, h=6.63 × 10-34 Js]
Or
Calculate the uncertainty in the position of a dust particle with mass equal to 1 mg if the
uncertainty in velocity is 5.5 x 10-20 ms-1. (h=6.626 × 10-34 Js)
29. complete the following reaction
i.

30.i. Define common ion effect. 

ii. The solubility of AgCl in water at 298 K is 1.06 x 10-5 mole per litre. Calculate
its solubility product at this temperature.
SECTION -D
31. Read the page given below and answer the following questions
Thermodynamics deals with energy changes in chemical reactions and other processes
The energy of an isolated system remain constant according to first law of
thermodynamics. Internal energy change and enthalpy change are state functions
whereas and ‘q and w are path functions. We can measure the transfer of heat on one
system to another which causes change is temperature. The magnitude of rise or fall in
temperature depends upon heat capacity of a system. Heat transfer at constant volume is
called ΔU (internal energy change) whereas at constant pressure is called ΔH (enthalpy
changes). Entropy is measure of degree of randomness or disorder. Free energy is
measure of useful work done by the systems. The process is spontaneous if it leads to
decrease in free energy. Gases can be liquefied at low temperature and high pressure.
Volatile liquids have high vapour pressure. Drops of liquids are spherical in shape.
(i) Which of the following is an intensive property?
(a) Mass (b) Volume (c) Density (d) All of these
(ii) Which of the following is state function?
(a) q (b) w (c) q+w (d) All of these
(iii) Name the system which does not exchange matter
but exchange energy with the surrounding?
(a) Open system (b) Closed system (c) Isolated system (d) All of these
(iv) ΔHvap for water at 373 K is 40.66 kJ mol, calculate ΔU at 373 K in kJ mol-1
(R-8.314 JK-1mol-1) H2O (l)------------- H2O (g)
(a) -37.56 kJ (b) +37.56 kJ (c) 44.0 kJ (d) 40.66 kJ mol
Or
What is sign of ΔH and ΔS for the reaction which is spontaneous at all temperature?
(a) AH=+ve, AS=-ve (b) AH=-ve, AS = +ve
(c) AH = +ve, AS = +ve (d) AH=-ve, AS = -ve
32. Read the passage given below and answer the following questions:
The formation of positive and negative ions from neutral atom depends upon ease of
formation of these ions. The arrangement of the positive and negative ions in the solid
is called crystal lattice in crystalline compounds. Formation of positive ion needs
ionization enthalpy (endothermic) and formation of negative ions is associated with
electron gain enthalpy (exothermic). Ionic bonds will be formed between atoms of low
ionization enthalpy and high electron gain enthalpy. Most of ionic compound have
cations derived from metallic elements and anions from non-metallic elements except
NH4+ is an exception. Ionic compounds in the crystalline forms has 3-D orderly
arrangement of cations and anions, e.g. NaCl has rock salt structure. In ionic solid,
stability is provided by its enthalpy of lattice formation and not by achieving octet of
electrons. Lattice enthalpy is defined as energy required to completely separate one
mole of solid ionic compound into gaseous constituting ions. Coordinate bond is formed
by unequal sharing of electrons. Pair of electrons belong to one of the atom but shared
by both. It is denoted by starting from donor atom ending at acceptor atom. It is
also called dative bond.
(1) The type of bonds present in NH4CI is/are
(a) Ionic (b) Covalent (c) Coordinate (d) All of these
(ii) Which of the following has highest lattice enthalpy?
(a) NaCl (b) KCI (c) MgO (d) NaBr
(iii) X -+ e- X-2, this process is
(a) exothermic (b) endothermic (c) highly exothermic (d) none of these
(iv) Which of the following is most ionic?
(a) Lil (b) NaCl (c) CsF (d) KBr
Or
Which of the following has coordinate bond?
(a) H3O+ (b) NH4+ (c) BF-4 (d) All of these
SECTION-E
33.i. Draw the cis- and trans-structures for hex-2-ene. Which iosmer will have higher
boiling point and why?
ii. Which conformation of ethane has the lowest potential energy?and why?
(a) Eclipsed (b) Skewed (c) Staggered
iii. An alkene ‘A’ contains three C—C, eight C—H, a-bonds, and one C—C n-bond.
‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the
IUPAC name of’A’.
30.i. Why is benzene extra-ordinarily stable though it contains three double bonds?
ii.Explain why the following systems are not aromatic?
 iii. Describe Friedel’s craft reaction with suitable examples.
Or
i. What is Huckel rule?
ii. . How will you convert benzene into (i)p-nitro bromobenzene (ii) m-nitro
chlorobenzene (iii) p-nitrotoluene (iv) acetophenone?
34. i. Define Hess’s Law of Constant Heat Summation.
ii. Calculate the maximum work obtained when 0.75 mol of an ideal gas expands
isothermally and reversible at 27°C from a volume of 15 L to 25 L.
iii. Calculate the standard enthalpy of formation of CH3OH. from the following data:
(i) CH3OH(l) + 3/2 02 (g) ———-> CO2 (g) + 2H20 (l); ∆rH– = – 726kj mol-1
(ii) C(s) + 02(g) —————> C02 (g); ∆cH– = -393 kj mol-1
(iii) H2(g) + 1/202(g) —————-> H20 (l); ∆fH– = -286 kj mol-1
35. i. What will be the conjugate bases for the Bronsted acids? HF, H2S04 and
H2C03?
ii.  The pH of a sample of vinegar is 3.76. Calculate the concentration of
hydrogen ion in it.
iii. The value of Kc for the reaction  302(g) —>203(g)
is 2.0 x 10-50 at 25°C. If equilibrium concentration of 02 in air at 25°C is 1.6 x
10-2, what is the concentration of O3?
OR
(i). Out of diamond and graphite, which has greater entropy?
ii. What is the enthalpy change for an adiabatic process?
iii