10,2 Data =

P-x-y diagram T= 90 °C
t-x-y diagram P= 90 kPa
a) Benzene(1)/ethylbenzene(2)
b) 1-Chlorobutane(1)/chlorobenzene(2)

a) Antoine coef. Benzene = 1 ; Ethylbenzene = 2

A1 = 13.7819 B1 = 2726.81 C1 = 217.572
A2 = 13.9726 B2 = 3259.91 C2 = 212.3

Bulp P 140
B
Psat = exp(A - )
T(°C) + C
120
P1 sat = 136.50
P2 sat = 24.26
100
P = P2sat+(P1sat-P2sat)x1
asumsi = x1 = 0.3
P/kPa

P= 57.93 80

x1*P1sat
y1 = 60
P
y1 = 0.71
40
x1 y1 P (kPa)
0 0.00 24.26
0.3 0.71 57.93 20
0 0.5 1
1 1.00 136.50
x1-y1

B1
Tsat = (-C
A1-lnP 135
T1sat = 76.20
T2sat = 131.83
125

T-T2sat
x1 =
T1sat-T2sat 115
x1 = 0.8

x1.T1sat
T (°C)

105
y1 =
T
y1 = 0.6
95

T = T2sat+(T1sat-T2sat)x1
T= 90 °C 85

x1 y1 T (°C) 75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0 0 131.83
x1-y1
 75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5 0.42 104.02 x1-y1

1 1.00 76.20
x1
0
0.1
b) Antoine coef. 0.2
1-Chlorobutane = 1 Chlorobenzene = 2 0.3
A1 = 13.7965 A2 = 13.8635 1
B1 = 2723.73 B2 = 3174.78
C1 = 218.265 C2 = 211.7

B 150
Psat = exp(A - )
T(°C) + C
P1 sat = 142.71
P2 sat = 28.23
125

P = P2sat+(P1sat-P2sat)x1
asumsi = x1 = 0.2
P= 51.13 100 x1
0
P/kPa

x1*P1sat 0.1
y1 =
P 75 0.2
y1 = 0.56 0.3
0.4
x1 y1 P (kPa) 0.5
50
0 0.00 28.23 0.6
0.2 0.56 51.13 0.7
1 1.00 142.71 0.8
25 1
0 0.5 1
B1
Tsat = (-C x-y1
A1-lnP
T1sat = 74.71
T2sat = 127.35
130
T-T2sat
x1 =
T1sat-T2sat
x1 = 0.7 120

x1.T1sat 110
y1 =
T
y1 = 0.6
100
T (°C)

T = T2sat+(T1sat-T2sat)x1
T= 90 °C 90

x1 y1 T (°C) 80
0 0 127.352
0.5 0.42 101.033
70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1-y1
 80

70
1 1.00 74.713 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1-y1
x1 y1 P (kPa) 140
0 0.00 24.26 130
0.1 0.24 35.49 120
0.2 0.47 46.71 110
0.3 0.71 57.93 100
0.4 0.94 69.16
90
1 1.00 136.50
80
70
60
50
40
30
20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1 y1 T (°C) 135
0 0 131.83 130
0.1 0.08 126.27
125
0.2 0.17 120.71
0.3 0.25 115.14 120

0.4 0.34 109.58 115

0.5 0.42 104.02 110
0.6 0.51 98.45
105
0.7 0.59 92.89
0.8 0.68 87.33 100
0.9 0.76 81.76 95
1 1.00 76.20
90

85

80

75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 y1 P (kPa) 150
0.00 28.23 140
0.28 39.68 130
0.56 51.13 120
0.84 62.58 110
1.00 142.71 100
90
80
70
60
50
40
30
20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

y1 T (°C) 130
0 127.352
0.083015 122.088 120
0.16603 116.824
0.249045 111.561 110
0.33206 106.297
0.415075 101.033 100
0.49809 95.769
0.581105 90.505 90
0.66412 85.241
1.00 74.713 80

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1