ZIMBABWE SCHOOL EXAMINATIONS COUNCIL General Certificate of Education Advanced Level CHEMISTRY 9189/3 PAPER3 Multiple Choice JUNE 2011 SESSION 1 hour Additional materials: Data Booklet Mathematical tables andor calculator ‘Multiple Choice answer sheet Sof clean eraser Soft pencit (type B or HB is recommended) TIME 1 hour INSTRUCTIONS TO CANDIDATES Do not open this booklet until you are told to do so, Write your name, Centre number and candidate number on the answer sheet in the spaces provided unless this has already been done for you. There are forty questions in this paper. Answer all questions. For each question, there are four possible answers, A, B,C and D. Choose the one you consider correct and record your choice in oft pencil on the separate answer sheet. Read very carefully the instructions on the answer sheet. INFORMATION FOR CANDIDATES Each correct answer will score one mark, A mark will not be deducted for a wrong answer Any rough working should be done in this booklet, — This question paper consists of 15 printed Pages and 1 blank page. Copyright: Zimbabwe School Examinations Council, J201 1 eziMsec nou [Turn over /Section A For each question there are four possible answers, A, B, Cand D. Choose the one ou consider 10 be correct. 1 Ina sample of nitrogen gas containing ''N and '"N, the mass spectrum may show peaks corresponding to ions with masses A 28; 28.5; 30. B28; 29; 30. C 26; 28; 30. D 26; 28; 29. 2 A sample of 0.05 mol of the chloride of an clement X was dissolved in distilled water and the solution was made up tol dm’, 12.5 em’ of this reacted with 25 em’ of 0.1 mol dm~ AgNO3ic ‘What is the formula of the chloride? A X,CI BE XCh Cc XC D xc 3 Atoms X and ¥ have the following configurations: x 2p* 38° 3p* 3d" 4s? ap! A B Cc D 4 The molecules listed below are of general formula XY, with n= 2. In which molecule is Y - X- Y angle greatest? A CHy B NH c BF; D PCh 918915 22011Which statement explains why aluminium metal conducts heat? A The erystal lattice breaks down on applying heat. B The atoms of aluminium become ionised when heated. C The heat causes the electrons of aluminium to become delocalised. D The heat energy is transferred from one atom to the next by the mobile electrons, Under what conditions of temperature and pressure will a real gas behave most like an ideal gas? Temperature Pressure A low low Blow high C high low D high high Which factor affects the solubility product, Ky, of silver sulphide, AgsS, when it is precipited by passing HS) into aqueous silver nitrate? 2AENOxiaq) + HaSiq) ==Ag2S,) + ZHNO aq) changing pressure of hydrogen sulphide an increase in temperature the presence of excess acid the addition of aqueous silver nitrate come ‘The standard enthalpy changes for two reactions are given by the equations 2Fey, + 30., > FeO, AH’ = -822 kImol™ So CO, AH" = 7 110 kImol™ L +50 2 What is the standard enthalpy change for the reaction. Fe:Oxyg) + 3C yy > 2Feyg) + 3CO |? A +712 kimot* B +492 kImol™ C 492 kJmol D — -932 kJmol 9188832011 [Turn over10 u 12 ‘Which compound has the greatest magnitude of lattice energy? A LiF B Lil Cc Rb D NaCl ‘A current of 4 amperes is passed for SO minutes through molten aluminium oxide using inert electrodes. ‘What will be the volume of gas liberated measured at standard temperature and pressure? A 0.7dm° B 14 dm Cc 21dm* D = 22.4dm' ‘The use of the Data Booklet is relevant to this question. In acidic solution, MnO ; oxidises CI” to Which fact is correct about the reaction? A Oxidation number of chlorine changes from -1 to +2 B 2MnO; + 2CI” > 2MnOF + Ch, © 2MnO; + 8H" + 6CI” > 2MnO; + 4H,0 + 3C. D —-2MnO; + 16H" + 10CT- ~> 2Mn”* + 8H,O + 5Chr The alkaline hydrolysis of RBr, where R= (CHs)s, proceeds as follows: RBr-> R* + Br’, slow "+ OH" ROH, fast Which rate equation is consistent with this mechanism? A rate=k[OH™] Brate=K[RBr] C rate=k(RBr] [OH™] D —rate=k[R"] [OH"] 91893 201113 4 16 In an acid-base titration, 0.1 mol dm” solution of a base is titrated against 25 em’ of 0.1 mol dm™ ofan acid. The pH value is plotted against volume, V, of the base added as, shown, 10 pH at end point 5 1 Vien Which acid-base pair would give the titration curve shown above? A HpSOsaq) and NHya5) B HChug) and NH (aq) C€ — CH;COOH and KOH aq) DCH ,COOHyaq) and NH) Why is aluminium resistant to corrosion? A oxide layer is thiok B oxide layer is non porous C oxide layer is amphoteric D it does not readily react with water Which halide is a volatile liquid which is readily hydrolysed by water? A AICI; BB PCls Cc PbCh DD SnChy When copper is reacted with concentrated nitric acid to give a blue solution and a brown, acidic gas, the changes in oxidation numbers are Copper Nitrogen Aol 2 Bo2 1 Cre 2 D2 3 91898 011 [Turn over17 18 19 20 6 ‘The substance present in exhaust fumes of a car engine and contributes to acid rain formation is A Nz. BNO. c CO. D PbO. ‘The diagrams show structures of an clement, its oxide and halide. I My Nig oe @ clement ® halogen © oxygen © element element What could the element be? A silicon B lead C carbon D tin Which substances will not produce hydrogen when reacted together? copper and concentrated nitric acid ethanol and sodium magnesium and steam phenol and sodium vamp Consider the following four compounds 1 (CHs)sCH 2 CHsCHjCH;0H 3. CH)CH)CH:SH 4 CHsCH)CH,CHs ‘What is the correct order of decreasing boiling points of the compounds? Aol 4 3 2 (jo ee ZI 1 c 3 2 4 1 dD 4 1 2 3 91898 120111 21 Which amino acid contains three chiral carbons? A H.NCHCO,H B_H,NCHCO,H “| CHCH, ‘i Lo re cu, cH, c ANH D ied r r CH,OH CH, 88 J2012 (Turn over8 22 Aerosols may contain the local anaesthetic benzocaine, which eases the pain of wasp stings mu —-O—Z benzocaine Which substance(s) is/are formed when benzocaine is refluxed with dilute HCi(aq)? ° a B HN © c and CH,CH,OH ou O— CH,CH, oO ae a cc HN —{O)—c So—ci,cx, 0 D HN c and CH,CH,OH —©)— NS —H 91896 201123 24 25 9 The diagram represents part of the structure of terylene. oO Oo ll I eT O—CH,CHO — c—O)— c—o + n What type of reaction is involved in its formation? A electrophilic addition B_ electrophilic substitution C free radical substitution D condensation reaction The diagram shows the structure of compound X. cl cL F A portion of compound X is added to aqueous NaOH. How many halogens will be removed by hydrolysis? A 0 Bo2 c 3 Dias Which substance reacts with trichloroethene to give a chiral product? A Th Bo Br c Hc D NaOH sass non (Turn over26 27 28 29 10 Phenol is widely used in hospitals to disinfect especially against tuberculosis bacteria, however, it cannot be used on skin because itis irritating, A better skin germicide can be made by reacting phenol with aqueous chlorine, ‘What would be the formula of the germicide? a ocl 7 © ® © OH c OH ci Cc D ‘cl a ‘Whaat is the product of reacting phenyl methanol, CcHsCH1,OH, and ethanoyl chloride, CH:Cocr? A C6HsCH:COCI B CgHsCH,O0COCH; C — GyllsCOcr D —C«HsOCOCH; An organic compound X, gives an orange crystalline product with 2,4-dinitrophenyl- hydrazine but does not give a precipitate on boiling with Fehling’s solution (alkaline Which of the compounds could be X? A CH;CHO Bo CsHsCH2CHO C — CH;COCH; D —CH;CH,CO:H What is the organic product formed when ethanamide, CHsCO2NHb, is boiled with an excess of aqueous sodium hydroxide? A CH,CO;NH; B CHsCONH; C CH;COOH D —_CH,CO;Na* 91899 01130 iL What type of organic compounds are commonly used to provide artificial flavourings in sweets? A carboxylic acids B ketones C esters D acyl chlorides 91899 22011 [Turn over12 Section B For each of the questions in this section, one or more of the three numbered statements I to 3 may be correct. Decide whether each of the statements is or is not correct. (You may find it helpfidl to put a tick against the statement(s) which you consider to be correct). ‘The responses A to D should be selected on the basis of A B c D L2and3| 1and2 2and3 Lonly are only are | onlyare | is correct correct correct correct No other combination of statements is used as a correct response 31 The graph below represents relative radii of the species shown. radius/nm| py os cr Ar Kt What would be the correct explanation for the change in radii? 1, The nuclear charge is increasing from P*~ to K’. 2 ‘The attraction for the electrons becomes stronger from P? to K*. 3. The outermost electrons are further away from the nucleus from P*- to K*, 91898 201132 13 The graph below shows Boltzman distribution of molecular speeds in a gas sample. no of molecules speed Which statement(s) is/are correct? 1. Raising the temperature always increases the number of molecules with energy greater than activation energy. 2. The area under the curve is proportional to the number of molecules present. 3. Raising the temperature increases the spread of molecular speeds. Which statement(s) is/are true for a standard cell set up using the half cells? Nigy/Nig 3 E? =-0.25V Snji/Sn,, 3 E*=0.14V 1, electrons flow in external circuit from nickel to tin 2. the concentration of Sn**aq) will decrease 3. oxidation occurs at the nickel terminal s1e9 s20u4 [Turn over14 34 The diagram shows a reaction profile for the reaction, == B+C, AH, energy progress of reaction Which statement(s) about the reaction is/are correct? L is affected by the presence of a catalyst. 2. Itisa single step reaction, 3. Different E,’s are obtained for the forward and backward reactions. 35. Inwhich pair is sulphur in the same oxidation state in both members of the pair? 1. SFe 3 SOF 2. $02 ; HSO; 3. 36 Which statement(s) is/are true about the Haber process? I. Athigher pressures, the yield goes down. . At higher temperatures the yield goes down. 3. _ Inthe presence of a catalyst, the yield remains constant. 91896 201137 38 39 15 Which pairs of compounds have the same empirical formula? 1, cyclohexane and hexane 2. ethene and polyethene 3. cyclohexane and hex-I-ene Which statement(s) about the reaction mechanism of a reaction between an aldehyde and hydrogen cyanide catalysed by sodium cyanide is/are true? 1. Anew carbon-carbon bond is formed. 2. In the intermediate, the oxygen carries a negative charge. 3. The last stage involves formation of a hydrogen-oxy gen bond. Given the structure CH3CO (CH)sCH = CHCO-H. which statement(s) is/are true? 1. It gives a positive tri-iodomethane test 2 It can exist as cis-trans isomers. 3, Itgives a positive test with Felings solution, Which pair(s) of compounds can be distinguished by thei: ditferences in solubility? 1. ethanol and ethanoie acid 2. phenylbenzoate and sodium benzoare 3. propane and methylbenzene ‘a9 not