Reference TOTL-SP07-F02

Office Egypt
ISO / IEC 17025 Form Issue n° 00
Clause 7.2 & 7.6 Date 1-Apr-19
Selection, verification and validation of methods Author / Approver M. Saleh / M. Abd Elrazek
and measurement uncertainty

Analysis Uncertainty Calculations

Test Metod: ISO 20483 : 2013 Test Name: Crude Protein in Cereals and Pulses

Month Week Range 1 Range 2 Name P.T Results P.TActual Value Bias values
8.43 11.72 9.49 9.77 0.279999999999999
8.56 11.94 9.44 9.77 0.33
8.46 11.77
8.61 11.91
B1Sep-22 3rd week 8.51 11.86 Bahaa Eldin Mohamed

8.49 11.78
8.46 11.75
8.52 11.91
8.44 11.85
8.55 11.79 9.46 9.77 0.309999999999999
8.54 11.91 9.5 9.77 0.27
8.49 11.77
8.43 11.72
B1Oct-22 1 st week 8.51 11.86 M.A
8.47 11.91
8.55 11.89
8.45 11.77
8.62 11.90
8.51 11.86 9.5 9.77 0.27
8.49 11.78 9.45 9.77 0.32
8.46 11.75
8.52 11.91
B1Oct-22 2nd week 8.44 11.84 Bahaa Eldin Mohamed
8.55 11.78
8.54 11.91
8.49 11.77
8.43 11.72
8.51 11.86 9.44 9.77 0.33
8.47 11.92 9.46 9.77 0.31
8.55 11.89
8.46 11.72
B1Oct-22 2nd week 8.62 11.88 M.A
8.53 11.92
8.49 11.89
8.46 11.77
8.52 11.90
8.42 11.86 9.5 9.77 0.27
8.58 11.78 9.45 9.77 0.32
8.46 11.75
B1Oct-22 3rd week 8.62 11.91 Bahaa Eldin Mohamed
8.51 11.84
8.49 11.79
8.49 11.91
8.52 11.76
8.44 11.72 9.46 9.77 0.309999999999999
8.55 11.86 9.5 9.77 0.27
8.53 11.92
B1Oct-22 4th week 8.49 11.86 M.A
8.43 11.78
8.51 11.75
8.47 11.91
8.39 11.74
Mean 8.5005769231 11.831153846 9.47083333333 9.77 0.33
SD 0.0541390172 0.0709502407 0.02503028469 0.0250302846870577
SD^2 0.0029310332 0.0050339367 0.00062651515
RSD 0.0063688639 0.0059968995 0.00264288092 0.0026428809172432
RSD % 0.6368863864 0.5996899508 0.26428809172 0.264288091724323
Ustd %(max) 0.6368863864
Bias 0.33
Bias % 3.3776867963
U Certificate 0.32
(U(cref))% 1.6376663255
(RSD/√n)^2 0.07629
Ubias% 3.7545358928
Uc% 3.8081706947
(U)exp 7.6163413894

((U)exp)2 58.008656159
 Reference TOTL-SP07-F02

Office Egypt
ISO / IEC 17025 Form Issue n° 00
Clause 7.2 & 7.6 Date 1-Apr-19
Selection, verification and validation of methods Author / Approver M. Saleh / M. Abd Elrazek
and measurement uncertainty
Sampling Uncertainty Calculations

Test Metod: ISO 20483 : 2013 Test Name: Crude Protein in Cereals and Pulses

Sample 1 Sample 2
Batch No. Xi11 Xi12 Di1 Xi1bar di1 Xi21 Xi22 Di2 Xi2bar di2 Di Xibar di
1 8.42 8.53 0.109999999999999 8.475 1.30 8.52 8.62 0.1 8.57 1.17 0.095 8.5225 1.11
2 8.58 8.49 0.090 8.54 1.05 8.44 8.51 0.07 8.475 0.83 0.06 8.505 0.71
3 8.46 8.43 0.030 8.45 0.36 8.55 8.49 0.06 8.52 0.70 0.075 8.4825 0.88
4 8.62 8.51 0.110 8.57 1.28 8.53 8.46 0.07 8.495 0.82 0.07 8.53 0.82
5 8.51 8.47 0.040 8.49 0.47 8.49 8.52 0.03 8.505 0.35 0.015 8.4975 0.18
6 8.49 8.55 0.060 8.52 0.70 8.43 8.42 0.01 8.425 0.12 0.095 8.4725 1.12
7 8.46 8.46 0.000 8.46 0.00 8.51 8.58 0.07 8.545 0.82 0.085 8.5025 1.00
8 8.52 8.62 0.100 8.57 1.17 8.47 8.46 0.01 8.465 0.12 0.105 8.5175 1.23
9 8.44 8.51 0.070 8.48 0.83 8.55 8.62 0.07 8.585 0.82 0.11 8.53 1.29
10 8.55 8.49 0.060 8.52 0.70 8.46 8.51 0.05 8.485 0.59 0.035 8.5025 0.41
di1bar 0.79 di2bar 0.63 dibar 0.88

di analysis bar 0.71 di measurement bar 0.88

RSD analysis 0.63 RSD measurement 0.78
(RSD analysis)2 0.40 (RSD measurement)2 0.60
(Uc)sampling 0.64
(Ue)sampling 1.27
((Ue)sampling)2 1.6182
 Reference TOTL-SP07-F02

Office Egypt
ISO / IEC 17025 Form Issue n° 00
Clause 7.2 & 7.6 Date 1-Apr-19
Selection, verification and validation of methods Author / Approver M. Saleh / M. Abd Elrazek
and measurement uncertainty
Total Measuremenet Uncertainty Calculations

Test Metod: ISO 20483 : 2013 Test Name: Crude Protein in Cereals and Pulses

Expanded Uncertainty (%Ue) 7.72

Combined Uncertainty (%Uc) 3.860921

Confidence Level is 95%

Coverage Factor (K) = 2
Name Analysis(Precision) Analysis(Bias) Sampling(Precision) (UC)Total
Value 0.636886386439445 3.75453589283497 0.64 3.86092149
Percentage 16.4957093484138 97.2445543586472 16.4738647766927

Name Analysis Sampling (Ue)Total

Value 7.61634138935959 1.27 7.72
Percentage 98.6337253647009 16.4738647766927

Total MU percentage will be not equal 100% due to the different calculations for each parameter.