NAME

DURATION : 60 MINS Date : 02 . 09. 2023

FULL MARKS : 50

INSTRUCTIONS :

 READ THE QUESTIONS CAREFULLY

 ANSWER ALL QUESTIONS

 IF UNABLE TO SOLVE A QUESTION , MOVE ON TO THE

NEXT , DO NOT WASTE TOO MUCH TIME ON IT

 IF YOU FIND YOURSELF PANICKING AND UNABLE TO

SOLVE QUESTIONS THEN ..... PRAY !
1. The structure of an organic compound, X, is shown.

H H
H H
C C
H C
H
C C
H H
C C
H H
H H

What is the molecular formula of X?

A C6H9 B C6H12 C C7H12 D C7H14

2. A compound contains one atom of calcium, two atoms of hydrogen and two atoms of oxygen.

What is the correct chemical formula of the compound?

A CaO2H2 B HOCaOH C H2CaO2 D Ca(OH)2

3. The formulae of compounds W, X and Y are shown.

W CuSO4.5H2O
X MgSO4.7H2O
Y Cu(NO3)2.6H2O

Which statement is correct?

A W contains twice as many hydrogen atoms as oxygen atoms.

B X contains the most oxygen atoms.
C Y contains the most hydrogen atoms.
D Y contains the same number of hydrogen and oxygen atoms.

4. The equation shows the reaction between magnesium and sulfuric acid.

Mg + H2SO4 → MgSO4 + H2

(Mg = 24, H = 1, S = 32, O = 16)

In this reaction, what mass of magnesium sulfate will be formed when 6 g of magnesium reacts
with excess sulfuric acid?

A 8 B 24 C 30 D 60
5. The equation for the reaction between magnesium and dilute sulfuric acid is shown.

Mg + H2SO4 → MgSO4 + H2
Mr of MgSO4 is 120

Which mass of magnesium sulfate will be formed if 12 g of magnesium are reacted with sulfuric
acid?

A 5g B 10 g C 60 g D 120 g

6. Compound X contains carbon, hydrogen and oxygen only.

By mass, it contains 26.7% carbon and 2.2% hydrogen.

What is the empirical formula of X?

A CHO B C2HO C CH2O D CHO2

7. Calcium carbonate, CaCO3, reacts with dilute hydrochloric acid to produce carbon dioxide.

The equation for the reaction is shown. The relative formula mass of calcium carbonate is 100.

CaCO3 + 2HCl  CaCl 2 + H2O + CO2

10 g of calcium carbonate is reacted with an excess of dilute hydrochloric acid.

Which mass of carbon dioxide is produced?

A 2.2 g B 2.8 g C 4.4 g D 44 g

8. The structure of an ester is shown.

H O

H C C H H H

H O C C C H

H H H

What are the names of the carboxylic acid and the alcohol that react together to form this ester?

carboxylic acid alcohol

A ethanoic acid ethanol

B ethanoic acid propan-1-ol
C propanoic acid ethanol
D propanoic acid propan-1-ol
 9. Propene, C3H6, reacts with bromine, Br2, in an addition reaction.

Which structure represents the product of this reaction?

A B C D
H H H H Br H H H H H H H

H C C C H H C C C H H C C C H Br C C C Br

Br H H H Br H Br Br H H H H

10. The equation for the reaction of sodium with water is shown.

2Na + 2H2O  2NaOH + H2

What is the volume of hydrogen gas, measured at r.t.p., produced when 18.4 g of sodium reacts
with excess water?

A 9.6 dm3 B 15.0 dm3 C 19.2 dm3 D 30.0 dm3

[total:10]
SECTION B

1. Chemists use the concept of the mole to calculate the amounts of chemicals involved in a
reaction.

(a) Define mole.

[1]

(b) 3.0 g of magnesium was added to 12.0 g of ethanoic acid.

Mg + 2CH3COOH → (CH3COO)2Mg + H2

The mass of one mole of Mg is 24 g.

The mass of one mole of CH3COOH is 60 g.

(i) Which one, magnesium or ethanoic acid, is in excess? You must show your
reasoning.

[3]

(ii) How many moles of hydrogen were formed?

[1]
 (iii) Calculate the volume of hydrogen formed, measured at r.t.p.

[2]

(c) In an experiment, 25.0 cm3 of aqueous sodium hydroxide, 0.4 mol / dm3, was neutralised
by 20.0 cm3 of aqueous oxalic acid, H2C2O4.

2NaOH + H2C2O4 → Na2C2O4 +2H2O

Calculate the concentration of the oxalic acid in mol / dm3.

(i) Calculate the number of moles of NaOH in 25.0 cm3 of 0.4 mol / dm3 solution.

[1]

(ii) Use your answer to (i) and the mole ratio in the equation to find out the number of
moles of H2C2O4 in 20 cm3 of solution.

[1]

(iii) Calculate the concentration, mol / dm3, of the aqueous oxalic acid.

[2]

[TOTAL :11]

2. Carbon is an important element.

(a) Carbon exists as the isotopes 126C and 136C.

Complete the table.

number of protons number of electrons number of neutrons

isotope
in one atom in one atom in one atom

6C
12

6C
13

[2]

(b) Name two forms of the element carbon which have giant covalent structures.

................................................................... and ................................................................... [1]

 (c) The Avogadro constant is the number of particles in 1 mole.

The numerical value of the Avogadro constant is 6.02 × 1023.

(i) Calculate the number of molecules in 22.0 g of carbon dioxide, CO2.

............................... molecules [2]

(ii) Calculate the number of molecules in 6.00 dm3 of carbon dioxide gas at room temperature
and pressure.

............................... molecules [1]

[Total: 6]

3 Lead is a metallic element in Group IV. One of the ores of lead is galena, which is an impure form
of lead(II) sulfide, PbS.

Lead also occurs in the ore cerussite, which contains lead(II) carbonate, PbCO3.

(a) Calculate the relative formula mass, Mr, of PbCO3.

Mr of PbCO3 = .............................. [1]

(b) The Mr of PbS is 239.

  C
  alculate the percentage of lead by mass in PbS.

  percentage of lead by mass in PbS = ..............................  [2]

[total: 3]
4. (a) Ethanol is a member of the homologous series of alcohols.

Give two characteristics of members of a homologous series.

1 .................................................................................................................................................

2 .................................................................................................................................................
[2]

(b) Ethanol can be manufactured from ethene.

Ethene can be made from long chain hydrocarbons such as decane, C10H22.

Ethene is then converted into ethanol.

(i) Name the process used to obtain ethene from long chain hydrocarbons such as decane,
C10H22.

.......................................................................................................................................
[1]

(ii) Complete the chemical equation to show the formation of ethene from decane, C10H22.

C10H22 → C4H8 + ................... + ................... [2]

(iii) Write the chemical equation for the conversion of ethene into ethanol.

....................................................................................................................................... [1]

(iv) Name the type of reaction occurring when ethene is converted into ethanol.

....................................................................................................................................... [1]

(v) Give one condition for the reaction in which ethene is converted into ethanol.

....................................................................................................................................... [1]

(c) Ethanol can also be produced by fermentation of carbohydrates such as glucose.

Give two advantages of manufacturing ethanol by fermentation compared to manufacturing

ethanol from ethene.

1 .................................................................................................................................................

2 .................................................................................................................................................
[2]
(d) (i) Under certain conditions ethene can react with chlorine to produce chloroethene.

The structure of chloroethene is shown.

H H

C C

H Cl

The equation for the chemical reaction is shown.

C2H4 + Cl 2 → C2H3Cl + HCl

State the type of chemical reaction between ethene and chlorine that this equation shows.

....................................................................................................................................... [1]

(ii) Chloroethene monomers can be converted into a polymer called poly(chloroethene).

State the type of polymerisation that produces poly(chloroethene) from chloroethene.

....................................................................................................................................... [1]

(iii) Draw a section of the poly(chloroethene) molecule made from two monomer molecules.

[2]
(e) The structure of part of a polymer is shown.

O O O

N C N C N C

H H H

This polymer is made from one type of monomer only.

Complete the diagram to show the structure of the monomer used to produce this polymer.
Show all of the atoms and all of the bonds in the functional groups.

[2]

[Total: 16]

5. The equation for the reaction between powdered zinc carbonate and dilute nitric acid is shown.

ZnCO3....... + 2HNO3....... → Zn(NO3)2....... + H2O....... + CO2.......

(i) A student found that 2.5 g of zinc carbonate required 20 cm3 of dilute nitric acid to react
completely.

Calculate the concentration of dilute nitric acid using the following steps:

● calculate the mass of 1 mole of ZnCO3

.............................. g

● calculate the number of moles of ZnCO3 reacting

.............................. moles

● determine the number of moles of HNO3 reacting

.............................. moles
● calculate the concentration of HNO3.

.............................. mol / dm3

[total:4]