Chemical-Reviews For Experiment 1.1 Melting and Boiling Point - 1.2 Recystalllization

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Table 1.1.

Reagents and Characteristics

Reagent Characteristics Safety Protocols

Naphthalene IUPAC: Naphthalene Storage: Well-ventilated location (cool, dry,


Chemical Formula: C10H8 and dark) and separated from strong
Molecular Weight: 128.1705 g/mol oxidants and feedstuffs.
Melting Point: 80 C Safety measure and precaution: Can cause
Boiling Point: 218 C Irritant, Health Hazard and Environmental
Density: 1.16 g/cm3 at 20 C Hazard. Always wear protective gloves/eye
Classification: benzenoid polycyclic protection. Avoid spillage to the
aromatic hydrocarbon environment.
First aid: (eyes) flush eyes with water or
normal saline solution (20 to 30 minutes),
(skin) gently wash all affected skin areas
thoroughly with soap and, (inhalation) take
deep breaths of fresh air if breathed in,
otherwise give artificial respiration.
(swallow) immediately call medical
attention.
Disposal:Dry container. Keep away from
confined spaces (sewers). Do not dispose
of it into drains. Dilute to avoid
environmental damage.

Salicylic Acid IUPAC: 2 – hydroxybenzoic acid Storage: Away from sources of heat and
Chemical Formula: C7H6O3 closed containers with a well-ventilated
Molecular Weight: 138.12 g/mol area.
Melting Point: 158.6 C Safety measure and precaution: (Corrosive,
Boiling Point: 211C Irritant, and Health Hazard). Wear protective
Density: 1.44 g/cm3 gloves/Eye or face protection.
Classification: Beta hydroxy acid First aid: (eyes) rinse with eye wash. Continue
Rinsing. (skin) wash off with soap and
water. (inhaled) artificial respiration if not
breathing. (swallowed) rinse mouth with
water.
Disposal: Neutralize the substance and into
covered containers.

Urea IUPAC: urea Storage: Dry place and tightly closed


Chemical Formula: NH2CONH2 container.
Molecular Weight: 60.056 g/mol Safety measure and precaution: Proper lab
Melting Point: 132.7oC wear.
Boiling Point: 321oC First aid: (eyes) rinse in eye wash in several
Density: 1.32 g/cm3 minutes (skin) wash off with soap & water
Classification: Amides and dispose of affected clothing (inhalation)
move to fresh air (Swallow) rinse with water,
call for medical personnel.
Disposal: Collected in a sealable compatible
waste container. Do not empty into drains.

Fumaric Acid IUPAC: (2E)-But-2-enedioic acid Storage: keep in tightly closed container in a
Chemical Formula: C4H4O4 dry and well-ventilated space
Molecular Weight: 116.072 g/mol Safety measure and precaution: Avoid contact
Melting Point: 278oC with skin and eyes. Avoid formation of dust
Boiling Point: 522oC and aerosols.Further processing of solid
Density: 1.635 g/mL materials may result in the formation of
Classification: dicarboxylic acid combustible dusts. The potential for
combustible dust formation should be taken
into consideration before additional
processing occurs.
First aid: (inhaled) breathe fresh air or provide
artificial respiration, (contact) wash off with
plenty of water and soap, (eye contact)
Rinse thoroughly for 15 minutes,
(swallowed) Rinse with water.
Disposal: Sweep working area well and
dispose of container

2-Butanone IUPAC: Butan-2-one Storage: Store in a well-ventilated place. Keep


Chemical Formula: C4H8O container tightly closed Store locked up
Molecular Weight: 72.11 g/mol Safety measure and precaution: Wash face,
Melting Point: -86oC hands and any exposed skin thoroughly
Boiling Point: 79.64oC after handling Do not breathe
Density: 0.8050 g/mL dust/fume/gas/mist/vapors/spray Use only
Classification: ketone outdoors or in a well-ventilated area Keep
away from heat/sparks/open flames/hot
surfaces. - No smoking Keep container
tightly closed
First aid: (inhaled) breathe fresh air, (skin
contact) take off contaminated clothes and
rinse with water, (eyes) rinse with water,
(fire) CO2 extinguisher
Disposal: Dispose of contents/container to an
approved waste disposal plant

n-Pentane IUPAC: Pentane Storage: Store locked up. Store in a well-


Chemical Formula: C5H12 ventilated place. Keep container tightly
Molecular Weight: 72.15 g/mol closed. Keep cool.
Melting Point: -129.8oC Safety measure and precaution: Keep away
Boiling Point: 36.1oC from heat/sparks/open flames/hot surfaces
Density: 0.626 g/mL First aid: (inhaled) breathe fresh air, (skin
Classification: alkane contact) take off contaminated clothes and
rinse with water, (eyes) rinse with water,
(fire) CO2 extinguisher
Disposal: Dispose of contents and container in
accordance with all local, regional, national
and international regulations.

sec-Butanol IUPAC name: butan-2-ol Storage: fireproof container, separated from


Chemical Formula: C4H10O oxidants and aluminum
Molecular Weight:74.12 g/mol Safety Measure and Precaution: (flammable,
Melting Point: -114.7 irritant) Wear proper lab wear
Boiling Point: 99.5 Handling: Avoid contact with skin and eyes.
Density: 0.806 at 20 Avoid inhalation of vapor or mist.
Classification: Butanols First Aid: (eyes) rinse several minutes; (skin)
wash with soap and water, remove
contaminated clothing; (inhalation) breathe
fresh air; (mouth) rinse, medical attention
Disposal: closed container, absorbent

Glycerol IUPAC name: propane-1,2,3-triol Storage: closed container; cool, dry, and well-
Chemical Formula: C3H8O3 ventilated area; do not store in heat or
Molecular Weight: 92.09 g/mol direct sunlight; protect from moisture; do not
Melting Point: 18.1 °C freeze
Boiling Point: 290 °C Safety Measure and Precaution: Wear proper
Density: 1.26 g/cm3 at 20 °C lab wear
Classification: Triose Sugar Alcohols Handling: Avoid contact with skin, eyes or
clothing. Avoid ingestion and inhalation.
First Aid: (eyes) rinse immediately with plenty
of water, also under the eyelids; (skin) wash
immediately with plenty of water, remove
contaminated clothing; (inhalation) breathe
fresh air; (mouth) rinse, drink plenty of
water, medical attention
Disposal: closed container, absorbent

Benzoic Acid IUPAC name: benzoic acid Storage: closed container; cool, dry, and well-
Chemical Formula: C7H6O2 ventilated area
Molecular Weight: 122.12 g/mol Safety Measure and Precaution: (corrosive,
Melting Point: 122.4 °C irritant, health hazard) always wear proper
Boiling Point: 249.2 °C lab wear; work under hood
Density: 1.3 g/sm3 at 20 °C Handling: Avoid contact with skin and eyes.
Classification: aromatic carboxylic acid Avoid inhalation of substance or mixture
First Aid: (eyes) rinse with plenty of water;
(skin) rinse with water, remove
contaminated clothing; (inhalation) breathe
fresh air; (mouth) immediately drink plenty
of water, medical attention
Disposal: clean container, neutralize

Benzoin IUPAC name: 2-hydroxy-1,2- Storage: Store in a cool location. Keep away
di(phenyl)ethanone from food and beverages. Protect from
Chemical Formula:C14H12O2 freezing and physical damage. Provide
Molecular Weight: 212.24 g/mol Ventilation for containers. Keep the
Melting Point: 134 - 138 °C container tightly sealed. Store away from
Boiling Point: 194 °C incompatible materials.
Density: 1.31 g/cm³ Safety Measure and Precaution: Avoid contact
Classification: Ketone with skin, eyes, and clothing. Follow good
hygiene procedures when handling
chemical materials.
First Aid: Inhalation: Remove from exposure
site to fresh air, keep at rest, and obtain
medical attention. Eye exposure: Flush
immediately with water for at least 15
minutes. Contact a physician if symptoms
persist. Skin exposure: IF ON SKIN: Wash
with plenty of soap and water.
Disposal: Dispose of in accordance with local
regulations. Avoid disposing into drainage
systems and into the environment. Empty
containers should be taken to an approved
waste handling site for recycling or disposal.

Maleic Acid IUPAC name: (Z)-but-2-enedioic acid Storage: Dispose of in accordance with local
Chemical Formula: C4H4O4 regulations. Avoid disposing into drainage
Molecular Weight: 116.07 g/mol systems and into the environment. Empty
Melting Point:131-133 °C containers should be taken to an approved
Boiling Point: 167.16 °C waste handling site for recycling or disposal.
Density: 1.59 g/cm³ Safety Measure and Precaution: P261 Avoid
Classification: dicarboxylic acids and breathing dust/fume/gas/mist/vapours/spray
derivatives P280 Wear protective gloves/protective
clothing
First Aid: General notes Take off contaminated
clothing. Following inhalation Provide fresh
air. In all cases of doubt, or when symptoms
persist, seek medical advice. Following skin
contact Rinse skin with water/shower. After
contact with skin, wash immediately with
plenty of water. In case of skin reactions,
consult a physician. In case of skin irritation,
consult a physician. Following eye contact
Irrigate copiously with clean, fresh water for
at least 10 minutes, holding the eyelids
apart. In case of eye irritation consult an
ophthalmologist. Following ingestion Rinse
mouth with water (only if the person is
conscious). Call a doctor.
Disposal: P501 Dispose of contents/container
to industrial combustion plant.

n-Butanol IUPAC name: butan-1-ol Storage: Store in a well-ventilated place. Keep


Chemical Formula: C4H10O container tightly closed Store locked up.
Molecular Weight: 74.123 g/mol Safety Measure and Precaution: Wash face,
Melting Point: -89.8°C hands and any exposed skin thoroughly
Boiling Point: 117.7°C after handling. Do not eat, drink or smoke
Density: 810 kg/m3 when using this product. Wear protective
Classification: Primary Alcohol gloves/protective clothing/eye
protection/face protection. Do not breathe
dust/fume/gas/mist/vapors/spray. Use only
outdoors or in a well-ventilated area. Keep
away from heat/sparks/open flames/hot
surfaces. - No smoking. Keep container
tightly closed. Ground/bond container and
receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use
only non-sparking tools. Take precautionary
measures against static discharge. Keep
cool.
First Aid: IF INHALED: Remove victim to fresh
air and keep at rest in a position
comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel
unwell Skin If skin irritation occurs: Get
medical advice/attention IF ON SKIN (or
hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact
lenses, if present and easy to do.
ContinuerinsingImmediately call a POISON
CENTER or doctor/physician Ingestion IF
SWALLOWED: Call a POISON CENTER or
doctor/physician if you feel unwell Rinse
mouth
Disposal: Dispose of contents/container to an
approved waste disposal plant

n-Hexane Chemical Name (IUPAC): hexane Storage: fire-resistant containers; a well-


Chemical Formula: C6H14 ventilated area
Molecular Weight: 86.18 g/mol Safety measures and precautions: (flammable,
Melting Point: -95.3°C irritant, health hazard, environmental
Boiling Point: 68.7°C hazard) Always wear proper lab wear
Density: 0.63 g/cm3 at 20°C First aid: (eyes) rinse several minutes; (skin)
Classification: alkanes wash with soap & water, remove
contaminated clothing, (inhalation) breathe
fresh air
Disposal: a closed container

Propanoic acid Chemical Name (IUPAC): propanopic Storage: fireproof container; separated from
acid oxidants
Chemical Formula: C3H6O2
Molecular Weight: 74.08 g/mol Safety measures and precautions: (corrosive)
Melting Point: -20.7°C wear goggles & gloves First aid: (eyes)
Boiling Point: 141.1°C rinse several minutes; (skin) wash with soap
Density: 0.993 g/cm3 at 20°C & water, remove contaminated clothing,
Classification: Acids, Acyclic, (inhalation) breathe fresh air; (mouth) rinse,
Propionates medical attention
Disposal: closed container, neutralize and
dilute

tert-Butanol Chemical Name (IUPAC): 2-methyl-2- Storage: fireproof container; separated from
propanol oxidants
Chemical Formula: C4H10O Safety measures and precautions: (corrosive)
Molecular Weight: 74.12 g/mol wear goggles & gloves First aid: (eyes)
Melting Point: -20.7°C rinse several minutes; (skin) wash with soap
Boiling Point: 141.1°C & water, remove contaminated clothing,
Density: 0.993 g/cm3 at 20°C (inhalation) breathe fresh air; (mouth) rinse,
Classification: Acids, Acyclic, medical attention
Propionates Disposal: closed container, neutralize and
dilute

Silicone fluid IUPAC name: Polydimethylsiloxane Storage: closed container


Chemical Formula: C8H24O2Si3 Safety Measure and Precaution: (irritant)
Molecular Weight: 236.5 g/mol always wear goggles
Melting Point: -80.0°C First Aid: (skin) gently wash w/ soap and water;
Boiling Point: 153.0°C (eyes & mouth) rinse
Density: 0.940 g/m3 Disposal: closed container
Classification: Polymers

References: https://pubchem.ncbi.nlm.nih.gov/; https://www.nist.gov/; https://www.chemspider.com/;


https://pubchem.ncbi.nlm.nih.gov/ghs/#_prec
Table 2.1 Reagents and Characteristics

Reagent Characteristics Safety Protocols

Acetamide IUPAC: Ethanamide Storage: Store locked up.


Chemical Formula: C2H5NO Safety measure and precaution: Obtain,
Molecular Weight: 59.0672 g/mol read and follow all safety instructions
Melting Point: 81 C before use. Suspected carcinogenicity;
Boiling Point: 222 C Health Hazard. Always wear protective
Density: 1.16 g/cm3 at 20 C gloves/eye protection. Avoid spillage to
Classification: Amides the environment.
First aid: (eyes) flush eyes with water or
normal saline solution (20 to 30 minutes),
(skin) gently wash all affected skin areas
thoroughly with soap and, (inhalation)
take deep breaths of fresh air if breathed
in, otherwise give artificial respiration.
(swallow) immediately call medical
attention.
Disposal: Dry container. Do not dispose of it
into drains.

Acetanilide IUPAC: N-Phenylacetamide Storage: Store locked up.


Chemical Formula: C8H9NO Safety measure and precaution: An Irritant.
Molecular Weight: 135.16 g/mol Harmful if swallowed. Always wear
Melting Point: 114.3 C protective gloves/eye protection. Wash
Boiling Point: 304 C hands thoroughly after handling. Do not
Density: 1.1 g/cm3 at 20 C eat, drink, or smoke when using this
Classification: Amides product.
First aid: (eyes) flush eyes with water or
normal saline solution (20 to 30 minutes),
(skin) gently wash all affected skin areas
thoroughly with soap and, (inhalation)
take deep breaths of fresh air if breathed
in, otherwise give artificial respiration.
Rinse mouth. IF SWALLOWED: get
medical help.
Disposal: Dry container. Do not dispose of it
into drains.

Benzene IUPAC: Benzene Storage: Store in a well-ventilated place.


Chemical Formula: C6H6 Keep cool. Store locked up.
Molecular Weight: 78.11 g/mol Safety measure and precaution: An Irritant.
Melting Point: 5.5 C Flammable; Health Hazard. Harmful if
Boiling Point: 80 C swallowed. Always wear protective
Density: 0.9 g/cm3 at 20 C gloves/eye protection. Do not eat, drink,
Classification: Aromatic or smoke when using this product. Keep
Hydrocarbon away from heat, hot surface, sparks,
open flames and other ignition sources.
Do not breathe fume, gas mist, vapors,
spray. Wash hands after handling. Do
not touch eyes. Use only in a well-
ventilated area.
First aid: If irritation occurs, seek medical
attention immediately. If on skin, wash
with plenty of water. Take off immediately
all contaminated clothing. IF
SWALLOWED: get medical help.
Disposal: Dry container. Do not dispose of it
into drains.
Ethyl Acetate IUPAC: Ethyl acetate Storage: Keep container tightly closed.
Chemical Formula: C4H8O2 Safety measure and precaution: An Irritant.
Molecular Weight: 88.11 g/mol Flammable. Always wear protective
Melting Point: -84 C gloves/eye protection. Do not eat, drink,
Boiling Point: 77.1 C or smoke when using this product. Keep
Density: 0.9 g/cm3 at 20 C away from heat, hot surface, sparks,
Classification: Acetate ester open flames and other ignition sources.
Avoid breathing fume, gas mist, vapors,
spray. Wash hands after handling. Do
not touch eyes.
First aid: If irritation occurs, seek medical
attention immediately. If on skin, wash
with plenty of water. Take off immediately
all contaminated clothing. IF
SWALLOWED: get medical help.
Disposal: Dry container. Do not dispose of it
into drains.

References: https://pubchem.ncbi.nlm.nih.gov/; https://www.nist.gov/; https://www.chemspider.com/;


https://pubchem.ncbi.nlm.nih.gov/ghs/#_prec

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