This document summarizes techniques for fabricating ultrafine platinum wire using modifications of Wollaston's historic method from 1813. The key steps are:
1) Inserting high purity platinum wire into a silver rod and annealing before drawing the composite through progressively finer dies to reduce the diameter.
2) Further reducing the platinum core diameter by reinserting it into another silver rod and repeating the drawing.
3) Developing a technique to position the ultrathin platinum wire for examination before etching away the supportive silver cladding.
4) Producing multifilament platinum yarn by bundling and reinserting 10 platinum wires drawn within a silver rod.
This document summarizes techniques for fabricating ultrafine platinum wire using modifications of Wollaston's historic method from 1813. The key steps are:
1) Inserting high purity platinum wire into a silver rod and annealing before drawing the composite through progressively finer dies to reduce the diameter.
2) Further reducing the platinum core diameter by reinserting it into another silver rod and repeating the drawing.
3) Developing a technique to position the ultrathin platinum wire for examination before etching away the supportive silver cladding.
4) Producing multifilament platinum yarn by bundling and reinserting 10 platinum wires drawn within a silver rod.
This document summarizes techniques for fabricating ultrafine platinum wire using modifications of Wollaston's historic method from 1813. The key steps are:
1) Inserting high purity platinum wire into a silver rod and annealing before drawing the composite through progressively finer dies to reduce the diameter.
2) Further reducing the platinum core diameter by reinserting it into another silver rod and repeating the drawing.
3) Developing a technique to position the ultrathin platinum wire for examination before etching away the supportive silver cladding.
4) Producing multifilament platinum yarn by bundling and reinserting 10 platinum wires drawn within a silver rod.
This document summarizes techniques for fabricating ultrafine platinum wire using modifications of Wollaston's historic method from 1813. The key steps are:
1) Inserting high purity platinum wire into a silver rod and annealing before drawing the composite through progressively finer dies to reduce the diameter.
2) Further reducing the platinum core diameter by reinserting it into another silver rod and repeating the drawing.
3) Developing a technique to position the ultrathin platinum wire for examination before etching away the supportive silver cladding.
4) Producing multifilament platinum yarn by bundling and reinserting 10 platinum wires drawn within a silver rod.
I V. M. Jalan, D. A. Landsman and J. M. Lee, 9 L.Tournayan, A. Auroux, H. Charcosset and R.
U.S. Patent 4,19z,go7;1980 Szymanski, in press in Adsorption Science and z P. N. Ross, Final Report for Contract RP Technology 1200-5, Lawrence Berkeley Lab., CA, 1980 10 T. M. Tri, Thesis, Lyon, 1982;T. M. Tri, J. 3 D. Ott and Ch. J. Raub, Metal1 (Berlin), 1978,32, Massardier, P. Gallezot and B. Imelik, C. R. (2),140 Acad. Sci. Paris, 1981,293, 35 4 R. Szymanski and H. Charcosset, C. R . Acad. 1 1 R. Szymanski, H. Charcosset, P. Gallezot, J. Sci. Paris, 1983,296, Ser. 11, 1485 Massardier and L. Tournayan, in press in Yournal of Catalysis 5 R.Szymanski and H. Charcosset, 3. Mol. Catal., 12 R. Szymanski, H.Charcosset and V. Perrichon, 1984, 253 337 Proc. 8th Int. Congr. on Catalysis, Berlin, 1984, 6 R. Szymanski, Thesis, Lyon, January 1985 Vol. 11, p.151 7 W. Bronger, Z. Anorg. Allg. Ckem., 1962,319,58 13 E. K. Poels and V. Ponec, “Catalysis, Volume 8 A. S. Darling, G . L. Selman and R. Rushforth, 4”, a Specialist Periodical Report, Royal Society Platinum Metals Rev., 1970,14, 54 of Chemistry, London, 1982,p.196
The Fabrication of Ultrafine Platinum Wire
WOLLASTON’S HISTORIC TECHNIQUE FURTHER DEVELOPED In February 1813 William Hyde Wollaston (Rev. Sci. Instrum., 1985, 56, (7), 134-1346), read a paper to the Royal Society describing a A preliminary treatment of the ultrahigh method that he had developed for making ex- purity metals to remove any surface con- tremely fine wire. Initially he had been con- taminants is followed by vacuum annealing cerned to produce fine gold wires, for use as before a piece of the 0.5- diameter platinum crosswires in the eyepiece of astronomical in- wire is fitted into a hole drilled along the centre struments. This he did by drilling a hole along of a 3.2mm diameter silver rod. Next this com- the centre of a silver rod into which a length of posite rod is slowly drawn through some seven- gold wire was inserted. When the diameter of ty progressively finer dies, to an overall this composite had been reduced sufficiently by diameter of o.smm. Following a further drawing through dies, the silver was dissolved vacuum anneal the silver:platinum composite is to yield the fine gold wire. However Wollaston inserted into another annealed silver rod and found it very difficult to drill the central hole in the drawing continued. Although it is not possi- the silver so he substituted platinum for the ble to repeat the annealing stage again without gold and modified the technique to make use of the wire breaking up into short pieces, the the higher melting point of platinum. He ar- other operations can be carried out as often as ranged a platinum wire with a diameter of r / r o o is necessary to reduce the platinum core to the of an inch along the longitudinal axis of a cylin- ultrathin diameters required to test the theory drical mould which was then filled with molten of quasi-one-dimensional electronic localisation silver. Following successive reductions of the and interaction effects, at liquid helium composite ingot, the silver was dissolved to give temperatures. a platinum wire 1/5000 of an inch in diameter. Techniques have been developed that enable This was excellent for his intended use, but by these ultrathin wires to be positioned for ex- exercising the utmost care both with the quality amination before the supportive silver cladding of the platinum and during the wire drawing is etched off. operation he was able to produce platinum wire as small as 1/30,000 of an inch in diameter Multifilament Platinum Yarn (approximately 8500 a). In another procedure ten platinum wires are Wollaston’s technique for producing fine inserted into separate holes again drilled wire has remained in use, and modified pro- longitudinally into a silver rod. During cedures that enable both single and multiple repeated reductions, lengths of the resulting ultrathin platinum filaments to be produced composite wires are bundled together, re- a with diameters as small as 80 have recently inserted in another silver rod and the sequence been reported by A. C. Sacharoff and R. M. repeated. When finally the silver is etched Westervelt of Harvard University and J. Bevk away, a fine multifilament platinum yarn is of A T & T Bell Laboratories, Murray Hill obtained. I.E.C.