Problem Set 1

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PROBLEM SET 1

Carbohydrates and Lipids


30
CYS:
Group:
Members: Signature:

Note: Member/s of the group with no signature will be regarded as to having no significant contribution
to this activity. The member/s may submit individually otherwise, a grade of zero shall be given.

I. Carbohydrates: Structures and Functions

A. Monosaccharide WOO is an enantiomer of the monosaccharide MEH (with the structure as


shown). Draw monosaccharide WOO in Fischer projection. Convert monosaccharide WOO into
its two anomeric forms in Haworth projection. (5 pts)

Structure of Monosaccharide WOO

Structure of Monosaccharide MEH

α-Anomer of WOO β-Anomer of WOO

BT-CHM113: Chemical Biology 3 (1st term AY 2023-2024) 1 of 4


B. Complete the table below: (6 pts)

Classification
Type/s of Reducing or
(disaccharide, Monosaccharide Branched or
Carbohydrate Glycosidic non-reducing
oligosaccharide, unit/s unbranched?
Linkage/s sugar?
polysaccharide)
Sucrose

Stachyose

Amylopectin

C. What are the common structural features of cellulose and chitin? Why is it necessary for
structural polysaccharides to have such features? Express your answer in maximum of three
sentences. (4 pts)

BT-CHM113: Chemical Biology 3 (1st term AY 2023-2024) 2 of 4


II. Lipids: Structures and Functions (Part 1)

A. Draw the block diagrams of triacylglycerol, glycerophospholipid, and sphingophos-


pholipid. Label what kind of linkage is involved within the structure. (Do not just copy and
paste from the lecture slides or the internet.) (6 pts)

B. Draw a polyunsaturated fatty acid with the following structural characteristics:


• 20 carbon atoms
• cis-double bonds at positions 5, 8, 11
Indicate the structural notation indicating the delta designation (e.g. 18:1(Δ9)) and its omega
family classification. (4 pts)

Fatty Acid Structure:

Structural notation:

Omega family classification:

BT-CHM113: Chemical Biology 3 (1st term AY 2023-2024) 3 of 4


C. Considering the triglyceride below, draw the products of the given reactions. (6 pts)

1. Complete hydrolysis

2. Saponification using NaOH

3. Complete hydrogenation

BT-CHM113: Chemical Biology 3 (1st term AY 2023-2024) 4 of 4

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