I "\

Co r--Ioe:r
-
Sttrobol ·~ Cu
da-hro name ·- C<1Fa:11rn
A:t:omrc. oumbel: .1~ 29
_ _ _ _ _::........:,;A.....x..::tomPc ma~s •,. 6'3' · 5-f arnu
Va Ie. n c ij ·· J aod 2.

: Occu:r:e.oce,
\ Coppe.:r ccrnn bo+h '?a no±rve. os tile.II a.s co mbroe.
I\ ,.s±-a:be . !i?,C.s na±Pve >Tt:a-le. rs -f:o"ocJ l'o Co nod ei , Lb Poa , U<:tl
,Mexf'co and i2tJ.ssf'a . 2o "-kpal, 'i'f OCCCl'ts o.s Cb alcoputr-be

'. <ille coro!'.!? on ores of cop p2.T arQ : -

 1:hakopijttJ.e air: Ccfper fl:/ tr-!e ,. Cr, f'eS2
Cho lcn ctt.e or Coppe r 8 b o c~ ·- Cu, C:
Rub 't Copp e..,.. OY Ct.ip er te ·- Cu~ CJ
---

Q f&w,bt og. ~ .. rod foa nod CooceoLrohroo -----

~ p ore. fs cr:usbe d ro '" riJ ca:11,'i'he)C a od
J
i'fbe o
I I
Douidm d -Ptne.l~
bo 11 rod I~ . {i){; rs ca ace nha .j. e d b'd
ro
,f'ro./:b floohi±roo process , '?o JbPs mc,-/:bod , :!:be f'rne I~ poU1ettd _
1 ore rs rnfx:C?d wrtb u.2o±er and Proe or! ro a took • fi1e
I [Y1 r,d:rn:e fs oa rf c:,±e d b~ co00 pt:e s.sec-l O h:: ./:l, en :the .ru Iphrde -
ox:e comes to -bbe ,soJtoce aloo~ wr-1-h :!-be ~l"o±b and +h e
! toopu...-Ptf>es l~e++-le ±a the,_ bot+o ro .
I

h. 1
I
Roa st[oa
-
1

(J

OCP a£ excess: oYr Po t:everberoto"l:td' +'nt:oore , fJ.s O ?t:<°.s ul+::;

the fropartres 0£ sulpbot , pbos-phoroJJ s , ob':enrc etc a'ce.
1 cer:n~v 0 J ct.s ±:bo er vo la+ ele ox rder
I I
,0 :t a2 /J
S02 1
--,..;---_ _ _.LjuP_ _J+~ sl o2L---======A===:::!..),,~ 2ue~,_QQ'5.-5_11__ _ _ _ _ ____
AA.s ± QQ, J, >: 2tJs, Q3 t --
1 e&urPoaQ &ocu±fna
a ,t2roce.s s, copper pu•d+ee.1 .... _ __ ts , d row,
coove>::te _...
1
roPx·bu:0 of £etrou s s11\ 0 brde
I ' C I l p>r: O (I > SC I Irbrd P , Pe-rte \J S O x:t
dt---
(\ nd cuprY c oxrd e
fj
Cu? s + 2£} S:+ 9S{h
26? .s f JO,
2Cu.2S -+ 302. - -- - -=>-., ., QCu:i.O + 2~02

r I l l
' \
C\ \
\ "
I
"
~ '--' ·:w.:.......;:
't-\~~ 30 ~~ '
~,- \ ;,

n·

\
\ ; r1 t • ~ (.' •. ( :~
\
 u--
l

-~ e PrA co~,
o ro nee
f\' madI 0 ,S' I?
Jur uact ,foo :hike s

C1.s r bIe 6'.\.u.o1..1~- - -

- Ali rsr0.1),1.___ __~
AI1100,nl'u tn ,, r\ rca+e
2 cu , a -t-.:.2us.J..10,L,J.2:...___
Cu,~ ~ j8~e~OL___ _ _
Cu2 0-+ l'1~,S-
f'~ o -+ Sro?
=-=~=====-?_ rr~e~~fDQ~~- ~ - - --
-= 4

ro 't _ _ - -
Cu,D
- ±L--:,,C_ =====,==...:__:.2'-!i..Ct. !u._l_ -t~--~- - __

lne
---- 1
- - - - - - - - -- ~ -
o,o\:te n rr:o s.1 ron±c lnY oq_<f 50 'L,_ cupp£ .X --, t:u,,~.$
:th el I ,
a o~ E'e S ts koo, •lCL.J l.L_ mal-:t e o... . en •
 - d:
I

L1
.ll y
1•

c1
2 1'
Ll
b 1'

wbrcb per .gR ../o bt1t:C?)>

.
_ _ ,
t

-
+
=~- - - - - - - - - - - - - -

--
- .,
 r
..,

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r
()~
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Re too Po Po~ sol1J Poo las su/pbo±e )

f4:0 pert ees a£ Ca.pru r ·

I

I Colo 11 ~
Peculra -r 'todderb (Reddr~b btoci1o)
:•

2. :,fb.f'i , @ I) ea I, le , du c trle , sped±ec 8ra v r¼J ·- B. ·,~ 5

3,l, ~ood coodu ck a£ ttieob aod olo c ±-l:fc1+-~

11I
Cberofca\ . Ptgpgr:t:r~r 0£ Copf:>=
I
J. f tlckPoq 0£ grr

2Cu :t H!2 0-t CO2 t Oo - - - - - - CuC03 . Co(OH)?:

--:--- - - - - - - - - - - - -~~a,u..1.sf..c--L
1_. ca...f'lpr-1,~~>-~cuor..r:.o.bOJoorualJt:.ee~ - -- -
1
/Copper fs no± o.ef'.,,-1-.d
/I
ob, '° but:
/,b' d.111 ab at: ,, . . draotz1 ho,pot: v
t Po mors+: or)'
aod Pa 0£ co, ff: es _-
ii ;
r'/cesence
/! S/ot,,l~ convert-eel '°oto
tlie et:e e I\ /, 0 I f c COpr er' C a>: 6oM +. . .- - - -

Ii
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l l 11 I I)
\\ I' \j I

_J~h.l.--Ueo~ \t2e.ald__ fn__ 1--0ft_ glYPs

c.uprrc.. ox,·dc a-l 30Q ·"c und
t:oi-~- -c,11p,t-o.-. u_~~ ~ ,•d~ cihov e. J ao rJ''c
1

=;I~ - - --2 C11- -+- _0:1. - - ~~

JO tJ O oc.
' l:
1
>- !2 Cu o I
----4--_ _ _ _ Lt_ Cu__
.,. _Q
__
? ~.~~---- 7 2Cct1-0
_J_l1~Q~R~,~~Cui1~+~wnQ~~~1c:~:==~~~o
➔------------·-- -

2. 1
• ScffQo a£ Acrds ·
r,) 11 , ,!b drI H~ o9 •

Cu + 8 H "-lO 3 - - - - ~ 3 c. u( f\lOs) :2 --t- 2~0 + ~20

rh-~. wrl:b Cooc · H2 S0'-1

/J
Cu 1: Co O c 2 H2 S04
cO pp e.,-- s II Ip b a i~

:rr;) toitb Coor· fill

2 Cu ➔ Coo c • 41-l (I -+ Oz ► 2 Cu cl z + 2 µ, Q

J. " c:ttoo
CJ t _ ill! t-, h -q =p
Q\J_e au , Q mro oOC0
I Cu -t N µ~ OH CCu CNl:fa h. ] DH

[ Co CNi-Jl)y 1 Cou' -- -
(i\+1 coromme copp2:t (rr) v •d.1:o.~rJt.
\h 1
 ' Coooroerc eo L iJtteJ'....
• · P+ Ps lotgel'd- use d ,o t
el e c rr t'c fad ust Tt
l

-· ,:_.L. ~l . L~l,A. --t;~~..U.:. lc. .le4CLOP~~:~:.:__e_b_2e_o_t_•s_e_d_ fo__o_

e t_t'_c_"_'±_tJ):_f'__
o_ s_
fo_s::_e_c±_r_c_
Pd-e.,_ =f
-b

:,~,~/~ 9, 2raf! t llrg

•;~J Z J C11 mo
a
c;in d dot I\! fi:l d,e_ t.
1te.QJ.J\'l"e
v er
fts J~4fcfeom
\
I
roo~es tncopabfl P-LL :ta a I
i
(}
11se f,too ffe) ,,,d·ored ~a lPve;r so 1

: +ba! ooe roCJt su .P~e-r -A,-am ooo em~oi .

• 1: C,1 .Jia11ld be pzeseo:I: fa 011 r bod
'& oli ber as ox'i'J a l'e Qn7t1rre' I
I, ood blue pto:tef ns ( roe:hollopto±:ePns)

Vrlrro\

,' fea-l:abijJr:a!e J rappet: .<ulpbad:e , C.,s:O.., · 5H2-0 1s koo,v0 os 7@!¢

 C

<ffie ropp•l'.'. s,ilphaie ,sd1d:Pon ohtarn,d P,

evaparo-l,J :b c,~sf:-
-- :\l r:zatPon poYn~ u>tie~ +be c7 ~,d--n ls: 0 + blue
- ,,?:trrol 1sepora1e cvi •
J,pot
CuS o~. 5lh.0
Glue vFitfal .

Mgpq~g c+Yr1

~
11
u
±bf oc±foo 0£ drl . H, CQq 0 a copper sco tps fo the prerec,ce
\ rr
CoppeY s11lphote Pr prepared on /,n-~r- scale £·roro d-be coppt

£'1:c,ro +be ,s: olu:hfoa of (uS 04 l o:ir+ol.s Ote ohtoPoiod "it coocentraL
rn<a-=

Blue, vft'rf ol .

. fropgJres
soled coo±o mfo~ feve coole o,ler a£ wok
-1 . J+ , I l
f~Q di I 'l Po
<' 1~ · SC I ib e ,41 o±er ; brl: en rn /,, b/o rn a bS'o lo:te
 ? ,n·1.
rus o" . 8 ~2 o , r u {O•,
Cc,so.,. ~ ~ 'l O ~),, ;otf c .'- l.uS 0,4 . I hO

8) u r \ h (,) ~ rlC /Jr1hj Jtr ,, c

.eale_ .11~,
(Monah~d tdJ 11 ( arn o ; ,;h{)11")
_ __ (Tr f h~abcl )

rn/c., f / ,."J

;oo •c
,, CufO ,,.J.b O
cxor~su~t ...
_ ___._Cc,~...Jl.l.i Q ~ _ - - - Cu.SCH . 311, 0 -
~[ufs h whrL·
___ _ .R. . .l. .u_.. c. _--=c'-'--v~~......shil __ _ _ P.o It Jkt

'( abovt. ~ 'fSo •c CuS~

Cu, O:t o, Cu o + .<'O ,
Jd oo ·c
Red o~fde Bio d a xrd <

'f . lcJcl-), sode11rn ,byJ>-oxfde so lukroo rt p'lroJu ce" a paI.,_

bl ue ppL a£ r.Ls: ,bydtoxrde .

5. When ommaof u m ,b'd"da:-o:xrde rs- added drop bl/ d,...of

Q,f(\~)
±o a sal11±Poo a£ coppo>: ,s: ,, lpba+e to 9Yve blur.t h ,vbr+e...
ppl . of ,hl'.f droxfdc> o,J excess aroourr+ of amcno.c.hJn:
cupzcrc
,~ dtax ,de caeve(' dQQP blvio salutroo o£ coppQ.T campk
koo r,)n as t e. 4:r:amrrie. co,npe>: {,JI) wlpho+e .
2 f\l t} -,O H + Cu S Ot1 - ----,. C1 dDH),2 -r.LNHJ a.S~,..
(/tmft ed ) '13/ufsh tu!L whtl.£..
_4_t!J~.1L~ / lJ $_°'1_ _ _ _ _ ;, [c_vJ ~ H3 } 4 ] SO¼ ~ t4;i [J

_ _ _ _ _ (~ x ce ..H) ----·-- dt~p bL.it.

_c..crnpl e. Y so~ C1t/ }J ~3 )SO,,. L1H1 0 f; 1nowo. cu
~L

_ t_,_b.J.~_£_rf~t.I .l re,oeent_ ar1_e.rnp lci!-fEd_fc"'" dr.s .'idvtc q . . cg

1
J - .,

Pr, the. p-re p-1,.ra_~faa - a [ !U: L1Jr lt1L s1Lk..

 .1 ( '
tuprous
·( )

, r! llbeta±e s . -1r & ,,,J.b po-bass rum

~r
I

CoSOt1 + 2k r
-~ --------
90 ,I2

--r----
,I - -------..Cu
--F
1i fiPe r:@Ot t>'Cfl ,, I ~LLI'. ,.,
r used .Pct: +be
, 1 11
-1, f--+~" S ~ --
Cl~ o
d I ; z:~~e~stt~Pm~o~tkPn~
+r-l:t
ro oroe:f:trc --
0
~~~~)Pfl.!tt..~tan:=
--L,j l"l+-
coppet -:Prnm
=
--
ta±Yoa .

Uses rf 7$lue
-- ' I.
VEtta
I • !ro me drdn -e. o.s 00 ,
oot.eseptPc. ·
J, ,I Used Po aaCJ rPcuJ±ure. +i erc1~Jg
asoo and Q e tmfc.tde.
3. 1b 1
±be r
pJpar-atloQ
1-- "
e~
r
i-ehlrne's ,siolutPoou --
I

-51. ~o :tbe pr:epara:tPoo

I ot-ri 0±hel' Fmpor+ad ~ rnpoooci1 otr. coppe>'-

---Mh
~e,-r~ - ~,- - - - - - - - ~
caoopounds 0£ toppeY

--
,___ l .
-J?l - _f.s_ usod ±o provrde lr8h±
r To used ro los:s 1ad ush 1r f:ll
8
- ~UJJ~~ - - - - - - - - - - - - - - - + - - - - - - - -- - - - - -- - - - -