Group-18 (Noble Gases) Notes

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Element symbol atomic no

Helium He 2

Neon Ne 10

Argon Ar 18

Krypton Kr 36
Xenon Xe 54
Radon Rn 86

Oganesson Og 118

Group 18 elements are termed as noble gases because


they form very few compounds under certain conditions
occurrence

All except Rn and our in the atmosphere


og

Their abundance in dry air is I volume of


o
by
which Ar is major constituent

He and sometimes we are found in minerals of


radioactive origin Lex Pitch blend monazite cleveite

The main commercial source of He is natural gas


Rn is obtained as a decay product of Isra
33Rd The BERN

Og is produced by collision of Iff atoms and


ca ions 88Cf 4286 titog 3h

General atomic and physical properties

meltingand solubility in
III IE DegH LDF boilingpoint clathrate water
He X
Ne x
Ar t've ins inc
Kr inc des nine
Xe v u v u v

compoundsLiqufficationDensityAtomicity colour odour


He x X x

Ne x g X X

Ar X inc inc 1 X x

Kr few 1 X X
Xe v r I x
many x

why noble gases have very low boiling points


ANI monoatomic small size weak LDF
which noble gas has unusual property of
diffusing through commonly used lab materials
like rubber plastics or glass

ANI Helium

chemical Properties
Noble gases are chemically inert due to
a very high IE
lb Highly the DegH
e Stable electronic configuration
difficult to excite e's

Discovery of noble gas compounds


D
Oat PAF Of PAF
Red

IE of Oz IE of Xe

xet PAF xet Ptt


Red
First discovered
compound of noble
gases

Xe reacts directly only with Fz


Fluorides of xenon
Xetz Xety XeFg

Preparation

d
Xe t Fa Xetz
exc

D
Xet Ez Xefy
1 5

d
Xe t Fa Xeff
1 20

Xefy t 0252 XeFg t 02

Low temp 02
Xet 0212 Xetz t
Xe t 02
Properties
F donor or acceptor

Fluorinating Xefn crystalline solids


agents colourless
i e oxidisers
H2O

readilyhydrolyse
Hydrolysis of Xenon fluorides

Hydrolysis of Xetz and Xety with water Redox

Etz Hat Eat Yeii t HF

XeOfa t H2o Xe02Fat 2nF hydrolysis

Xe Fo t Xe 03 t G HF complete
3,19 hydrolysis

EE t Hao s ke t 02 t Oz t Hf

Trick ef Xe fo t
Xeegoxetost HF
Hao Xeozt HF
Alkaline hydrolysis of Xefo
EEF t TH ing kept 024 of t F t tho
Perygnate
Mesh Xef H2O XeOz t HF
To F
vote
H Xe
of Eton of't Xe
Xe to
xenation
oxidising actions of Xe fluorides

XeFn n 2,4 6
Hz HF
HX X2 XF
NO NOF
NOz NOLF
GHG 9645ft HF
Pt PAF
Sty SFG
NH3 Nz NFz
xelg

Reaction with fluorides

with covalent fluorides with ionic fluorides


Xefn act as F ion donor Xefn act as F ionacceptor
t
XeFt t PF Aef PET Xetzt Nat Nat Xetz

Xef t HF xefstCHEJ Xefot Csf Cst very

XeFICBE Xe Rbt xeE


Xetz t BE Fat RDF
is not stored in due to the
Xeto glass
reactions
following
Xero t sioz xeofat Sift

Xeoft Sio Xeoafat si Fa

Xe0zEt si 02 Xe 03 t Sify

Reactions of Xe03

NathXeof
xe0z t Naor for Nadeogtxetoat Hao

Yeo Exe Fg 3
Xeofy

xe03 XeOE 2Xe02Ez

shapes of xe compounds species

XeFa XeF4 Xero Xe 03 Xe 04 XeOFz Xe 03 Fz


Xe0zF2 Xeoty xeFzt Xetz Xefst Xeff
XeFI

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