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  • Formularios FQII

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    Viviana Vanessa Jumbo Fernández
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    This document contains mathematical equations describing various thermodynamic, kinetic, and surface chemistry concepts. Key equations include: 1) Equations relating the natural logarithm of activity coefficients (lnγ±) to ionic strength for dilute solutions, using the Debye-Hückel limiting law. 2) Equations for reaction rate (v) in terms of the rate constant (k), concentrations of reactants and products, and equilibrium constant (K). 3) Equations relating surface tension (γ) to factors like radius (R), perimeter (p), wetting angle (θ), and work of adhesion (w).

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    This document contains mathematical equations describing various thermodynamic, kinetic, and surface chemistry concepts. Key equations include: 1) Equations relating the natural logarithm of activity coefficients (lnγ±) to ionic strength for dilute solutions, using the Debye-Hückel limiting law. 2) Equations for reaction rate (v) in terms of the rate constant (k), concentrations of reactants and products, and equilibrium constant (K). 3) Equations relating surface tension (γ) to factors like radius (R), perimeter (p), wetting angle (θ), and work of adhesion (w).

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    4 views4 pages

    Formularios FQII

    Uploaded by

    Viviana Vanessa Jumbo Fernández
    This document contains mathematical equations describing various thermodynamic, kinetic, and surface chemistry concepts. Key equations include: 1) Equations relating the natural logarithm of activity coefficients (lnγ±) to ionic strength for dilute solutions, using the Debye-Hückel limiting law. 2) Equations for reaction rate (v) in terms of the rate constant (k), concentrations of reactants and products, and equilibrium constant (K). 3) Equations relating surface tension (γ) to factors like radius (R), perimeter (p), wetting angle (θ), and work of adhesion (w).

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    of 4

    ∆ ∆ , , − ,

    = ∆ = ln ≈
    ∆ , ,

    ∆ , ∆ ∆
    − = ln ∆ ≈
    ∆ , ∆ ,

    ∆ 1 1
    ln =− − ∆ =∆ +∆
    R

    = − = ( + + ⋯+ )

    = = = + ln

    −∆ ∆ ∆
    = + ln ln = =−

    ∆ 1 1
    ln =− − − = =
    , → ∆
    1
    = − = =
    1+
    ∆ 1 1
    ln = − = =
    , → ∆

    ∆ ln
    ln = = =−
    ( − )

    = = =

    = + ( − ) =
    + ( − )

    = =
    + ( − )
    ∗ ′
    = ∆ =− ln =

    ′ ′ =
    ′= ′′ =

    = = ∆ = −
    , ,

    ∆ = − =

    ( , , )= ( , , )+ ln =

    − = ln =

    ∗∗ =
    ln = ( )+ ( )

    = = = (1 − )

    ln =− − ∗∗
    ∆ =− ln

    = = = +

    = ± = + ± = =

    ± = ± ± ± = ± =

    = = + ln + ln ± + ln
    ±

    = = (1 − )
    1 𝐹
    log 𝛾± = 𝑧 𝑧 𝐶 𝑧
    (2.303)8𝜋𝑁 𝜖𝑅𝑇
    1
    𝐿 𝐼= 𝐶𝑧
    log 𝛾± = 0.5092 𝑧 𝑧 𝐼 2
    𝑚𝑜𝑙
    𝐹 1 𝛼
    ϰ = 𝐶 𝑧 =𝑟 =𝛼
    𝜖𝑅𝑇 ϰ 𝛾±
    𝑠
    𝐿 =𝑠
    log 𝛾 = −0.5092 𝑧 𝐼 𝛾±
    𝑚𝑜𝑙
    𝑉
    𝜇 = 𝜇 + 𝑘𝑇 ln 𝛾± + 𝑘𝑇 ln 𝑚 𝐼=
    𝑅
    𝑙 1 𝐴 𝐴 𝑘
    𝑅=𝜌 𝐶= = =𝑘 Λ=
    𝐴 𝑅 𝜌𝑙 𝑙 𝐶
    Λ
    Λ=Λ −𝐵 𝐶 Λ = 𝜈 𝜆 +𝜈 𝜆 𝛼=
    Λ
    1 𝐶Λ 1 𝑣 𝜆±
    = + 𝑢 = 𝑢± =
    Λ 𝐾Λ Λ 𝐸 𝐹
    𝑘 𝑘 𝑘
    Λ= = 𝑆≈ 𝐸 =𝜙 −𝜙
    𝐶 𝑆 Λ

    𝑘 =𝑘 ó −𝑘 ∆𝐺 = −𝑛𝐹𝐸

    𝑎 𝑑𝐶
    ∆𝐺 = ∆𝐺 + 𝑅𝑇 ln 𝑣=
    𝑎 𝑑𝑡
    0.0591 𝑎 𝑑𝜉 1 𝑑𝑛
    𝐸=𝐸 − log =
    𝑛 𝑎 𝑑𝑡 𝜈 𝑑𝑡
    𝜕𝐺 𝜕 𝐺 𝐻 𝜕(𝐺 ⁄𝑇)
    = −𝑆 =− =𝐻
    𝜕𝑇 𝜕𝑇 𝑇 𝑇 𝜕(1⁄𝑇)
    𝑑 𝜉 1 𝑑𝐶 𝑑 𝜉
    𝑑𝐺 = 𝑑𝐻 − 𝑇𝑑𝑆 = = 𝑘𝐶
    𝑑𝑡 𝑉 𝜈 𝑑𝑡 𝑑𝑡 𝑉
    𝑑 𝜉
    = 𝑘𝐶 𝐶 𝐶 𝐶 … 𝐶 =𝐶 , exp[−𝑘𝑡]
    𝑑𝑡 𝑉
    1 𝑑𝐶 ln 2
    ln = ln 𝑘′ + 𝛼 ln 𝐶 𝑡 =
    𝜈 𝑑𝑡 𝑘
    𝑑𝑁 ln 2
    = 𝜆 𝑑𝑡 𝑁 = 𝑁 exp −𝜆 𝑡 𝑡 =
    𝑁 𝜆
    𝑑 𝜉 1 1 1
    = 𝑘𝐶 = + 𝑘𝑡 𝑡 =
    𝑑𝑡 𝑉 𝐶 𝐶, 𝑘𝐶 ,
    𝑑 𝜉 1 1 1 1
    = 𝑘𝐶 𝐶 = + 𝜈 𝑘𝑡 = + 𝜈 𝑘𝑡
    𝑑𝑡 𝑉 𝐶 𝐶, 𝐶 𝐶,
    𝐶 𝐶 𝐸∗
    ln − ln = −𝑘 𝜈 𝐶 , −𝜈 𝐶 , 𝑡 𝑘 = 𝐴 exp −
    𝐶, 𝐶, 𝑅𝑇
    𝐶
    ln = − −𝑘𝜈 𝐶 , 𝑡 ∆𝐻 = 𝐸 ∗ − 𝐸 ∗
    𝐶,
    𝐶 𝑘 [𝐸] [𝑆]
    ln = −𝑘 −𝜈 𝐶 , 𝑡 𝑣 =
    𝐶, 𝐾
    𝑑[𝑃] [𝐸] [𝑆]
    𝑣 = =𝑘 𝑣 = 𝑘 [𝐸]
    𝑑𝑡 𝐾 + [𝑆]
    𝑣 𝐹
    𝑣 = 𝛿𝐿 = 𝛾𝑑𝐴 𝛾=
    2 2𝑙

    𝐹 = 4𝜋𝑅𝛾𝑓 𝐹 = 𝐹 + 𝛾𝑝 2𝜋𝑅 𝛾 = 𝑤𝑔

    𝑔𝑟ℎ(𝜌 − 𝜌 ) 𝑃 2𝑀 𝛾 𝑋 𝑀 𝛾 𝛼
    𝛾= ln = ln =
    2𝑐𝑜𝑠𝜙 𝑃 𝜌 𝑟𝑅𝑇 𝑋 𝜌 𝑅𝑇 𝑎
    2𝛾 𝜂 𝜌 ∙𝑡 𝐸
    𝑃 =𝑃 + = 𝜂 = 𝐴 𝑒𝑥𝑝
    𝑅 𝜂 𝜌 ∙𝑡 𝑅𝑇
    𝛾 −𝛾 𝑃𝐾 1 1 1 1
    𝑐𝑜𝑠𝜙 = 𝑋 = = +
    𝛾 1 + 𝑃𝐾 𝑚 𝛽 𝛽𝐾 𝑃

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