Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

A. PRODUCT NAME : Lead-acid Battery

B. RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE
: Lead-acid Batteries for automotive
C. MANUFACTURER/SUPPLIER/DISTRIBUTOR INFORMATION
MANUFACTURER : Sebang Global Battery CO.,Ltd.
Sonjae-ro 287beon-gil, Gwangsan-Gu, Gwangju, KOREA
TEL: +82-62-601-6122 FAX: +82-62-951-4126

2. HAZARDS IDENTIFICATION

A. HAZARD CLASSIFICATION
PHYSICAL HAZARDS
: Not Classified.
HEALTH HAZARDS
: Acute toxicity Category 4 (inhalation)
: Skin corrosion/irritation Category 1
: Serious eye damage/eye irritation Category 1
: Carcinogenicity Category 1B
: Germ cell mutagenicity Category 2
: Specific target organ toxicity – single exposure Category 1
: Specific target organ toxicity – repeated exposure Category 1
ENVIRONMENTAL HAZARDS
: Not Classified.

B. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS

PICTOGRAMS :

SIGNAL WORD : DANGER.

HAZARD STATEMENTS
H332 Harmful if inhaled.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H350 May cause cancer (inhalation).
H341 Suspected of causing genetic defects.
H370 Specific target organ toxicity – single exposure; Respiratory tract irritation

10페이지 중 1페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

Causes damage to organs (Hematopoietic system, kidney, central nervous

H372 system, peripheral nervous system, cardiovascular system, immune system,
respiratory).

PRECAUTIONARY STATEMENTS :
[Prevention]
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a wellventilated area.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P281 Use personal protective equipment as required.
P270 Do not eat, drink or smoke when using this product.
[Response]
IF INHALED: Remove victim to fresh air and keep at rest in a position
P304 + P340
comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
P303 + P361 + P353
Rinse skin with water/shower.
P363 Wash contaminated clothing before reuse.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see ... on this label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
P305 + P351 + P338
lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.
[Storage]
P405 Store locked up.
[Disposal]
Dispose of contents/container in accordance with local/regional/national
P501
regulations.
C. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION (e.g. Dust explosion hazards)
NFPA/HMIS Rating
Health=3, Flammability=0, Instability=1
:
(0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme)

3. COMPOSITION / INFORMATION ON INGREDIENTS

10페이지 중 2페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

Chemical name / Synonym CAS No. or ID Content (%)

Lead 7439-92-1 52 - 59
Antimony 7440-36-0 0.5 - 0.7
Sulfuric acid / Oil of vitriol 7664-93-9 30 - 38
Polypropylene / PP Resin 9003-07-0 6-9
Separator Not available 1-2
* European Inventory of Existing Commercial Chemical Substances (EINECS).

4. FIRST AID MEASURES

If a battery ruptures, do not rub or scratch exposed eye. Immediately flush eyes
A. EYE CONTACT : with running water for at least 15 minutes, keeping eyelids open. Cold water
may be used. GET MEDICAL ATTENTION IMMEDIATELY.

If a battery ruptures, do not rub or scratch exposed skin. If liquid get on the skin,
immediately flush the contaminated skin with water for at least 15 minutes. If
B. SKIN CONTACT : liquid penetrate through the clothing, immediately remove the clothing and
shoes under a safety shower and continue to wash the skin for at least 15
minutes. GET MEDICAL ATTENTION IMMEDIATELY.

If a battery ruptures, move to fresh air in case of accidental inhalation of mist. If

C. INHALATION : breathing has stopped, perform artificial respiration. If breathing is difficult, give
oxygen. GET MEDICAL ATTENTION AS SOON AS POSSIBLE.

If solutions of a battery chemicals have been swallowed and the person is

conscious, give one glass of water. Vomiting may occur spontaneously, but Do
D. INGESTION :
NOT induce vomiting. Never give anything by mouth to an unconscious person.
GET MEDICAL ATTENTION IMMEDIATELY.

E. MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE OR DELAYED

Not a likely route of exposure. If a battery ruptures, direct contact with the liquid
or exposure to vapors or mists may cause tearing, redness, swelling, corneal
EYES :
damage and irreversible eye damage. Splashes in the eyes will cause severe
burns.
Not a likely route of exposure. Direct contact with internal components of a
battery can be severely irritating to the skin and may result in redness, swelling,
SKIN :
burns and severe skin damage. Skin contact may aggravate an existing
dermatitis condition.
Not a likely route of exposure. If a battery ruptures, may be harmful or fatal if
INHALATION : inhaled in a confined area. May cause severe irritation and burns of the nose,
throat and respiratory tract.

Not a likely route of exposure. Causes serious burns of the mouth or perforation
INGESTION :
of the esophagus or stomach. May be fatal if swallowed.

* Lead may causes toxic to blood, kidneys, central nervous system (CNS). Repeated or prolonged
exposure to lead can produce target organs damage.
F. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND NOTES FOR PHYSICIAN

10페이지 중 3페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

Based on the individual reactions of the patient, the physician's judgement

:
should be used to control symptoms and clinical condition.

5. FIRE FIGHTING MEASURES

A. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA

Use extinguishing media appropriate for surrounding fire.
:
If a battery ruptures, use dry chemical, soda ash, lime, sand or carbon dioxide.
B. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Lead, lead compounds and sulfuric acid fume may be released during a fire
:
involving the product.
C. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective
:
clothing.
D. FIRE AND EXPLOSION HAZARD
Not flammable.
: Battery may rupture due to pressure buildup when exposed to excessive heat
and may be result in the release of corrosive materials.

6. ACCIDENTAL RELEASE MEASURES

A. NECESSARY MEASURES AND PROTECTIVE GEAR TO PROTECT HUMANS

If a battery ruptures, avoid contact with skin, eyes and clothing. Do not touch
: spilled material. Use personal protective equipment recommended in Section 8
(Exposure Controls/Personal Protection).

B. NECESSARY MEASURES TO PROTECT ENVIRONMENT

Notify authorities and appropriate federal, state, and local agencies. Prevent the
:
product from spreading into the environment. Avoid direct discharge into drains.
C. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
SMALL SPILLS: Collect all released material in a plastic lined metal container. If
necessary neutralize the residue with a dilute solution of sodium carbonate.
Wash affected area.
LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
:
by building a dike. Absorb with dry earth, sand or other non-combustible
material. Neutralize the residue with a dilute solution of sodium carbonate.
Dispose of all contaminated materials in accordance with current local
regulations.

7. HANDLING AND STORAGE

A. PRECAUTIONS FOR SAFE HANDLING

: Protect from physical damage.

10페이지 중 4페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

B. CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES)

Avoid contact with eyes. Store in a cool, dry, ventilated area away from sources
: of heat, moisture, incompatibilities, and direct sunlight. Have emergency
equipment (for fires, spills, leaks, etc.) readily available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

A. OCCUPATIONAL EXPOSURE LIMIT(S), BIOLOGICAL EXPOSURE STANDARD

OSHA-PEL 0.05 mg/m3 (Lead), 1 mg/m3 (Sulfuric acid), 0.5 mg/m3 (Antimony)

TWA 0.05 mg/m3 (Lead), TWA 0.2 mg/m3 (Sulfuric acid)

ACGIH-TLV
TWA 0.5 mg/m3(Antimony)

B. APPROPRIATE ENGINEERING CONTROLS

: Use local exhaust ventilation if necessary to control airborne mist and vapor.
C. INDIVIDUAL PROTECTION MEASURES
If significant mists or aerosols are generated an approved respirator is
recommended. If respiratory protection is required, institute a complete
Respiratory protection :
respiratory protection program including selection, fit testing, training,
maintenance and inspection.
Eye protection : Wear safety glasses with side shields (or goggles).
Wear chemical resistant gloves. Gloves should be replaced immediately if signs
Hand protection :
of degradation are observed.

Use good work and personal hygiene practices to avoid exposure. Consider the
Body protection : provision in the work area of a safety shower and eyewash. Always wash
thoroughly after handling chemicals.

9. PHYSICAL AND CHEMICAL PROPERTIES

A. APPEARANCE (PHYSICAL STATE, COLOUR etc.) : Off-white cloudy liquid with solid object.
B. Odour : Characteristics.
C. ODOR THRESHOLD : Not available.
D. pH : pH < 1 (Sulfuric acid)
E. MELTING POINT/FREEZING POINT : Not available.
F. INITIAL BOILING POINT AND BOILING RANGE : Not available.
G. FLASH POINT : Non-flammable.
H. EVAPORATION RATE : Not available.
I. FLAMMABILITY (SOLID, GAS) : Not applicable.
J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS
: Non-flammable.
K. VAPOR PRESSURE : Not available.

10페이지 중 5페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

L. SOLUBILITY : Soluble in water.

M. VAPOR DENSITY : Not available.
N. SPECIFIC GRAVITY : Not available.
O. PARTITION COEFFICIENT OF n-OCTANOL/WATER: Not available.
P. AUTO-IGNITION TEMPERATURE : Not applicable.
Q. DECOMPOSITION TEMPERATURE : Not available.
R. VISCOSITY : Not available.
S. MOLECULAR WEIGHT : Mixture.
Note: These physical properties are typical values for this product.
A. APPEARANCE (PHYSICAL STATE, COLOUR etc.) : Bluish white, silvery gray.
B. Odour : None.
C. ODOR THRESHOLD : Not available.
D. pH : Not applicable.
E. MELTING POINT/FREEZING POINT : 327.5℃
F. INITIAL BOILING POINT AND BOILING RANGE : 1740℃ (1013 hPa)
G. FLASH POINT : Non-flammable.
H. EVAPORATION RATE : Not applicable.
I. FLAMMABILITY (SOLID, GAS) : Not applicable.
J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS
: Non-flammable.
K. VAPOR PRESSURE : 1.33 hPa (973℃)
L. SOLUBILITY : Insoluble in water.
M. VAPOR DENSITY : Not applicable.
N. SPECIFIC GRAVITY : 11.34 g/cm3
O. PARTITION COEFFICIENT OF n-OCTANOL/WATER: Not applicable.
P. AUTO-IGNITION TEMPERATURE : Not applicable.
Q. DECOMPOSITION TEMPERATURE : Not applicable.
R. VISCOSITY : Not applicable.
S. MOLECULAR WEIGHT : 207.2
Note: These physical properties are typical values for Lead(Pb).

10. STABILITY AND REACTIVITY

A. CHEMICAL STABILITY
: Stable at normal temperatures and storage conditions.
B. POSSIBILITY OF HAZARDOUS REACTIONS
: Hazardous polymerization will not occur.
C. CONDITIONS TO AVOID (STATIC DISCHARGE, SHOCK, VIBRATION etc.):
Overcharging. Sources of ignition. Mechanical impact. Contact with
:
incompatible chemicals.

10페이지 중 6페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

D. SUBSTANCES TO AVOID
: If a battery ruptures, avoid contact with organic materials and alkaline materials.
E. HAZARDOUS DECOMPOSITION PRODUCTS
Lead, Lead compounds and sulfuric acid fumes may be released during a fire
:
involving the product.

11. TOXICOLOGICAL INFORMATION

A. Information on the likely routes of exposure

Inhalation : Corrosive. severe irritation and burns.
Ingestion : Serious burns.
Eye/Skin
Tearing, redness, swelling, corneal damage, irreversible eye damage and
Eye :
severe burns.
Skin : Redness, swelling, burns and severe skin damage.
B. Delayed and immediate effects and also chronic effects from short and long term exposure
Acute toxicity (possible route of exposure) :
2140 mg/kg (Sulfuric acid),
Oral (LD50) : Rat
7000 mg/kg (Antimony)
Skin (LD50) : Not available.
Inhalation (LC50) : Rat 0.347 mg/L(4hr) (dust//mist)
Skin corrosion/irritation : cat 1
Serious eye damage/irritation : cat 1
Respiratory sensitization : Not available.
Skin sensitization : Not available.
Carcinogenicity : cat 1B

ACGIH Group A2, IARC Group 1 (Mist containing sulfuric acid)

* Note: Sulfuric acid mist is not expected under normal use of the product.
ACGIH Group A3, IARC Group 2B (Lead), IARC Group 3 (Polypropylene)

Germ cell mutagenicity : cat 2

Reproductive toxicity : Not available.
STOST-single exposure : cat 1
: Respiratory.
STOST-repeated exposure : cat 1
Hematopoietic system, kidney, central nervous system, peripheral nervous
:
system, cardiovascular system, immune system, respiratory.
Aspiration hazard : Not available.
C. Numeric measure of toxicity (such as acute toxicity estimates) - ATEmix
Oral (LD50) : Rat > 5,000 mg/kg

10페이지 중 7페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

Skin (LD50) : Not available.

Inhalation (LC50) : Rat 2.51 mg/L(4hr) (dust//mist)

12. ECOLOGICAL INFORMATION

A. Aquatic/terrestrial ecology toxicity

Fish (LC50) : Not available.
Daphnia (EC50) : Not available.
Algae (EC50) : Not available.
B. Persistence and degradability
Persistence : Not available.
Degradability : Not available.
C. Bioaccumulative potential
: Not available.
D. Mobility in soil : Not available.
E. Other hazardous effects : Not available.

13. DISPOSAL CONSIDERATIONS

A. DISPOSAL METHODS
Dispose of in accordance with local, state, and federal regulations. Hazardous
wastes must be transported by a licensed hazardous waste transporter and
: disposed of or treated in a properly licensed hazardous waste treatment,
storage, disposal or recycling facility. Consult local, state, and federal
regulations for specific requirements.
B. PRECAUTIONS (INCLUDING DISPOSAL OF CONTAMINATED CONTAINER OR PACKAGE)
Since emptied containers retain product residue, follow label warnings even
:
after container is emptied.

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (BL).
Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of
transportation.
A. UN NUMBER : UN 2794
B. UN PROPER SHIPPING NAME
BATTERIES, WET, FILLED WITH ACID, electric storage.
C. TRANSPORT HAZARD CLASS(ES) : 8
D. PACKING GROUP (IF APPLICABLE) : None.
E. MARINE POLLUTANT SUBSTANCES (APPLICABLE/NOT APPLICABLE)

10페이지 중 8페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

: Not Applicable.
F. SPECIAL PRECAUTIONS FOR USER : Not available.

15. REGULATORY INFORMATION

₪ INVENTORIES
EINECS/EU : Listed (EINECS No. 231-100-4(Lead), 231-639-5(Sulfuric acid))
TSCA/US : Listed.
ENCS/JAPAN : Listed (ENCS No. 1-527(Lead), 1-430(Sulfuric acid))
AICS/AUSTRALIA : Listed.
DSL/CANADA : Listed.
IECSC/CHINA : Listed.
PICCS/PHILIPPINES : Listed.
KECI/S.KOREA : Listed (KE-21887(Lead), KE-32570(Sulfuric acid))
₪ International Environmental Agreement
PIC : Not listed.
POPs : Not listed.
Ozone depletion : Not listed.
EU. Directive 67/548/EEC on the classification, packaging, and labelling of dangerous substances, Annex I
Classification : C; R35
Risk Phrases : R35
Safety Phrases : S1/2, S26, S30, S45
₪ U.S. Federal, Heanth and Environment) and U.S. Federal, Right-To-Know
CERCLA Section 103 (40 CFR 302.4)
: 10lb (4.535 kg) (Lead), 1000 lb (453.599 kg) (Sulfuric acid)
EPCRA (SARA Title III) Section 302 (EHS -TPQ)
: 1000 lb (453.599 kg) (Sulfuric acid)
EPCRA (SARA Title III) Section 304 (EHS - Reporting Quantities)
: 1000 lb (453.599 kg) (Sulfuric acid)
EPCRA (SARA Title III) Section 313 - Toxic chemical release reporting
Sulfuric acid (acid aerosols including mists, vapors, gas, fog, and other airborne
:
forms of any particle size)
OSHA Specifically Regulated Substances (29 CFR 1910.1001-.1052)
: Not applicable.
₪ CANADA REGULATORY INFORMATION
WHMIS Ingredient Disclosure List : Regulated.
NOTE: The regulatory information given above only indicates the principal regulations specifically applicable to the
product described in the Safety Data Sheet. The user's attention is drawn to the possible existence of additional
provisions which complete these regulations. Refer to all applicable national, international and local regulations or
provisions.

10페이지 중 9페이지
 Control No.

Material Safety Data sheet (MSDS) Date First May 16, 2017
Date Final May 23, 2022

16. OTHER INFORMATION

A. SOURCE OF DATA :
Guideline for Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
EC-ECB, International Uniform Chemical Information Database (IUCLID)
Hazardous Substances Data Bank (HSDB)
Registry of Toxic Effects of Chemical Substances (RTECS)
National Institute of Technology and Evaluatio -NITE (Japan).

NFPA 704 Standard System for the Identification of the Hazards of Materials for Emergency Response.

International Chemical Safety Cards(ICSC)(http://www.nihs.go.jp/ICSC)

3E Company/Ariel WebInsight DB.
B. THE DATE OF PREPARATION OF THE MSDS : May 16, 2008
C. THE DATE OF PREPARATION OF THE LATEST REVISION
: May 23, 2016
D. OTHER INFORMATION
:

The above information is believed to be correct but does not propose to be all inclusive and shall be used
only as a guide. Sebang Global Battery CO.,Ltd. shall not be held liable for any damage resulting from
handling or from contact with the above product. Each individual should make a determination as to the
suitability of the information for their particular purpose(s). Various government agencies may have
specific regulations regarding the transportation, handling, storage, use, or disposal of this product which
may not be covered by this MSDS. The user is responsible for full compliance.

Support on preparation of the GHS-MSDS: RGB Chemicals Co.,Ltd. +82-2-597-0645

10페이지 중 10페이지