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    6 views4 pages

    Structure of Atom

    Uploaded by

    Jane Evangeline

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    Dato: ‘Start Tim End Tim« CHEMISTRY SYLLABUS: Structure of Atom ‘Max. Marks : ‘Section! - Straight Objective Type ‘This secon contains 5 mupleccice questons. Each queston has 4 hoes (a) (0) (and), ut of which ONLY ONE scorect Ifthe kinetic energy of an electron is increased fur times, the wavelength of the de-Broglie wave associated with it ‘would become (@) one fourth () halt (©) fourtimes (@) twotimes 2. Anclestron, cis moving in the fifth stationary state, and ‘another electron e, is moving in the fourth stationary state, Timo : 60 min. ‘The radius of orbit ofclectron,¢, is five times the radius of atbitof letion,e, calculate the ato of velectyofeletron €\(v,) tothe velocity of electron e,(¥) @s1 O41 OLS OL the shortest wavelength ofthe spectral line ofl the Lyman series is X, then the longest wavelength of the linein Balmer series of Li?* is @) wo * © & @ as " 5 OF En @0OO_2 @0OO 3. OO0OO ‘Space for Rowgh Work Be 4. If we apply potential difference so that an electron is accelerated continuously in @ vacuum tube such that a decrease of 10% occurs in its de-Broglie wavelength, In sucha casethe change observed in kinetic energy ofeletron ‘willbe approximately (@)_adeerease of 11% (©) anincrease of 10% (0) anincrease of 11.1% (2) anincrease of 23.4% 5. Therato ofthe frequency coresponding tothe thir nein Lyman series of hydrogen alomic spectrum to that ofthe frst line in Balmer series of L* spectrum is s 4 3 o} oF oF ‘Section I|- Multiple Correct Answer Type “This sation contin 4 matiplecaec answers} ype queso. Each ‘qstonteas4 cies (2 (0), (ard (9), cut cf wich ONE OR MORE isezecorect 6 Theenergy ofan electron in the first Bohr orbit of H-atom is-136eV. Then, which ofthe following tatement()isfare ‘correct for He"? (@)_ The energy of electron in second Bohr orbit is =136eV (©) The kinetic energy of electron in the first orbit is 54460V (©). The kinetic energy of electron inthe second orbit is 16 (@ The speed of electron in the second orbit is 219% 106ms" 7. Identify the elements of lowes atomic numbers which have ‘the characteristics listed as below ‘A Eleven electrons B_oneclestron with m,=2 Two electrons with oa @ cuts. User @ ave @ anv 8 Tthewave numberof *tineofBalmer series of atoms “then {@)_ wavenumber of ine of yman series of Heo il 108s 3 (©) wavenumber of Mine oflyman series of Heo wll abe 5 ro con) (©) the wavelength of 2"line oftyman series of H-atom is ord (@ thewavelength of 2 line oftyman series of H-atom is Bx 3 ‘According to Bohr’ theory (@) when a roquired amount of energy is supplied to an clectron in an atom it jumps from lower obit to higher bit and remains there ‘when a roquired amount of energy is supplied to an electron in an atom it jumps from lower orbit to higher ‘orbit and remains there for very shot interval oftime and returns back to lower obi, radiating energy (©) the angular momentum ofan electron is proportional toits quantum number, ‘the angular momentum ofan electron is independent ofits quanturm number, n © @ ‘Section Il -Integer Type ‘Thissecten contans 5 questions, Teanswerioeactothe qestons isa singe igtnegerengngtom 009, 10. Suppose voc of an parce traveling tna the pucks ofa cope atom sons oariveat aden 10° mee Fhe icles the copper an ives yx 10 Then wha il be thal of? 1, Aneleton has sped of 30.00 em sc accurate upto (001% Whats the ucetintyn locating its aston. 12, the energies of two radiation of wavelength 800 nm aa 400 mare Ean epee Theale the vac oe, 13, The work insti ( ofsame metas lied below The numberof meals which will show potsetic eft thn light of 30 nm wavlengi fils on the meta is Meal Li Nak Mg Gu Ag Fe MW (eV) 24.23.2237 48 43 47 63 475 14. Inan atom how many obi) wil have the quanta numbers =3, Ss st Section IV - Comprehension Type Direction (Qs. 15-9): Besed upon the given paragraphs, Stil chic questons have tobe answered, Each question has 4 choies (6) and (ou of which ONLY ONE is coed. PARAGRAPHLL Directions (Qs. 15-17): By appropriately matching the information given nthe thee columns ofthe following table, give the answer ofthe questions tht follows. [Bohr’s theory successfully explains the hydrogen spectrum. It also explains the spectrum of some other one-lecron system (Hike stem) such as He’ Li, Beef With the help of Bobr’s theory we find ou, Radius ofthe orbit in which the electron is revolving around the nucleus, Energy of electron in an orbits, velocity and wavelength Column ‘Caan ‘Cobar dee? 2 Radius o Be ® AD) Velocity @ @ (Uy Energy «i ® 2 9) Wavelength w © Fxo0529 15, Theonlyecorret combination of formula forthe radius give in column lis © OMe ©) MEE © ows @ May@ 16, The only correct combination of formula forthe velocity ‘given in column Tis @ agin) © MOR © S) @) ain 17. The only correct combination of formula for the energy given in column Tis @ MDo@ © canaDe © aes @ aoe PARAGRAPH2 Radial wave funetion depends on and /but no¢on m-Thus ch of the three p-rbitas have the same radial form. The wave functions may have postive or negative regions but thei radial probability distributions (figure below) show the following features, 15.@O@OO_16.@0OO @®OO Radial distributions may have several peaks, the number ‘bing equal t (1), The outermost peak is by far the largest, showing where theeletron is mestlikely tobe found. The distance of this peak fom the nucleus is & measure of the radius ofthe cxbital ands oughly propertionalto7(although it slightly

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