No.

of Printed Pages : 12
4722
£vÄ Gs
A Register Number

!4722Chemistry! PART - III

÷Áv°¯À/CHEMISTRY
( uªÌ ©ØÖ® B[Q» ÁÈ / Tamil & English Version )

Põ» AÍÄ : 3.00 ©o ÷|µ® ] [ ö©õzu ©v¨ö£sPÒ : 70

Time Allowed : 3.00 Hours ] [Maximum Marks : 70

AÔÄøµPÒ : (1) AøÚzx ÂÚõUPЮ \›¯õP¨ £vÁõQ EÒÍuõ GߣuøÚ

\›£õºzxU öPõÒÍÄ®. Aa_¨£vÂÀ SøÓ°¸¨¤ß, AøÓU
PsPõo¨£õÍ›h® EhÚi¯õPz öu›ÂUPÄ®.
(2) }»® AÀ»x P¸¨¦ ø©°øÚ ©mk÷© GÊxÁuØS®
AiU÷PõikÁuØS® £¯ß£kzu ÷Ásk®. £h[PÒ ÁøµÁuØS
ö£ß]À £¯ß£kzuÄ®.
Instructions : (1) Check the question paper for fairness of printing. If there is any
lack of fairness, inform the Hall Supervisor immediately.
(2) Use Blue or Black ink to write and underline and pencil to draw
diagrams.

SÔ¨¦ : ÷uøÁ¯õÚ ChzvÀ £h® Áøµ¢x, \©ß£õkPøÍ GÊuÄ®.

Note : Draw diagrams and write equations wherever necessary.

£Sv - I / PART - I
SÔ¨¦ : (i) AøÚzx ÂÚõUPÐUS® Âøh¯ÎUPÄ®. 15x1=15
(ii) öPõkUP¨£mkÒÍ ©õØÖ ÂøhPÎÀ ªPÄ® Hئøh¯
Âøhø¯z ÷uº¢öukzxU SÔ±mkhß Âøh°øÚ²® ÷\ºzx
GÊuÄ®.
Note : (i) Answer all the questions.
(ii) Choose the most appropriate answer from the given four alternatives
and write the option code and the corresponding answer.

[ v¸¨¦P / Turn over

4722 2

1. J¸ TÌ©UPøµ\À ÁÈ÷¯ JÎUPØøÓø¯ ö\¾zx® ÷£õx PõnU QøhUS®

{PÌÄ :

(A) v›uÀ (B) GvºªßÁõ´ öuõ[P»ø\Ä

(C) ißhõÀ ÂøÍÄ (D) ªß•øÚU PÁºa]

The phenomenon observed when a beam of light is passed through a colloidal

solution is :

(a) Coagulation (b) Cataphoresis

(c) Tyndall effect (d) Electrophoresis

2. ]º÷PõÛ¯zvøÚ y´ø©¯õUP¼À ¤ßÁ¸® ÂøÚPÒ £¯ß£kQßÓÚ.

C®•øÓ __________ GÚ AøÇUP¨£kQÓx.

523 K
Zr(impure)+2I2  → ZrI4

1800 K
ZrI4  → Zr(pure)+2I2

(A) ¦»zy´ø©¯õUPÀ (B) E¸UQ¨ ¤›zuÀ

(C) ©õßm •øÓ (D) Áõß BºPÀ •øÓ

The following set of reactions are used in refining Zirconium. This method
is called as __________.

523 K
Zr(impure)+2I2  → ZrI4

1800 K
ZrI4  → Zr(pure)+2I2

(a) Zone refining (b) Liquation

(c) Mond’s process (d) Van Arkel process

A
 3 4722

3. ö£õ¸zxP.
(1) £õÀ©® (i) P»UP¨£mh QŸ®
(2) PÎ (ii) C[U
(3) ~øµ (iii) QŸ®
(4) TÌ© Pøµ\À (iv) öÁsön´
(A) (1) - (iv), (2) - (iii), (3) - (ii), (4) - (i)

(B) (1) - (iii), (2) - (i), (3) - (ii), (4) - (iv)

(C) (1) - (ii), (2) - (i), (3) - (iv), (4) - (iii)

(D) (1) - (iii), (2) - (iv), (3) - (i), (4) - (ii)

Match the following :
(1) Emulsion (i) Whipped Cream
(2) Gel (ii) Ink
(3) Foam (iii) Cream
(4) Sol (iv) Butter
(a) (1) - (iv), (2) - (iii), (3) - (ii), (4) - (i)
(b) (1) - (iii), (2) - (i), (3) - (ii), (4) - (iv)
(c) (1) - (ii), (2) - (i), (3) - (iv), (4) - (iii)
(d) (1) - (iii), (2) - (iv), (3) - (i), (4) - (ii)

4. DNA &ÂÀ Põn¨£k® ¤›ªiß Põµ[PÒ :

(A) ø\m÷hõ]ß ©ØÖ® øu¯ªß
(B) ø\m÷hõ]ß ©ØÖ® AiøÚß
(C) ø\m÷hõ]ß ©ØÖ® ²µõ]À
(D) ø\m÷hõ]ß ©ØÖ® SÁõøÚß
The pyrimidine bases present in DNA are :
(a) Cytosine and Thiamine
(b) Cytosine and Adenine
(c) Cytosine and Uracil
(d) Cytosine and Guanine

A [ v¸¨¦P / Turn over

4722 4

5. J¸ }›¯ Pøµ\¼ß pH ©v¨¦ §ä⯮ GÛÀ, A¢u Pøµ\À :

(A) |k{ø»zußø© öPõshx
(B) ]ÔuÍÄ Aª»zußø© öPõshx
(C) Põµzußø© öPõshx
(D) AvP Aª»zußø© öPõshx
The pH of an aqueous solution is zero. The solution is :
(a) Neutral
(b) Slightly acidic
(c) Basic
(d) Strongly acidic

6. ¥ÚõÀ |k{ø» ö£º›U S÷Íõøµkhß ÂøÚ¦›¢x u¸® {Ó® :

(A) Ahº £aø\ {Ó®
(B) ]Á¨¦ {Ó®
(C) GÆÂu {Ó•® E¸ÁõÁvÀø»
(D) Fuõ {Ó®
On reacting with neutral Ferric Chloride, Phenol gives :
(a) Dark green colour
(b) Red colour
(c) No colouration
(d) Violet colour

.. ..
7. GßÓ ÷\º©zvß IUPAC ö£¯º :
H2 N−CH2−(CH2 )4−CH2−NH2
(A) öí¨÷hß-1, 7-øh¯«ß (B) öíU\õö©zv½ß øh¯«ß
(C) öíU÷\ß-1, 6-A«ß (D) öíU÷\ß-1, 6-øh¯«ß
.. ..
IUPAC name for the amine H2 N−CH2−(CH2 )4−CH2−NH2
(a) Heptane-1, 7-diamine (b) Hexamethylene diamine
(c) Hexane-1, 6-amine (d) Hexane-1, 6-diamine

8. ö©õzu©õP 9650 T¿®PÒ ªßÞmhzøu¨ ö£ØÖÒÍ G»UmµõßPÎß

GsoUøP :
(A) 6.022×1022 (B) 6.22×1023
(C) 6.022×10−34 (D) 6.022×1024
The number of electrons that have a total Charge of 9650 Coulombs is :
(a) 6.022×1022 (b) 6.22×1023
(c) 6.022×10−34 (d) 6.022×1024

A
 5 4722

9. ¤ßÁ¸ÁÚÁØÖÒ sp2 CÚUP»¨¦ CÀ»õux Gx ?

(A) L¦À»›ß (B) QµõLø£m (C) øÁµ® (D) QµõL¥ß
Which of the following is not sp2 hybridised ?
(a) Fullerene (b) Graphite (c) Diamond (d) Graphene

→?
Rh/Ir AønÄ
10. CH3−CHO+CO 

(A) £õ¼ ¦µ¨¤½ß (B) ¤³mhß&1&AÀ

(C) A]miU Aª»® (D) A]m÷hm
Rh/Ir complex
CH3−CHO+CO  → ?
(a) Poly propylene (b) Butan-1-al
(c) Acetic acid (d) Acetate

11. E÷»õP SøÓ²ÒÍ SøÓ£õk Põn¨£k® £iP® :

(A) ZnO (B) NaCl (C) KCl (D) FeO
The crystal with a metal deficiency defect is :
(a) ZnO (b) NaCl (c) KCl (d) FeO

12. ¤ßÁ¸® ÂøÚ°À,

ÂøÍö£õ¸Ò ‘X’ BÚx __________ ÷\õuøÚø¯z uµõx.

(A) A÷¯õ÷hõL£õº® ÷\õuøÚ (B) hõ»ßì ÷\õuøÚ
(C) Lö£¼[ Pøµ\À ÷\õuøÚ (D) ÂUhº ÷©¯º ÷\õuøÚ
In the following reaction,

Product ‘X’ will not give :

(a) Iodoform test (b) Tollen’s test
(c) Fehling solution test (d) Victor Meyer test

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4722 6

13. J¸ ÂøÚ°ß ÂøÚ÷ÁP ©õÔ¼ ©ØÖ® öÁ¨£{ø»US Cøh÷¯¯õÚ

Áøµ£h® ¤ßÁ¸©õÖ. CÁØÖÒ öÁ¨£{ø» •Êø©US® AºïÛ¯ì
ußø©°øÚU SÔ¨¤k® Áøµ£h® :

(A) (B)

(C) (D) (B) ©ØÖ® (C) BQ¯ Cµsk®

Among the following graphs showing variation of rate constant with

temperature (T) for a reaction, the one that exhibits Arrhenius behaviour
over the entire temperature range is :

(a) (b)

(c) (d) Both (b) and (c)

A
 7 4722

14. ¤ßÁ¸® ÷\º©[PÎÀ E¸ÁõP Áõ´¨¤À»õu ÷\º©® Gx ?

(A) XeF 2 (B) XeOF 4

(C) NeF 2 (D) XeO 3

Which one of the following compounds is not formed ?

(a) XeF 2 (b) XeOF 4

(c) NeF 2 (d) XeO 3

15. K 4 Fe ( CN )6  &À Fe2+ &ß AønÄ Gs :

(A) 4 (B) 2

(C) 3 (D) 6

In K 4 Fe ( CN )6  , the co-ordination number of Fe2+ is __________.

(a) 4 (b) 2

(c) 3 (d) 6

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4722 8

£Sv & II / PART - II

SÔ¨¦ : H÷uÝ® BÖ ÂÚõUPÐUS Âøh¯ÎUPÄ®. ÂÚõ Gs 24 &US

Pmhõ¯©õP Âøh¯ÎUPÄ®. 6x2=12

Note : Answer any six questions. Question No. 24 is compulsory.

16. ÷£õµõUêß £¯ßPøÍz u¸P.

Give the uses of Borax.

17. Cøh{ø» uÛ©[PÒ ©õÖ£k® BU]á÷ÚØÓ {ø»Pøͨ ö£ØÖÒÍÚ. Hß ?

Why ‘d’ block elements exhibit variable oxidation state ?

18. A»S TmiøÚ Áøµ¯ÖUPÄ®.

Define unit cell.

19. BìÁõÀm }ºzuÀ Âvø¯U TÖP.

State Ostwald’s dilution law.

20. \©õÚ PhzxzvÓß. – Áøµ¯ÖUPÄ®.

Define equivalent conductance.

21. ªß£SÎU Phzxz vÓøÚ £õvUS® PõµoPøÍU SÔ¨¤kP.

Mention any two factors that affect electrolytic conductance.

22. ªßÚõØ \ÆÅk £µÁÀ GßÓõÀ GßÚ ?

What is meant by Electro Osmosis ?

23. ö£¨øhk ¤øn¨¦ £ØÔ ]Ö SÔ¨¦ ÁøµP.

Write a short note on peptide bond.

A
 9 4722

24. ¤ßÁ¸® ÂøÚ°À A ©ØÖ® B &I PshÔP.

From the following reaction, identify A and B.

£Sv - III / PART - III

SÔ¨¦ : H÷uÝ® BÖ ÂÚõUPÐUS Âøh¯ÎUPÄ®. ÂÚõ Gs 33 &US
Pmhõ¯©õP Âøh¯ÎUPÄ®. 6x3=18

Note : Answer any six questions. Question No. 33 is compulsory.

25. AønÄ Gs GßÓõÀ GßÚ ? bcc Aø©¨¤À EÒÍ J¸ AqÂß AønÄ

Gs ¯õx ?
What is meant by term “Coordination Number” ? What is the Coordination
Number of atoms in a bcc structure ?

26. ÷í»áß Cøha ÷\º©[PÒ GßÓõÀ GßÚ ? Cµsk GkzxUPõmkPÒ u¸P.

What are interhalogen compounds ? Give two examples.

27. Cµmøh E¨¦PÒ ©ØÖ® AønÄa ÷\º©[PÐUS Cøh÷¯¯õÚ

÷ÁÖ£õkPÒ ¯õøÁ ?
Give the difference between double salts and coordination compounds.

28. p &öuõSvz uÛ©[PÎÀ, •uÀ uÛ©zvß •µs£mh £s¦PÐUS

Põµn©õÚ PõµoPøÍU SÔ¨¤kP.
Mention the factors responsible for the anomalous behaviour of the first
element of p-block.

29. ªßÚõØ£SzuÀ £ØÔ¯ L£õµ÷h ÂvPøÍU TÖP.

State Faraday’s laws of electrolysis.

A [ v¸¨¦P / Turn over

4722 10

30. ¤ßÁ¸® ©õØÓ[PøÍ GÆÁõÖ {PÌzu»õ® ?

(i) Gzv½ß QøÍUPõÀ → A]mhõÀiøík
(ii) QÎ\µõÀ → AU÷µõ½ß
How are the following conversions effected ?
(i) ethylene glycol → acetaldehyde
(ii) glycerol → acrolein

31. Põº£õU]¼U Aª» öuõSvUPõÚ ÷\õuøÚPøÍz u¸P.

Give the tests for carboxylic acid group.

32. DNA ©ØÖ® RNA &US Cøh÷¯ EÒÍ H÷uÝ® ‰ßÖ ÷ÁÖ£õkPøÍ GÊxP.
Give any three differences between DNA and RNA.

33. ¤ßÁ¸ÁÚÁØøÓ \P¨¤øn¨¦ £iP[PÒ, ‰»UTÖ £iP[PÒ, A¯Û¨

£iP[PÒ AÀ»x E÷»õP¨ £iP[PÒ GÚ ÁøP¨£kzxP.
(i) øÁµ® (ii) ¤zuøÍ (iii) NaCl

(iv) |õL¨u½ß (v) SÐU÷Põì (vi) SiO2

Classify the following into covalent, molecular, ionic and metallic solids.
(i) Diamond (ii) Brass (iii) NaCl
(iv) Naphthalene (v) Glucose (vi) SiO2

£Sv & IV / PART - IV

SÔ¨¦ : AøÚzx ÂÚõUPÐUS® Âøh¯ÎUPÄ®. 5x5=25

Note : Answer all the questions.

34. (A) ~øµªu¨¦ •øÓ°øÚ ÂÁ›UPÄ®.

AÀ»x
(B) (i) P¢uP øh BUø\iß öÁÐUS® £s¤øÚ ÂÍUSP.
(ii) Ｏzvß H÷uÝ® Cµsk £¯ßPøÍz u¸P.
(a) Explain Froth flotation process.
OR
(b) (i) Explain the bleaching action of Sulphur dioxide
(ii) Write any two uses of Helium.

A
 11 4722

35. (A) (i) Cøhaö\¸PÀ ÷\º©[PÒ GßÓõÀ GßÚ ?

(ii) &À Põn¨£k® Cøn¯õPõu G»UmµõßPÎß
Ti 3+ , Mn 2+
GsoUøPø¯U PshÔP. ÷©¾® AøÁPÎß Põ¢uz v¸¨¦z
vÓß ©v¨¦PøÍU PshÔP.
AÀ»x
(B) (i) VB öPõÒøP°ß Áµ®¦PÒ ¯õøÁ ?
(ii) &BÚx Hß øh¯õPõ¢uz ußø©²øh¯x GßÖ
[Ni(CN)4]2− VB
öPõÒøP°ß Ai¨£øh°À ÂÍUSP.
(a) (i) What are interstitial compounds ?
(ii) Calculate the number of unpaired electrons in Ti3+, Mn 2+ and
calculate the spin only magnetic moment.
OR
(b) (i) What are the limitations of VB theory ?
(ii) Based on the VB theory, explain why [Ni(CN)4]2− is diamagnetic.

36. (A) (i) ÂøÚ÷ÁP® ©ØÖ® ÂøÚ÷ÁP ©õÔ¼ BQ¯ÁØÔØQøh÷¯¯õÚ

Cµsk ÷ÁÖ£õkPøÍ GÊxP.
(ii) A →ÂøÍö£õ¸Ò GßÓ §ä⯠ÁøP ÂøÚUPõÚ
öuõøP¨£kzu¨£mh ÷ÁP Âv°øÚ Á¸ÂUPÄ®.
AÀ»x
(B) 0.20 ÷©õÀ ¼mhº −1 ÷\õi¯® A]m÷hm ©ØÖ® 0.18 ÷©õÀ
¼mhº−1 A]miU Aª»® BQ¯øÁ P»¢xÒÍ J¸ uõ[PÀ Pøµ\¼ß
pH ©v¨ø£U PshÔP. A]miU Aª»zvß Ka ©v¨¦ 1.8×10−5.

(a) (i) Write two differences between rate and rate constant of a reaction.
(ii) Derive integrated rate law for a zero order reaction A → product.
OR
(b) Find the pH of a buffer solution containing 0.20 mole per litre sodium
acetate and 0.18 mole per litre acetic acid. K a for acetic acid is
1.8×10−5.

A [ v¸¨¦P / Turn over

 4722 12

37. (A) ö£ß\õÀiøíøh ¤ßÁ¸® ÷\º©[PÍõP GÆÁõÖ ©õØÖÁõ´ ?

(i) ö£ß\õ°ß
(ii) ]ßÚªU Aª»®
(iii) ©õ»øPm £aø\
AÀ»x
(B) (i) K›øn¯, D›øn¯ ©ØÖ® ‰Âøn¯ BÀPíõÀPøÍ ¿Põì
÷\õuøÚ°ß ‰»® ÷ÁÖ£kzxP.
(ii) øh GzvÀ Du›ß £¯ßPøÍU TÖP.
(a) How will you convert benzaldehyde into the following compounds ?
. (i) Benzoin
(ii) Cinnamic acid
(iii) Malachite green
OR
(b) (i) Differentiate primary, secondary and tertiary alcohols using Lucas
test.
(ii) Give the uses of diethyl ether.

38. (A) ÂøÚ÷ÁP ©õØÓ® £ØÔ¯ £µ¨¦ PÁºuÀ öPõÒøPø¯ ÂÁ›UPÄ®.

AÀ»x
(B) C 2 H 3 N GÝ® ‰»UTÖ Áõ´£õkøh¯ P›©a ÷\º©® (A), Na(Hg)/
C2H5OH Ehß JkUP©øh¢x C2H7N GÝ® Áõ´£õkøh¯ ÷\º©® (B)
&Iz u¸QÓx. ÷\º©® (B) Põºø£»«ß ÂøÚUS Em£kQÓx. ÷\º©®
(B) ø|mµì Aª»zxhß ÂøÚ¦›¢x ø|mµáøÚ öÁÎ÷¯ØÔ C2H6O
GßÓ ‰»UTÖ Áõ´£õkøh¯ ÷\º©® (C) &Iz u¸QÓx. A, B ©ØÖ®
C &IU PshÔ¢x ÂøÚPøÍ GÊxP.
(a) Describe adsorption theory of catalysis.
OR
(b) A compound ‘A’ of molecular formula C 2 H 3 N on reduction with
Na(Hg)/C2H5OH gives ‘B’ of molecular formula C2H7N which undergoes
carbylamine test. Compound ‘B’ on reaction with nitrous acid gives
compound ‘C’ of molecular formula C2H6O by liberating nitrogen. Identify
A, B and C and write the reactions involved.

-oOo-

A
No. of Printed Pages : 11
5922
£vÄ Gs
A Register Number

!5922Chemistry!
PART - III
÷Áv°¯À/CHEMISTRY
( uªÌ ©ØÖ® B[Q» ÁÈ / Tamil & English Version )

Põ» AÍÄ : 3.00 ©o ÷|µ® ] [ ö©õzu ©v¨ö£sPÒ : 70

Time Allowed : 3.00 Hours ] [Maximum Marks : 70

AÔÄøµPÒ : (1) AøÚzx ÂÚõUPЮ \›¯õP¨ £vÁõQ EÒÍuõ GߣuøÚ \›£õºzxU

öPõÒÍÄ®. Aa_¨£vÂÀ SøÓ°¸¨¤ß, AøÓU PsPõo¨£õÍ›h®
EhÚi¯õPz öu›ÂUPÄ®.
(2) }»® AÀ»x P¸¨¦ ø©°øÚ ©mk÷© GÊxÁuØS®
AiU÷PõikÁuØS® £¯ß£kzu ÷Ásk®. £h[PÒ ÁøµÁuØS
ö£ß]À £¯ß£kzuÄ®.
Instructions : (1) Check the question paper for fairness of printing. If there is any lack of
fairness, inform the Hall Supervisor immediately.
(2) Use Blue or Black ink to write and underline and pencil to draw
diagrams.

SÔ¨¦ : ÷uøÁ¯õÚ ChzvÀ £h® Áøµ¢x, \©ß£õkPøÍ GÊuÄ®.

Note : Draw diagrams and write equations wherever necessary.

£Sv - I / PART - I
SÔ¨¦ : (i) AøÚzx ÂÚõUPÐUS® Âøh¯ÎUPÄ®. 15x1=15
(ii) öPõkUP¨£mkÒÍ ©õØÖ ÂøhPÎÀ ªPÄ® Hئøh¯ Âøhø¯z
÷uº¢öukzxU SÔ±mkhß Âøh°øÚ²® ÷\ºzx GÊuÄ®.
Note : (i) Answer all the questions.
(ii) Choose the most appropriate answer from the given four alternatives
and write the option code and the corresponding answer.

[ v¸¨¦P / Turn over

5922 2

1. uÛ- © Á›- ø \ Am- h - Á - ø n- ° À, 15 &® öuõ- S v 3 &® Á›- ø \- ° À EÒÍ J¸

uÛ-©z-vß G»Um-µõß Aø©¨¦ :

(A) 1s2 2s2 2p6 3s2 3p2 (B) 1s2 2s2 2p4

(C) 1s2 2s2 2p6 3s2 3p3 (D) 1s2 2s2 2p3

An element belongs to group-15 and 3rd period of the periodic table. Its electronic
configuration would be :

(a) 1s2 2s2 2p6 3s2 3p2 (b) 1s2 2s2 2p4

(c) 1s2 2s2 2p6 3s2 3p3 (d) 1s2 2s2 2p3

2. £õU-øém-iß Cø¯-¦ :

(A) Al2O3⋅nH2O (B) Fe2O3⋅2H2O

(C) Al2O3 (D) CøÁ Gx-Ä-ªÀ-ø»

Bauxite has the composition :

(a) Al2O3⋅nH2O (b) Fe2O3⋅2H2O

(c) Al2O3 (d) None of the above

3. J¸ •uÀ ÁøP ÂøÚ-¯õ-Úx 60 {ª-h[-P-ÎÀ 75% {øÓ-Ä ö£Ö-Q-Ó-x. A÷u ÂøÚ,

A÷u {£¢-u-øÚ-P-ÎÀ 50% {øÓ-Ä ö£Óz ÷uøÁ-¯õÚ Põ-»® :

(A) 35 {ªh[PÒ (B) 20 {ªh[PÒ

(C) 75 {ªh[PÒ (D) 30 {ªh[PÒ

If 75% of a first order reaction was completed in 60 min, 50% of the same reaction
under the same conditions would be completed in :

(a) 35 minutes (b) 20 minutes

(c) 75 minutes (d) 30 minutes

A
 3 5922

4. ¤ß- Á - ¸ - Á - Ú - Á Ø- Ö Ò G¢u ÂøÚU Põ- µ o ø|m- ÷ µõ ö£ß- ^ øÚ AÛ- ½ - Ú õP

©õØ-Ö-Q-Óx ?
(A) ZnHg/NaOH (B) Zn/NH4Cl
(C) Sn/HCl (D) CøÁ AøÚz-x®
Which of the following reagent can be used to convert nitrobenzene to aniline ?
(a) ZnHg/NaOH (b) Zn/NH4Cl
(c) Sn/HCl (d) All of these

5. HO−CH 2 −CH 2 −OH &I ö£º-A-÷¯õ-iU Aª-»z-x-hß öÁ¨-£¨-£-kz-x® ÷£õx

E¸ÁõÁx :
(A) ö©z-u-ÚÀ
(B) ö©z-u-Úõ-°U Aª-»®
(C) CO2

(D) QøÍ-¯õU-\õÀ
HO−CH2−CH2−OH on heating with periodic acid gives :
(a) Methanal
(b) Methanoic acid
(c) CO2
(d) Glyoxal

6. E÷»õP A¯- Û - ° ß BU- ê - á - ÷ ÚØÓ Gs §ä¯ ©v¨- ¤ - ø Ú¨ ö£Ø- Ô - ¸ U- S ®

Aøn-Äa ÷\º-©® :
(A) K4 [Fe(CN)6 ] (B) [Fe(CN)3(NH3)3]
(C) [Fe(CO)5 ] (D) (B) ©Ø-Ö® (C) Cµs-k®
A complex in which the oxidation number of the metal is zero is :
(a) K4 [Fe(CN)6 ] (b) [Fe(CN)3 (NH 3)3 ]
(c) [Fe(CO)5 ] (d) Both (b) and (c)

A [ v¸¨¦P / Turn over

5922 4

7. ¤ß-Á-¸-Á-Ú-ÁØ-ÖÒ Gx ö»Í-›&¨-µõßì-hm Aª-»-©õ-P-Ä®, Põ-µ-©õ-P-Ä® ö\¯À-£h

•i-²-® ?

(A) HPO42− (B) HCl (C) Br − (D) SO42−

Which of the following can act as Lowry-Bronsted acid as well as base ?

(a) HPO42− (b) HCl (c) Br − (d) SO42−

8. ÷£õ-µõU-êß }ºU Pøµ-\-»õ-Úx :

(A) Põ-µz- ußø© Eøh-¯-x
(B) |k-{-ø»z ußø© Eøh-¯-x
(C) D›-¯À-¦z ußø© Eøh-¯-x
(D) Aª-»-z ußø© Eøh-¯-x
An aqueous solution of borax is :
(a) basic
(b) neutral
(c) amphoteric
(d) acidic

9. ¤ß-Á-¸-Á-Ú-ÁØ-ÖÒ Gx J¸-£-i-zuõÚ ÂøÚ-÷Á-P ©õØ-Óz-vØS Gkz-xU-Põmk ?

(A) Gs-ön-°ß øím-µ-á-÷ÚØ-Ó®
(B) ÷í£º •øÓ-°À A÷©õ-Û¯õ u¯õ-›z-uÀ
(C) }ºzu HCl •ß-Û-ø»-°À _U-÷µõ-]ß }µõØ-£-Sz-uÀ
(D) öuõk •øÓ-°À P¢-uP Aª-»® u¯õ-›z-uÀ
Which one of the following is an example for homogeneous catalysis ?
(a) Hydrogenation of oil
(b) Manufacture of ammonia by Haber’s process
(c) Hydrolysis of sucrose in presence of dil.HCl
(d) Manufacture of sulphuric acid by Contact process

A
 5 5922

10. A]m-÷hõ-Û-¼-¸¢x \¯-÷Úõ-øím-›ß E¸-Áõ-S® ÂøÚ ¤ß-Á-¸-Á-Ú-ÁØ-ÖÒ GuØS

\õ-ßÓõP EÒÍx ?
(A) G»Um-µõß PÁº ÷\º¨¦ ÂøÚ
(B) P¸-P-Áº £v-½mk ÂøÚ
(C) P¸-P-Áº ÷\º¨¦ ÂøÚ
(D) G»Um-µõß PÁº £v-½mk ÂøÚ
The formation of cyanohydrin from acetone is an example of :
(a) electrophilic addition
(b) nucleophilic substitution
(c) nucleophilic addition
(d) electrophilic substitution

11. ¤ß-Á-¸® BU]-á-÷ÚØÓ {ø»-P-ÐÒ, »õ¢-u-Úõ´-k-P-Îß ö£õ-x-ÁõÚ BU]-á-÷ÚØÓ

{ø» ¯õx ?
(A) +5 (B) +4 (C) +3 (D) +2
Which of the following oxidation states is most common among the lanthanoids ?
(a) +5 (b) +4 (c) +3 (d) +2

12. L£õ-µ÷h ©õ-Ô-¼ __________ GÚ Áøµ-¯-ÖU-P¨-£-k-Q-Ó-x.

(A) J¸ ÷©õÀ ö£õ-¸øÍ Âk-ÂUP ÷uøÁ¨-£-k® ªß-Þm-h®
(B) 1 G»Um-µõ-ÚõÀ _©¢x ö\À-»¨-£-k® ªß-Þm-h®
(C) 6.22×1010 G»Um-µõ-ÚõÀ _©¢x ö\À-»¨-£-k® ªß-Þm-h®
(D) 1 ÷©õÀ G»Um-µõ-ÚõÀ _©¢x ö\À-»¨-£-k® ªß-Þm-h®
Faraday constant is defined as :
(a) Charge required to deposit one mole of substance
(b) Charge carried by 1 electron
(c) Charge carried by 6.22×1010 electrons
(d) Charge carried by one mole of electrons

A [ v¸¨¦P / Turn over

5922 6

13. ¤ß-Á-¸® Aª-÷Úõ Aª-»[-P-ÎÀ Gx ^ºø©²-øh-¯x ?

(A) ¦÷µõ-¼ß (B) A»-Ûß (C) QøÍ-^ß (D) ¼²-]ß

Which of the following amino acids are achiral ?

(a) Proline (b) Alanine (c) Glycine (d) Leucine

14. E÷»õP SøÓ-²ÒÍ SøÓ-£õk Põ-n¨-£-k® £i-P® :

(A) ZnO (B) NaCl (C) KCl (D) FeO

The crystal with a metal deficiency defect is :

(a) ZnO (b) NaCl (c) KCl (d) FeO

15. ‰k-£-Û Gß-£x GÆ-ÁøP TÌ-©® ?

(A) Áõ-²-ÂÀ }º-©® (B) Áõ²ÂÀ vs-©®

(C) }º-©z-vÀ Áõ-² (D) Áõ-²-ÂÀ Áõ-²

Fog is colloidal solution of :

(a) liquid in gas (b) solid in gas

(c) gas in liquid (d) gas in gas

A
 7 5922

£Sv - II / PART - II

SÔ¨¦ : H÷u- Ý ® BÖ ÂÚõUPÐUS Âøh¯ÎUPÄ®. ÂÚõ Gs 24 &US

Pmhõ¯©õP Âøh¯ÎUPÄ®. 6x2=12

Note : Answer any six questions. Question No. 24 is compulsory.

16. PÛ-©® ©Ø-Ö® uõx BQ-¯-ÁØ-ÔØ-Q-øh-÷¯-¯õÚ ÷ÁÖ-£õ-k-PÒ ¯õøÁ ?

What are the differences between minerals and ores ?

17. Fe3+ ©Ø-Ö® Fe2+ &À Gx AvP {ø»¨-¦z ußø© Eøh-¯x ? Hß ?

Which is more stable Fe3+ or Fe2+ ? Why ?

18. AønÄ Gs – Áøµ-¯-ÖU-P-Ä®.

Define Coordination number.

19. \-P¨-¤-øn¨-¦¨ £i-P[-PÒ – Áøµ-¯-ÖU-P-Ä®.

Define covalent solids.

20. •uÀ ÁøP ÂøÚU-PõÚ Gkz-xU-Põm-k-PøÍ GÊ-x-P.

Give examples for the first order reaction.

21. AŸ-Û-¯ì öPõÒ-øP-°ß Áµ®-¦-PÒ ¯õøÁ ?

What are the limitations of Arrhenius concept ?

22. ªß-•-øÚU PÁºa] – SÔ¨¦ Áøµ-P.

Write a note on Electrophoresis.

A [ v¸¨¦P / Turn over

5922 8

23. IUPAC ö£¯-›-øÚU SÔ¨-¤-kP.

(A) (B)

Give the IUPAC names :

(a) (b)

24. ¤ß-Á-¸® ÂøÚÁ-›-ø\-°À EÒÍ A ©Ø-Ö® B ÷\º-©[-PøÍ Ps-h-Ô-P.

3NaN LiAlH
4 → B+ N
CH3 − Br  → A  2

Identify A and B in the following sequence of reactions.

3NaN LiAlH
4 → B+ N
CH3 − Br  → A  2

£Sv - III / PART - III

SÔ¨¦ : H÷u- Ý ® BÖ ÂÚõUPÐUS Âøh¯ÎUPÄ®. ÂÚõ Gs 33 &US

Pmhõ¯©õP Âøh¯ÎUPÄ®. 6x3=18

Note : Answer any six questions. Question No. 33 is compulsory.

25. íõ-»-á-Û-øha ÷\º-©[-PÒ Gß-ÓõÀ GßÚ ? Gkz-xU-Põmk u¸-P.

What are interhalogen compounds ? Give examples.

A
 9 5922

26. Cøha-ö\-¸-PÀ ÷\º-©[-P-Îß £s-¦-PÒ ¯õøÁ ?

What are the properties of interstitial compounds ?

27. Aº-ï-Û-¯ì \©ß-£õm-iøÚ GÊ-v AvÀ Ch® ö£Ø-ÖÒÍÁØøÓ ÂÍU-S-P.

Write Arrhenius equation and explain the terms involved.

28. ªß-£-S-ÎU Phz-xz-v-ÓøÚ £õ-vU-S® Põ-µ-o-PÒ ¯õøÁ ?

What are the factors that affects electrolytic conductance ?

29. J¸-£-iz-uõÚ ÂøÚ-÷Á-P ©õØ-Ó® Gß-ÓõÀ GßÚ ? Gkz-xU-Põmk u¸-P.

What is homogeneous catalysis ? Give example.

30. øh Gz-vÀ Duº u¯õ-›U-S® H÷u-Ý® J¸ •øÓ-ø¯ GÊ-x-P.

Write any one method of preparation for diethyl ether.

31. ÷í÷»õ-L-£õº® ÂøÚ-ø¯ GÊ-x-P.

Write Haloform reaction.

32. G¤-©º-PÒ Gß-ÓõÀ GßÚ ? Gkz-xU-Põmk u¸-P.

What are Epimers ? Give example.

33. [Ag(NH3)2]+ &ß DÛ, ø©¯ E÷»õ-P A¯Û ©Ø-Ö® IUPAC ö£¯-øµ GÊ-x-P.
Write the following for the complex [Ag(NH3)2]+.

(a) Ligand (b) Central metal ion (c) IUPAC name

A [ v¸¨¦P / Turn over

5922 10

£Sv - IV / PART - IV

SÔ¨¦ : AøÚzx ÂÚõUPÐUS® Âøh¯ÎUPÄ®. 5x5=25

Note : Answer all the questions.

34. (A) (i) ¦Â Dº¨¦ •øÓ – SÔ¨¦ Áøµ-P.

(ii) {U-P-ø»z y´-ø©-¯õU-P¨ £¯ß-£-k® ©õsm •øÓ-°øÚ ÂÍU-S-P.

AÀ-»-x-

(B) (i) ©¢u Cøn ÂøÍÄ Gß-ÓõÀ GßÚ ?

(ii) ÷£õ-›U Aª-»z-vß £¯ß-PÒ ¯õøÁ ?

(a) (i) Write a note on gravity separation method.

(ii) Explain the Mond’s Process of refining nickel.

OR

(b) (i) What is inert pair effect ?

(ii) What are the uses of boric acid ?

35. (A) (i) BU-ê-á-Ûß £¯ß-PÒ ¯õøÁ ?

(ii) \»-øÁz-yÒ GÆ-ÁõÖ u¯õ-›U-P¨-£-k-Q-Óx ?

AÀ-»-x-

(B) öÁº-Úº öPõÒ-øP-°ß ÷Põm-£õ-k-PøÍU TÖ-P.

(a) (i) What are the uses of oxygen ?

(ii) How will you prepare bleaching powder ?

OR

(b) Write the postulates of Werner’s Theory.

A
 11 5922

36. (A) £i-P vs-©[-PøÍ £i-P Ái-Á-©ØÓ vs-©[-P-Î-¼-¸¢x ÷ÁÖ-£-kz-x-P.

AÀ-»-x-
(B) (i) pH & Áøµ-¯-ÖU-P-Ä®.
(ii) ö£õx A¯Û ÂøÍøÁ J¸ Gkz-xU-Põm-k-hß ÂÍU-SP.
(a) Differentiate crystalline solids and amorphous solids.
OR
(b) (i) Define pH.
(ii) Explain common ion effect with example.

37. (A) ö|ºßìm \©ß-£õm-øhz u¸-ÂU-P-Ä®.

AÀ-»-x-
(B) ÂøÚ-÷Á-P ©õØ-Ô-°ß ]Ó¨-¤-¯À-¦-PÒ ¯õøÁ ?
(a) Derive an expression for Nernst equation.
OR
(b) What are the characteristics of catalyst ?

38. (A) L£õº-ªU Aª-»z-vß JkU-S® £s-¤øÚ Gkz-xU-Põm-k-hß ÂÍU-S-P.

AÀ-»-x-
(B) ]ÖSÔ¨¦ Áøµ-P.
(i) Põº-ø£-»-«ß ÂøÚ
(ii) Põ¨-›-¯À uõ-¼-ø©k öuõ-S¨-¦
(a) Explain the reducing action of formic acid with example.
OR
(b) Write a note on :
(i) Carbylamine reaction
(ii) Gabriel phthalimide synthesis

-o0o-

A [ v¸¨¦P / Turn over

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*********
DEPARTMENT OF CHEMISTRY
SHRI VIDHYABHARATHI MATRIC HR.SEC.SCHOOL
SAKKARAMPALAYAM , AGARAM (PO) ELACHIPALAYAM
TIRUCHENGODE(TK), NAMAKKAL (DT) PIN-637202
Cell : 6380839669

*********
SHRI VIDHYABHARATHI MAT.HR.SEC.SCHOOL, SAKKARAMPALAYAM. 99655-31727 Page 10
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 DIRECTORATE OF GOVERNMENT EXAMINATION, CHENNAI – 6
tt e t t
HIGHER SECONDARY SECOND YEAR EXAMINATION – MAY 2022
CHEMISTRY KEY ANSWER
lai NN
NOTE:
PP a
1. Answers written with Blue or Black ink only to be evaluated.
www ww
2. PART – I, choose the correct answer and write with option code. If one of them (option
or answer) is wrong, then award zero mark only.
MAXIMUM MARKS : 70
PART - I
15 x 1 = 15
TYPE - A TYPE - B
Q.No OPTION
P P aadd
ANSWER Q.No OPTION
P aadd
ANSWER
P
1s 2sw . .3s 3p
1 c
ww
2
w
2p2 6 2 3 1 c
www
Glycine
2 a Al O .nH O
2 3 2 2 a Methanal
3 d 30 minutes 3 a basic

i5
4 c Sn/HCl
Methanal
4
5
d FeO
Hydrolysis of sucrose in
aadd
a c
presence of dil.HCl
6 c
www
[Fe(CO)5] 6 c
wwww
Sn/HCl
7 HPO42- 7 charge carried by one
a d
mole of electron
8 t
a basic 8 a Al2O3 .nH2O
9
c Hydrolysis of sucrose in .9 d 30 minutes
presence of dil.HC
10 c nucleophilic additiona 10 a HPO42-
w
11 c +3 11 c w[Fe(CO) ]5

12 charge carried by one mole 12 +3

d c
of electron

i
13 c Glycine
i14
13 c 1s2 2s2 2p6 3s2 3p3
14 d FeO a liquid in gas
a
a
w. P c
15 liquid in gas 15 nucleophilic addition
w
1|Page
 PART – II

i iNNee
Q.No 24 is compulsory 6 x 2 = 12

Q.No ss
a Answer aas
Marks
d
16 P a and ores
Difference between minerals
w 2 x1
ww
Any two differences 2
17 Stability of Fe2+ & Fe3+

e t
Fe3+ is more stable 1
Half filled d orbital (or)
lai
d5 configuration
1 2
(or) Electronic configuration ofaa Fe3+
18
ww
Coordination number.P
.
wwww
Any one correct definition 2
19 Covalent solids

eet t
2
Correct definition
(or) 2
entirely by covalent bonds 1
20 PPaa
Examples of First order reaction

www
Any two examples
Equation (or) Explanation
2x1
2

21
tt
Limitation of Arrhenius concept
Two Limitations 2x1 2
22 Electrophoresis
Correct definition 2 2
23 IUPAC Names ww
a. 2-methyl propan-2-ol (or) 2- methyl -2-propanol 1 2
b t
phenyl methanol 1

a24a Identificaton of A & B compounds

A = CH3 - N3
aad a
(or) Methyl azide 1

w w P 1
2
3
w
B = CH - NH (or)
2 Methylamine

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 PART – III

et t
Q.No 33 is compulsory 6 x 3 = 18

a
Q.No
ssaal
Answer Marks
ss
PPa
25 Interhalogen compounds

w
Correct defini ion
Any one example
2
1
3

26 Properties of interstitial compound

eet 3x1 3
Any three properties
a
27 Arrhenius equation
1
3

Four terms explanation 4x½

28 Factors that affects electrolytic conductance
• Dielectric constant of Solvent
• Viscosity of the medium 3x1

a ad d
• Temperature of the solution a 3

w PP
•
w
Dilution of the solution
(Any three factors)
29 Homogeneous catalysis
ee
Correct definition
2

aalaa
3
Any one example (Equation (or) Explanation) 1
30
a ad
Preparation of diethyl ether
P P
Any one equa ion w
w(or)
w of preparation with suitable condition. 3
3

Equation without condition (or) Explanation only

2
31
e tt
Haloform reaction
e
Any one correct equation 3
3
(or)
Explanation only 2

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Q.No Answer Marks
ee
i Epimers
32
Correct explanation 2 3
Any one example 1
33
Ligand
www: NH
[Ag(NH3)2]+ complex
3 (or) ammine 1
3
Central metal ion : Ag+ (or) silver (I) ion (or) Ag (I) 1
et t
IUPAC name : diamminesilver(I) ion
t 1
a
PART – IV
5 x 5 = 25
ww
Answer all the questions
34 a (i) Gravity separation method

tt
Correct explanation
(or)
2

1
Any one example of ores
s5
(ii) Mond’s process

www
Two Correct equations with temperature
(or)
3

Equation without temperature (or) explanation only 2

34 b
et t
(i) Inert pair effect
Correct definition 2
(ii) Uses of boric acid 5

35 a
Any three use
w
(i) Uses of Oxygen
3 x1

Any two uses 2 x1

eet
(ii) Preparation of bleaching powder 5
Correct equation 3
(or)
Explanation only 2

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Q.No Answer Marks

ii
35 b Postulates of Werner’s theory
Five Postulates 5 x1 5

36 a PPaa
Crystalline and amorphous solids differences
5
www
5 x1
Any Five differences
36 b (i) pH definition

tt t
Correct definition (or) pH = -log10[H3O+] (or) pH = -log10[H+] 2
(ii) Common ion effect 5
Correct definition 2

w
Any one example (Equation (or) Explanation) 1
37 a ww
Nernst equation
½

1
½ +½
5
1

(or)

(or) 1

w wlog
Ecell = E°cell -
.

w
37 b Characteristics of catalyst
5
eet
Any Five characteristics 5x1

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aQ38iNo
i Answer
ll Marks
a
dda
Reducing action of formic acid

P as well as an acid group

Contains both an aldehyde
(or) 2

ww w
Any one example with correct equation
ww
3
(or)
Explanation only 2
38 b (i) Carbylamine reaction
t
Correct equation 2
(or)
Explanation only 1
www
5
(ii) Gabriel phthalimide synthesis
Correct equation 3
(or)
Explanation only.
2

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