safety data sheet

Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier
Product name Armaflex 520CN

Other means of identification

Synonym No information available

Recommended use and restrictions on use

Recommended use Adhesive for processing all flexible Armaflex insulation material (except
HT/Armaflex and Armaflex Ultima)
Uses advised against No information available

Details of the supplier of the safety data sheet

Supplier Armacell (Guangzhou) Limited
Address Guanqiao Industrial Park, Shilou Town Panyu, Guangzhou, China
Phone +86-20-8486-5693
FAX +86-20-8486-3373

Emergency contact
+86-20-8486-5693

2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids Category 2
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Reproductive toxicity Category 2
Specific target organ toxicity (single exposure) Category 3 (Narcotic effects)
Specific target organ toxicity (repeated exposure) Category 2 (Nervous system)
Chronic aquatic toxicity Category 2

GHS label elements including precautionary statements

Pictograms

Signal word Danger

Hazard statements H225 - Highly flammable liquid and vapor.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H361 - Suspected of damaging fertility or the unborn child.
H336 - May cause drowsiness or dizziness.
H373 - May cause damage to organs through prolonged or repeated exposure
(Nervous system).
H411 - Toxic to aquatic life with long lasting effects.
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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Precautionary statements
Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
P264 - Wash thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
Response P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam
to extinguish.
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P312 - Call a POISON CENTER or doctor if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical advice/attention.
P314 - Get medical advice/attention if you feel unwell.
P391 - Collect spillage.
Storage P405 - Store locked up.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 - Store in a well-ventilated place. Keep cool.
Disposal P501 - Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

Primary hazards
No information available

Specific hazards
No information available

3. COMPOSITION/INFORMATION ON INGREDIENTS
Description Mixture
Chemical identification CAS No Component and composition -%
Hexane 110-54-3 30 - 60
Toluene 108-88-3 10 - 30
Acetone 67-64-1 10 - 30
Synthetic resins - 10 - 30
Additives - 1 - 10

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

4. FIRST AID MEASURES

Description of first aid measures
General advice Do not get in eyes, on skin, or on clothing. Remove contaminated clothing and
shoes. Do not breathe dust/fume/gas/mist/vapors/spray. In case of accident or
unwellness, seek medical advice immediately (show directions for use or safety
data sheet if possible).
Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing. Get medical advice/attention if you feel unwell.
Skin contact Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. Wash contaminated clothing before reuse. If skin
irritation persists, call a physician.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention.
Ingestion Rinse mouth. Get medical attention. Never give anything by mouth to an
unconscious person.

Most important symptoms/effects, acute and delayed

Causes skin irritation. Causes serious eye irritation. Suspected of damaging fertility or the unborn child. May cause
drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure (Nervous
system).

Indication of immediate medical attention and special treatment needed, if necessary

Treat symptomatically.

Protection of first-aid providers

No information available

5. FIRE-FIGHTING MEASURES
Suitable fire-extinguishing media
Suitable extinguishing media CO2, dry chemical, dry sand, alcohol-resistant foam.
Unsuitable extinguishing media Do not use straight streams.

Specific hazards arising from the chemical

Thermal decomposition can lead to release of irritating and toxic gases and vapors, such as carbon monoxide,
carbon dioxide.

Special protective actions for fire fighters

Evacuate personnel to safe areas. Move containers from fire area if you can do it without risk. Cool drums with
water spray. Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Stay
upwind. Ensure adequate ventilation, especially in confined areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency measures

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. ELIMINATE all
ignition sources (no smoking, flares, sparks or flames in immediate area). Take precautionary measures against
static discharges. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing.
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash
contaminated clothing before reuse. Wash thoroughly after handling.

Environmental precautions
Local authorities should be advised if significant spillages cannot be contained. Prevent entry into waterways,
sewers, basements or confined areas.

Methods and material for containment and cleaning up

Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national regulations (see Section 13).

7. HANDLING AND STORAGE

Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in
confined areas. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Take precautionary
measures against static discharges. Use personal protection recommended in Section 8. Avoid contact with skin,
eyes or clothing. Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat, sparks, flame and other
sources of ignition. Keep locked up and out of reach of children. Keep away from food, drink and animal feeding
stuffs. Store in accordance with local regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters/Occupational Exposure Limits
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Denmark European Union
Hexane (CAS #: 110-54-3) TWA: 50 ppm TWA: 500 ppm IDLH: 1100 ppm TWA: 20 ppm TWA: 20 ppm
S* TWA: 1800 mg/m3 TWA: 50 ppm TWA: 72 mg/m3 TWA: 72 mg/m3
(vacated) TWA: 50 TWA: 180 mg/m3
ppm
(vacated) TWA: 180
mg/m3
Toluene (CAS #: 108-88-3) TWA: 20 ppm TWA: 200 ppm IDLH: 500 ppm TWA: 25 ppm TWA: 50 ppm
(vacated) TWA: 100 TWA: 100 ppm TWA: 94 mg/m3 TWA: 192 mg/m3
ppm TWA: 375 mg/m3 Skin Skin
(vacated) TWA: 375 STEL: 150 ppm
mg/m3 STEL: 560 mg/m3
(vacated) STEL: 150
ppm
(vacated) STEL: 560
mg/m3
Ceiling: 300 ppm

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Acetone (CAS #: 67-64-1) STEL: 500 ppm TWA: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA 500 ppm
TWA: 250 ppm TWA: 2400 mg/m3 TWA: 250 ppm TWA: 600 mg/m3 TWA 1210 mg/m3
(vacated) TWA: 750 TWA: 590 mg/m3
ppm
(vacated) TWA: 1800
mg/m3
(vacated) STEL: 2400
mg/m3 The
acetone STEL does
not apply to the
cellulose acetate fiber
industry. It is in effect
for all other sectors
(vacated) STEL: 1000
ppm

Chemical name Latvia France Finland Germany Italy

Hexane (CAS #: 110-54-3) TWA: 20 ppm TWA: 20 ppm TWA: 20 ppm TWA: 50 ppm TWA: 20 ppm
TWA: 72 mg/m3 TWA: TWA: 72 mg/m3 TWA: TWA: 72 mg/m3 TWA: 180 mg/m3 TWA: 72 mg/m3
100 mg/m3 1000 mg/m3 Skin Ceiling / Peak: 400
STEL: 300 mg/m3 STEL: 1500 mg/m3 ppm
Ceiling / Peak: 1440
mg/m3
Toluene (CAS #: 108-88-3) TWA: 14 ppm TWA: 20 ppm TWA: 25 ppm TWA: 50 ppm TWA: 50 ppm
TWA: 50 mg/m3 TWA: 76.8 mg/m3 TWA: 81 mg/m3 TWA: 190 mg/m3 TWA: 192 mg/m3
STEL: 40 ppm TWA: 1000 mg/m3 STEL: 100 ppm Ceiling / Peak: 200 Skin
STEL: 150 mg/m3 STEL: 100 ppm STEL: 380 mg/m3 ppm
Skin STEL: 384 mg/m3 Skin Ceiling / Peak: 760
STEL: 1500 mg/m3 mg/m3
Skin
Acetone (CAS #: 67-64-1) TWA: 500 ppm TWA: 500 ppm TWA: 500 ppm TWA: 500 ppm TWA: 500 ppm
TWA: 1210 mg/m3 TWA: 1210 mg/m3 TWA: 1200 mg/m3 TWA: 1200 mg/m3 TWA: 1210 mg/m3
STEL: 1000 ppm STEL: 630 ppm Ceiling / Peak: 1000
STEL: 2420 mg/m3 STEL: 1500 mg/m3 ppm
Ceiling / Peak: 2400
mg/m3

Chemical name Poland Portugal Spain Switzerland Netherlands

Hexane (CAS #: 110-54-3) TWA: 72 mg/m3 TWA: 50 ppm TWA: 20 ppm Skin STEL: 144 mg/m3
TWA: 72 mg/m3 STEL: 400 ppm TWA: 72 mg/m3
STEL: 1440 mg/m3
TWA: 50 ppm
TWA: 180 mg/m3
Toluene (CAS #: 108-88-3) STEL: 200 mg/m3 TWA: 50 ppm S* Skin STEL: 384 mg/m3
TWA: 100 mg/m3 STEL: 100 ppm STEL: 200 ppm TWA: 150 mg/m3
STEL: 384 mg/m3 STEL: 760 mg/m3
TWA: 50 ppm TWA: 50 ppm
TWA: 192 mg/m3 TWA: 190 mg/m3
Acetone (CAS #: 67-64-1) STEL: 1800 mg/m3 STEL: 750 ppm TWA: 500 ppm STEL: 1000 ppm STEL: 2420 mg/m3
TWA: 600 mg/m3 TWA: 500 ppm TWA: 1210 mg/m3 STEL: 2400 mg/m3 TWA: 1210 mg/m3
TWA: 500 ppm
TWA: 1200 mg/m3

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Chemical name Norway United Kingdom Australia Austria Belgium

Hexane (CAS #: 110-54-3) TWA: 20 ppm STEL: 60 ppm 20 ppm STEL 80 ppm -
TWA: 72 mg/m3 TWA: STEL: 216 mg/m3 72 mg/m3 STEL 288 mg/m3
40 ppm TWA: 20 ppm TWA: 20 ppm
TWA: 275 mg/m3 TWA: 72 mg/m3 TWA: 72 mg/m3
STEL: 20 ppm
STEL: 72 mg/m3
STEL: 40 ppm
STEL: 275 mg/m3
Toluene (CAS #: 108-88-3) TWA: 25 ppm STEL: 100 ppm 50 ppm Skin -
TWA: 94 mg/m3 STEL: 384 mg/m3 191 mg/m3 STEL 100 ppm
Skin TWA: 50 ppm 150 ppm STEL STEL 380 mg/m3
STEL: 25 ppm TWA: 191 mg/m3 574 mg/m3 STEL TWA: 50 ppm
STEL: 94 mg/m3 Skin Skin TWA: 190 mg/m3
Acetone (CAS #: 67-64-1) TWA: 125 ppm STEL: 1500 ppm 500 ppm STEL 2000 ppm -
TWA: 295 mg/m3 STEL: 3620 mg/m3 1185 mg/m3 STEL 4800 mg/m3
STEL: 125 ppm TWA: 500 ppm 1000 ppm STEL TWA: 500 ppm
STEL: 295 mg/m3 TWA: 1210 mg/m3 2375 mg/m3 STEL TWA: 1200 mg/m3

Appropriate engineering control measure

Ensure adequate ventilation, especially in confined areas. Showers. Eyewash stations. Remove all sources of
ignition.

Individual protection measures, such as personal protective equipment (PPE)

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Hand protection Wear protective gloves.
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear suitable protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance physical state Liquid
Color Straw colored
Odor No information available
Odor threshold Not determined
Property
Melting point Not determined
Boiling point > 65 °C
Flash point ca. 20 °C
Explosive limit 1 - 13%
Vapor pressure Not determined
Vapor density >1
Relative density 0.82
Solubility Negligible
Partition coefficient: n-octanol/water Not determined
Viscosity 150 - 200 cPs
Molecular mass Not determined
pH Not determined
Evaporation rate Not determined
Flammability (solid, gas) Highly flammable liquid and vapor
Auto-ignition temperature Not determined
Decomposition temperature Not determined

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Other information
Explosive properties Vapors may form explosive mixtures with air
Oxidizing properties Not determined

10. STABILITY AND REACTIVITY

Reactivity/Incompatible materials
The mixture can react dangerously with strong oxidizing agents.

Chemical stability
Stable under normal conditions.

Possibility of hazardous reactions

Vapors may form explosive mixtures with air.

Conditions to avoid
Heat, flames and sparks. Strong heating. Incompatible materials.

Hazardous decomposition products

Carbon monoxide, carbon dioxide.

11. TOXICOLOGICAL INFORMATION

Effects on humans
Causes skin irritation. Causes serious eye irritation. Suspected of damaging fertility or the unborn child. May cause
drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure (Nervous
system).

Acute toxicity
Chemical name
Hexane (CAS #: 110-54-3)
Acetone (CAS #: 67-64-1)
Toluene (CAS #: 108-88-3)
Oral LD50 Dermal LD50 Inhalation LC50
25000 mg/kg ( Rat ) - 169 mg/L ( Rat ) 4 h
5800 mg/kg ( Rat ) - -
- 12200 mg/kg ( Rabbit ) 49 mg/L (Rat) 4 h

Skin corrosion/irritation
Causes skin irritation (Hexane, Toluene).

Serious eye damage/eye irritation

Causes serious eye irritation (Acetone).

Respiratory organ or skin sensitization

No sensitization responses were observed.

Germ cell mutagenicity

No information available.

Carcinogenicity
Chemical name IARC
Toluene (CAS #: 108-88-3) Group 3

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Reproductive toxicity
Suspected of damaging fertility or the unborn child (Hexane, Toluene).

Specific target organ toxicity

Single exposure: May cause drowsiness or dizziness (Hexane, Toluene, Acetone).
Repeated exposure: May cause damage to organs through prolonged or repeated exposure (Nervous system).

Aspiration hazard
No information available.

12. ECOLOGICAL INFORMATION

Ecotoxicity
Chemical name
Hexane (CAS #: 110-54-3)
Toluene (CAS #: 108-88-3)
Acetone (CAS #: 67-64-1)
Algae EC50
9.285: 72 h mg/L EL50
12.5: 72 h mg/L EC50
7200: 72 h mg/L EC50
Fish LC50 Crustacea EC50
12.51: 96 h mg/L LL50 21.85: 48 h mg/L EL50
31.7: 96 h mg/L LC50 92: 48 h mg/L LC50
9.24: 48 h mg/L EC50
8300: 96 h mg/L LC50 8450: 48 h mg/L LC50
18500: 48 h mg/L EC50

Persistence and degradability

Readily biodegradable (Hexane, Toluene).

Bioaccumulation potential
Chemical name Partition coefficient (LogPow)
Hexane (CAS #: 110-54-3) 3,9
Toluene (CAS #: 108-88-3) 2.73
Acetone (CAS #: 67-64-1) -0.24

Chemical name Bioconcentration factor (BCF)

Toluene (CAS #: 108-88-3) 90
Acetone (CAS #: 67-64-1) 0.69

Mobility in soil
No information available.

Mobility
No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Waste from residues/unused
products
Contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws
and regulations.
Disposal should be in accordance with applicable regional, national and local laws
and regulations.

14. TRANSPORT INFORMATION

Land (ADR)
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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

UN number 1133
Class 3
Subsidiary risk Not applicable
Packing group Ⅱ
Proper shipping name ADHESIVES containing flammable liquid
HIN No information available

Sea (IMDG)
UN number 1133
UN class 3
Subsidiary risk Not applicable
Packing group Ⅱ
Proper shipping name ADHESIVES containing flammable liquid
Marine pollutant P
Severe marine pollutant No

Sea (Annex Ⅱ of MARPOL 73/78 and the IBC Code)

Pollution category No information available
Ship type No information available
Product name Armaflex 520CN

Air (IATA)
UN number 1133
Class 3
Subsidiary risk Not applicable
Packing group Ⅱ
Proper shipping name ADHESIVES containing flammable liquid

Special precautions No information available

15. REGULATORY INFORMATION

According to SS 586: Part 3: 2014

Applicable national regulations

Workplace Safety and Health Act & Workplace Safety and Health (General Provisions) Regulations: The product
is subject to the SDS, labeling, PEL and other requirements in the Act/Regulations.
Environmental Protection and Management Act and Environmental Protection and Management (Hazardous
Substance) Regulations: This product is subject to the requirements in the Act/Regulation.
Maritime and Port Authority of Singapore (Dangerous Goods, Petroleum and Explosives) Regulations: This
product is subject to the requirements of this Regulations.
qq
International regulations
Chemical inventory status
Component AICS DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS TSCA
NCS
Hexane X X X X X X X X
110-54-3 ( 30 - 60 )
Toluene X X X X X X X X
108-88-3 ( 10 - 30 )

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 safety data sheet
Trade Name Armaflex 520CN

Current version: 1.0.0, issued: 16.12.2016 Replaced version: -, issued: - Region: Singapore

Acetone X X X X X X X X
67-64-1 ( 10 - 30 )
"-" Not Listed
"X" Listed

16. OTHER INFORMATION

Date of preparation of the latest revision of the SDS
Issue date 16-Dec-2016
Revision date 16-Dec-2016
Revision note Not applicable

Key/legend to abbreviations and acronyms used in the SDS

TWA - TWA (Time Weighted Average)
STEL - STEL (Short Term Exposure Limit)
Ceiling - Maximum limit value
TSCA - Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
IECSC - Chinese Inventory of Existing Chemical Substances
EINECS/ELINCS - European INventory of Existing Commercial chemical Substances/European LIst of Notified Chemical
Substances
ENCS - Japanese Existing and New Chemical Substances
KECL - Korea Existing Chemicals List
NZIoC - New Zealand Inventory of Chemicals
PICCS - The Philippine Inventory of Chemicals and Chemical Substances
AICS - The Australian Inventory of Chemical Substances

Key literature references and sources for data used to compile the SDS
ECHA: http://echa.europa.eu/
IFA GESTIS: http://gestis-en.itrust.de/nxt/gateway.dll?f=templates$fn=default.htm$vid=gestiseng:sdbeng
HSDB: http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
eChemPortal: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
NITE-CHRIP: http://www.nite.go.jp/en/chem/chrip/chrip_search/srhInput

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text

Author
Tabulation department REACH24H Consulting Group China, GHS Compliance Affairs Department
Tabulation staff Monica, Brad
Phone +86-571-8700-7530

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