-JEE 2024 Exam-

❑ Subject – Inorganic Chemistry

❑ Chapter – Chemical Bonding
OM PANDEY , IIT Delhi
Lecture No.- 1
 1 Oxides & Valency

2 Introduction to Bond

3 Lewis Dot Structure

ONE SHOT Video – All Exceptions +

JEE Mains/Adv. Questions
Today’s Targets 1 Lecture – History of Periodic Table + other
small topics
 Question

The electronegativity of aluminium is similar to :

A Lithium

B Carbon

C Boron

D Beryllium
 Question
The first ionization enthalpy of Na, Mg and Si, respectively, are : 496, 737 and
786 kJ mol–1. The first ionization enthalpy (kJ mol–1) of Al is :
[2022/29 July/Shift-1]
A 487

B 768

C 577

D 856
 Question

For electron gam enthalpies of the elements denoted as eg H, the incorrect
options is : [2023/1 February/Shift-2]

A egH (Cl) < egH(F)

B egH (Se) < egH(S)

C egH (I) < egH(At)

D egH (Te) < egH(Po)

 Question

The characteristics of element X, Y and Z with atomic numbers, respectively,

33, 53 and 83 are : [2021/16 March/Shift-2]

A X and Y are metalloids and Z is a metal

B X is a metalloid, Y is a non-metal and Z is a metal

C X, Y and Z are metals.

D X and Z are non-metals and Y is metalloid

X = 33 , As
Y = 53 , I
Z = 83 , Bi
 Question

The energy required to convert all atoms present in 2.4 g magnesium to Mg2+
ions if IE1 and IE2 of magnesium are 122 kJ mol–1 and 238 kJ mol–1 respectively
 Variable Oxidation State

Mn

Zn
 Oxides

Basic Oxides

Acidic Oxides

Amphoteric Oxides

Neutral Oxides
 Amphoteric Oxides

As Fe Sb Cr V Te

Zn Sn Be Al Pb Ga
ZnO
SnO
As2O3
SnO2
BeO Fe2O3

Al2O3
Sb2O3
PbO
Cr2O3
PbO2
Pb3O4
V2 O 5
Pb3O2
TeO2
Ga2O3
Basic Oxides Metals

Basic Oxides Amphoteric oxides Acidic Oxides

Li2O MnO2 CrO3

CaO TiO2 MnO3

MgO ZrO2
Mn2O7
Sc2O3
CrO Cr2O3 CrO3

MnO Mn2O3 MnO2 MnO3 Mn2O7

Oxidation State Acidity

SO2 SO3

Cl2O3 Cl2O6 Cl2O7

Acidic Oxides

Non-metal Oxide Metalloid oxides

Acidic Neutral As

Sb
B2O3 CO
Se
CO2 NO
Te
N2O
N2O5
Ge

P 2O5

Cl2O7
 Periodicity in nature of Oxides

Na2O MgO Al2O3 SiO2 P2O5 SO3 Cl2O7

CaO

SrO

BaO
 Question

Which of the following oxides are Acidic, Basic, Amphoteric respectively

[2020/9 Jan/Shift-2]

A MgO, P4O10, Al2O3

B N2O3, Li2O, Al2O3

C SO3, Al2O3, Na2O

D P4O10, Al2O3, MgO

Valence Electron & Valency
What is bond ?

Reason for bond formation

Tendency to gain stability

Tendency to acquire min. energy

Tendency to gain IGC

 Bond

Strong Bond Weak Bond

Covalent Bond Hydrogen Bond

Co-ordinate Bond Vander waal FOA

Ionic Bond

Metallic Bond
Covalent Bond Bond that involves the sharing of electrons to form
electron pairs between atoms
 Lewis Symbol No of dots = no of valence electron

Octet Rule
Atoms can combine either by transfer of electron from one atom to another atom
or by sharing of electrons in order to have an octet in their valence shell .
 Lewis Dot Structure
H2 Non-bonding Electrons

Lone Pair

Bond Pair
F2

O2
 Lewis Dot Structure

N2

Cl2

HCl
 Question
Three element of the 3rd period x, y, z such that the oxide of x is acidic, y is
amphoteric and z is basic, the order of atomic no. of three elements is
[2020/2 sep/Shift-1]
A x>y>z

B y>x>z

C z>x>y

D x>z>y