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  • Ellingam Diagram 10 Min

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    balramsolanki Solanki
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    The document presents an Ellingham diagram, which is a graph showing the relationship between the standard free energy change (ΔG) and temperature (T) for oxidation/reduction reactions of metals and their oxides. It includes oxidation/reduction reactions for several metals and metal oxides, and uses the diagram to determine which reactions are feasible based on the intersection of ΔG curves and temperature. Reactions with a negative ΔG are feasible.

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    Ellingam Diagram 10 min

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    The document presents an Ellingham diagram, which is a graph showing the relationship between the standard free energy change (ΔG) and temperature (T) for oxidation/reduction reactions of metals and their oxides. It includes oxidation/reduction reactions for several metals and metal oxides, and uses the diagram to determine which reactions are feasible based on the intersection of ΔG curves and temperature. Reactions with a negative ΔG are feasible.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    5 views4 pages

    Ellingam Diagram 10 Min

    Uploaded by

    balramsolanki Solanki
    The document presents an Ellingham diagram, which is a graph showing the relationship between the standard free energy change (ΔG) and temperature (T) for oxidation/reduction reactions of metals and their oxides. It includes oxidation/reduction reactions for several metals and metal oxides, and uses the diagram to determine which reactions are feasible based on the intersection of ΔG curves and temperature. Reactions with a negative ΔG are feasible.

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    © All Rights Reserved
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    of 4

    Ellingham Diagram

    Graph b/w G & T


    Thermodynamic principle of metallurgy

    2C + O2 2CO 2CO + O2 2CO2 C + O2 CO2

    G G G

    T T T
    Li Mn G

    Zn Fe
    K
    Cr Mn
    Ba
    Fe Al
    Sr
    Cd
    Mg
    Ca Co T
    Na Ni Al
    Mn3O4
    Sn Ag
    Mg Fe2O3 Al
    Pb
    Al Au Al
    Cu Cr2O3
    Pt Reductions of the oxide of the upper line is feasible by the
    Hg element represented by the lower line. If the difference is
    large, the reduction is easier.
    C + O2 CO2 G

    2C + O2 2CO

    2CO + O2 2CO2

    Reaction is Feasible ? T
    710°C
    FeO + C CO + Fe
    FeO + C CO + Fe
    FeO + CO CO2 + Fe
    FeO + CO CO2 + Fe
    G

    Mg + O2

    Al + O2

    1400°C
    At the point of intersection of the Al2O3 and MgO T
    curves the ΔG0 becomes ZERO for the reaction .

    Above 1400 °C which reaction is Feasible ? Mg + Al2O3 MgO + Al


    MgO + Al Al2O3 + Mg

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