GARDEN DEW RESIDENTIAL SCHOOL GARDEN DEW RESIDENTIAL SCHOOL

CLASS – XII (CHEMISTRY) CLASS – XII (CHEMISTRY)

MM:20 TIME: 45MIN
1. Activation energy of a chemical reaction can be determined by
(a) determining the rate constant at standard temperature
(b) determining the rate constants at two temperatures
(c) determining probability of collision
(d) using catalyst
2. According to Arrhenius equation rate constant k is equal to Ae-Ea/RT.
Which of the following options represents the graph of In k versus ?
MM:20 TIME: 45MIN
1. Activation energy of a chemical reaction can be determined by
(a) determining the rate constant at standard temperature
(b) determining the rate constants at two temperatures
(c) determining probability of collision
(d) using catalyst
2. According to Arrhenius equation rate constant k is equal to Ae-Ea/RT.
Which of the following options represents the graph of In k versus ?

3. Which of the following statement is not correct about order of a
reaction?
(a) The order of a reaction can be a fractional number.
(b) Order of a reaction is experimentally determined quantity.
(c) The order of a reaction is always equal to the sum of the
stoichiometric coefficients of reactants in the balanced chemical
equation for a reaction.
(d) The order of a reaction is the sum of the powers of molar
concentration of the reactants in the rate law expression.
4. Which of the following statement is correct?
(a) The rate of a reaction decreases with passage of time as the
concentration of reactants decreases.
(b) The rate of a reaction is same at any time during the reaction.
(c) The rate of a reaction is independent of temperature change.
(d) The rate of a reaction decreases with increase in concentration of
reactant(s).
5. Rate law for the reaction ‘B’ is doubled, keeping the concentration of
‘A’
constant, the value of rate constant will be
(a) the same (b) doubled (c) quadrupled (d) halved
6. The conversion of molecules X to Y follows second order kinetics. If
concentration of X is increased to three times how will it affect the rate
of formation of Y ?
OR
For a first order reaction, show that time required for 99% completion
is twice the time required for the completion of 90% of reaction.
7. A reaction is second order in A and first order in B.
(i) How is the rate affected on increasing the concentration of B three
times?
(ii) How is the rate affected when the concentrations of both A and B
are doubled?
8. The rate of a reaction quadruples when the temperature changes from
293 K to 313 K. Calculate the energy of activation of the reaction
assuming that it does not change with temperature.
9. The rate constant for the decomposition of hydrocarbons is 2.418 × 10 –
5s – 1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be
3. Which of the following statement is not correct about order of a
reaction?
(a) The order of a reaction can be a fractional number.
(b) Order of a reaction is experimentally determined quantity.
(c) The order of a reaction is always equal to the sum of the
stoichiometric coefficients of reactants in the balanced chemical
equation for a reaction.
(d) The order of a reaction is the sum of the powers of molar
concentration of the reactants in the rate law expression.
4. Which of the following statement is correct?
(a) The rate of a reaction decreases with passage of time as the
concentration of reactants decreases.
(b) The rate of a reaction is same at any time during the reaction.
(c) The rate of a reaction is independent of temperature change.
(d) The rate of a reaction decreases with increase in concentration of
reactant(s).
5. Rate law for the reaction ‘B’ is doubled, keeping the concentration of
‘A’
constant, the value of rate constant will be
(a) the same (b) doubled (c) quadrupled (d) halved
6. The conversion of molecules X to Y follows second order kinetics. If
concentration of X is increased to three times how will it affect the rate
of formation of Y ?
OR
For a first order reaction, show that time required for 99% completion
is twice the time required for the completion of 90% of reaction.
7. A reaction is second order in A and first order in B.
(i) How is the rate affected on increasing the concentration of B three
times?
(ii) How is the rate affected when the concentrations of both A and B
are doubled?
8. The rate of a reaction quadruples when the temperature changes from
293 K to 313 K. Calculate the energy of activation of the reaction
assuming that it does not change with temperature.
9. The rate constant for the decomposition of hydrocarbons is 2.418 × 10 –
5s – 1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be

the value of pre-exponential factor? the value of pre-exponential factor?

10. The following results have been obtained during the kinetic studies of 10. The following results have been obtained during the kinetic studies of
the reaction: the reaction:
2A + B → C + D 2A + B → C + D
Experiment [A]/ [B]/ mol Initial rate of Experiment [A]/ [B]/ mol Initial rate of
mol L-1 L-1 formation of D / mol L-1 L-1 formation of D /
mol L-1 min-1 mol L-1 min-1
I 0.1 0.1 6.0 x 10-3 I 0.1 0.1 6.0 x 10-3
II 0.3 0.2 7.2 x 10-2 II 0.3 0.2 7.2 x 10-2
III 0.3 0.4 2.88 x 10-1 III 0.3 0.4 2.88 x 10-1
IV 0.4 0.1 2.4 x 10-2 IV 0.4 0.1 2.4 x 10-2
Determine the rate law and the rate constant for the reaction. Determine the rate law and the rate constant for the reaction.