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    CamScanner 11-08-2022 22.35.41

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    Mustafa Khan

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    © All Rights Reserved
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    YT 6 No. of pages - 16 \-3¢ (M) MID-TERM EXAMINATION (2022-23) . CLASS : XI SUBJECT: CHEMISTRY (043) Time Allowed : 3 hours Maximum Marks : 70 Wma: 3 ue arf aia - 70 rarer Freer: 1 ast wer afar #1 2 awe 939 wea @ ot is Gel &, a, 4, 9 ot SF fami 2 3. Gsm 1 a 18 sehr va howe 2 velw eT | cin a 21 4 Gea Awe Wer 19 8 25 ae ala wy saa we BI wee oe a ia 4 5. Gs-1 A wer Wen 26 8 30 aH ay Ba We Zl Wee We i ast 2 6° Gea A wer dem 31 4 32 agate amenfta wer @i wolH wea 4 stat aT 2 7. -Ge-e Awe dem 33 4 35 Sh sata wer Bate wes ais ais a 2 8 we A anid arm ferred et 21 da arta fared sar 21 9. HereRet Herat cin tat Ho win a ornfa Tet zt GENERAL INSTRUCTIONS: 1. All questions are compulsory. 2. This question paper consists of 35 questions divided into five sections A, B, C, D and E. 3. Section A Q.No.1 to 18 are objective type questions. Carrying 1 mark each. 4. Section B question number 19 to 25 are very short answer type questions carrying, 2 marks each. 5. Section C question number 26 to 30 are short answer type questions carrying 3 marks each, 6. Section D question number 31 and 32 are of passage / case study based questions carrying 4 marks each. 7. Seetion E question numbers 33 to 35 are long answer type questions carrying 5 marks each, 8. There is no overall choice in question paper, only internal choices are available. 9. Use of calculators and long tables is not permitted. peer rrieas 1 XI-CHEMISTRY-M Scanned with CamScanner i WS-H (Section-A) » COB TH thay aad - One mole of CO; contains : @) 3 gatoms of Co, (b) 18.1 « 10" molecules of CO, (©) 6.02 x 10? atoms of O (6.02 « 10 atoms C St gata Fue dag at sasha atta af — The orbital angular momentum of an electron in a d-subshell is: h h (a) 65 (b) ao h 2h O oa a frafafan Ha gH a WE we wR A waa smart a uiatia gm? Which of the following atoms would most easily from a cation? @ B (bt) Ae © Si @ Cc NH #1 STH agi Fe eh fret-germ F - The shape of NH; is very similar to that of : (@) BH; (b) CH; . ©. CH @) SOF Wehr a wad aed gaat F fae aR salen Wena at wel Be The correct set of four quantum numbers for outermost electron of potassium (Z = 19) is : 1 1 4,1,0,4 31,0, 4 @. 41,0,5 O) ; © 4,0,0,4 @ 3,0,0,4 0,0, > 0,0, 2 XI-CHEMISTRY-M. Scanned with CamScanner frafafiaa Aa fra aa A ai ot 1 catenin aren oe ait 2? Which of the following clements never has an oxidation state +1? (@) F (bo) ce (©) Br @ 1 CHa at wad cat tht t C-H bond distance is the longest in: (@) CoH: (oe) GHs (©) CHs @) CoH frafatad acai A aad afr onftaw e+ Out of the following most metallic element is : (@) Mg ) K (Op ui @ Ca FER Seas F HER SI WaT : The hybridization of sulphur dioxide is: @ x (b) sp’ © sp (a) dsp? FA BT HT TTT aif — Select the incorrect statement: @ wh we Va a Fa BT ZI . Ice has less density than water. () Hau S are uaie Fa S facta set #1 Alcohol is soluble in water due to H-bonding. (oC) SF, ga stem Fram a wert tat 21 SF, follows the Lewis outer rule. XI-CHEMISTRY-M Scanned with CamScanner @ WH a wea ah a fire aa 21 Water has density more than ice. COFN.O wl srr wach Bag gy wa a cater wt Arrange C¢,F,N,O in increasing order of ionisation enthalpy? (@) O co; (b) NO; #t arard der onefat aifsral Draw resonating structures of NO; ion. auto" ms! ar SL aC ee Poet aR aT eT el ae eT? Calculate the wavelength of an electron moving, with @ velocity of 2x10" ms", (Given h = 6.634 * 10 JS, m= 9.1 * 10°! kg) cede snake o-oo Sra) ee aTSTATER Tel sete aT wT a sda? Define hydrogen bond. Is it forces? g' ind, Is it weaker or stronger than the vander ‘Waals 10 kg Hp 3it 20 kg #1 Hoe wa & fee fafa feat HCC(g) Ht AAT Br Uiteeert wifsre! Atria ee, ae 10 kg of Hy and 20 kj i -g of Cl, mixed to produce HCE.. C: of HC¢(g) formed. Identify the limiting reagent. clas Neen 7 XI-CHEMISTRY-M aa, Scanned with CamScanner 24, 25. G) frre eR nA gre sa’ apa aI AfeeT stg eM? What is the lowest value of ‘n’ that allows ‘d’ orbitals to exist? aaa F sept a den aan How many subshells are associated with n= 4? Taft NH; Wn HO eT ssi at safhfa fran agora ait 21 wena wet Yo one eto siren at orten arm ate 31 fader FIAT Although geometries of NH; and H,O molecules are distorted tetrahedral but bond angle in water is less than that of ammonia, Discuss. (b) seaVvOR OH, FET FS sre WOT FART Discuss the shape of C,H, the basis of hybridization. Frafafad wt 26 8 30 wg sata we ZI The following questions (26-30) are short answer type questions. 26. aewesthar. fagia $ agen frafetad smpsi st srafa sareu According to VSEPR theory draw the shape of following molecules. () Xe, (i) SF, (iii) NBs : ByzaVOR @ FF CH) FC RAMS Ht aT sta a eet 82 Whaat is the hybridization of carbon atoms in benzene (CsH,)? 8 ‘XI-CHEMISTRY-M mr Scanned with CamScanner 27. 28. (>) Fe A a froer sey ST afters ei 8? Which of the following maximum bond angle? H,0, CO2, NH, CHy (atta Ham fase S sre We WMD fH Be, sim, wT aif wai wet Tie? Use molecular orbital theory to explain why the Be; molecule docs not exist? N,0, Fak Ce wal 88 3a TH BifeT Among the elements N, O, F and Cé; pick out the element. (a) faaat afteas yer are bach 3? Which has highest first ionization gain enthalpy? fraat wad afte seo ecg afer weet 2? Which has most negative electron gain enthalpy? (©) faaat wad set wey fen 2? (b) Which has biggest atomic radius? @) & fem at sfeniia aif State Hund’s rule: (>) frefafaa et orem aif Account for the following: @ ae ware Ft waht sen aed 8? Bohr’s orbit are called stationary states. (Gi) Gm afar fade 4 A an wala ae eet 21 A moving cricket ball cannot have wave character. XE-CH Scanned with CamScanner 29. 30. @) 16g 88 er A ra wer at oT aT afar oT AY AAFC Calculate the amount of water produced by the combustion of 16 g of methane, () Ree & frat ate Baer AF 22 g CO,(g) area AT Tt 21 How many moles of methane are required to produce 22g CO;(g) after combustion? fafeatad 48 a a me Seaaeh afaata arr aqya BOT? Among the following pairs of orbitals which orbital will experience the ~ larger effective nuclear charge? (i) 28 3903s (2s and 3s) (i) 4d 39% 4f (4d and 48) (iii) 3d 88 3p (Bd and 3p) S-a (Section-D) Frfefiad wet 31 wa 32 de amenita wa #1 The following questions 31 and 32 case based questions. 31. Tate @ fey sit Frefefad weit st sat difse — We FG eg alan scien wens sta a at ae a aire fear st wet ti oi a wet aa aga, aciqea six data ict emt ifn an wie FS wa a wea at ont $1 safer fer salen when} fem a ser eh di ant at Sant sk ea Stoned at amet er nya gate Sonat Aa oneR-S aR A aa 31 sige sien eon aren} at Yat 1 safe Yasha salsa aon BRN feta & aftfiera st eaht 3 XL-CHEMISTRY-M Scanned with CamScanner @ Gi) Git) Read the passage and answer the questions follow: ‘An electron in an atom can be completely designated with the help of four quantum numbers. Out of these the first three i.e. principal (n), Azimuthal Ce) and magnetic (m) quantum numbers are obtained from the solution of Schrodinger wave equation, while spin quantum (s) arises from the spin of the electron around its axis whether clockwise or anticlockwise. Out of these principal quantum number tells about the size. Azimuthal quantum number about the shape, while magnetic quantum number signifies the orientation of the electron orbital. cael Ht aftrean Wen fad grr at ant 2? The maximum number of electrons in a sub-shell is given by : (a) €+2 (b) 4242 © e+) @ Jee+0, sP* cH cei fare 21 The electronic configuration of ,,P** is : (a). 1s?2s*2p*3s?3p? (b). 1s?2s?2p%3s? (c) |‘ 1s?2s?2p* (d)_1s?2s?2p"3s?3p%4s! feat feu ne wary # feat edaghi a frefetan acter cent det 8? n=3, €=2, m=0, §=-1/2 How many-electron in given atom have the following set of quantum numbers? n=3, £=2, m=0, s=—1/2 @ &) 18 78 (@)__ not possible n XI-CHEMISTRY- i ee ’ Scanned with CamScanner Gy) UH ANY Hate wr onffeena fivaat gra Prifsr ean 27 32, The orientation of an atomic orbital is govern by : () NAG aet Wer (>) aphtqert salen dear Principal quantum number Azimuthal quantum number (©) fer aan Hen (d)) Waar aaien FAI Spin quantum number Magnetic quantum number SAAVOR d-sTaT + fae sniqaa aaier den 2 : ‘The value of azimuthal quantum number for d-subshell is : (a) 2 (b) 1 © 3 @ 0 maia a ofgu sik freafatiar weal @ oer aera - weagit aerotaer fret faq me aca fee feR vet t - weer A we anh frk aa? fe ae ae fre eet aa a YS ti ait ae ara af wat 21 fee ot a Te aime 4 fee war S aa a we a] Fast oeafad wet ar amet St 3 fread at F ary ant oA Read the passage and answer the questions follow: The electronegativity, of any given element is not constant. It varies depending on the element to which it is bound though it is not a measurable quantity. It does provide a means of predicting the nature of force that holds a pair of atoms together a relationship that you will explore later. XI-CHEMISTRY-M Scanned with CamScanner cecil @ Gi) (iii) (iv) @ Si ara S dat Hem Ft Sepia Fda Ya aa 37 The correct order regarding the clectronegativity of hybrid orbitals of carbon is? (@) spsp*sp*> sp (a) sp sp? Frafefad, aris wow angio, ani A a aad aftr fepia wer $7 Among the following C, S, N, B, the most electronegative element is : f) ¢C (b+) N © Ss @ B BeaVOR Wad ofire faeia scion 2 : Most electronegative halogen is : @ F () ce ©) Br @ 1 NC, Siait Pat fags soe wa He: The increasing order of electronegativity of elements N, C, Si and P is : @ P

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