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SANKALP BATCH
Solutions Practice Sheet-05

1. Correct expression for relative lowering of vapour 6. Find the molality of an aqueous solution of urea
pressure of a dilute solution. which has a boiling point of 102.08°C.
PA0 − PA nA (Take Kb = 0.52 K kg mol–1)
(1) =
PA0 nB − nA (1) 1 (2) 2
(3) 3 (4) 4
PA0 − PA nB
(2) =
PA0 nA + nB 7. The boiling point of an azeotropic mixture of water-
PA0 − PA nB ethanol is less than that of both water and ethanol.
(3) = Then.
PA nA + nB
(1) The mixture will show negative deviation from
PA0 − PA nB Raoul’ts law
(4) =
PA0 nA (2) The mixture will show positive deviation from
Raoult’s law
2. Find elevation in boiling point of a solution obtained (3) The mixture will show no deviation from
by dissolving 90g of glucose in 200 g off water. Raoult’s law
(Kb of H2O = 0.52 K kg/mole) (4) This mixture cannot be considered as true
(1) 2.6 K (2) 5.3 K solution
(3) 1.3 K (4) 4.2 K
8. Calculate the relative lowering in vapour pressure
3. Find molar mass of a non-volatile solute whose 20g (RLVP) if 100g off a non-volatile solute of molar
on dissolving in 500g of water produces a solution mass 100g/mol is dissolved in 432g of water.
having boiling point = 105.2°C. (1) 0.04 (2) 0.07
[Kb = 0.52 k kg mole–1] (3) 0.06 (4) 0.09
(1) 8 g mol–1 (2) 6 g mol–1
(3) 4 g mol –1
(4) 12 g mol–1 9. Find boiling point of deci molal aqueous solution of
glucose. (Kb = 0.52 K kg/mole)
4. 30g of a non-volatile solute is dissolved in 360g of (1) 373.052 (2) 473.052
water at 100°C. If vapour pressure of solution is 570 (3) 573.052 (4) 273.052
mm of Hg, find molar mass of solute.
(1) 5.5 g (2) 4.5 g 10. One mole of non volatile solute is dissolved in two
(3) 6.5 g (4) 7.5 g mole of water. The vapour pressure of the solution
relative to that off water is
5. The temperature at which the vapour pressure ofa 2 1
(1) (2)
liquid becomes equal to the atmospheric pressure is 3 3
known as 1 3
(3) (4)
(1) Boiling point 2 2
(2) Freezing point
(3) Absolute temperature
(4) None of these
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ANSWER KEY

1. (4) 6. (4)

2. (3) 7. (2)

3. (3) 8. (1)

4. (2) 9. (1)

5. (1) 10. (2)

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Hint and Solution

1. (4) 5. (1)
PA0 − PA nB At boiling point vapour pressure of liquid
= = atmospheric pressure
PA0 nA + nB
For dilute solution 6. (4)
nA + nB  nA
ΔTb = K b m
PA0 − PA n
 = B
PA0 nA 102.08 − 100 = 0.52m

2.08
2. (3) m= =4
0.52
ΔTb = K b  m
90 / 180
m= = 2.5 7. (2)
200 / 1000 Theoretical
ΔTb = 0.52  2.5 = 1.3K
8. (1)
nB
3. (3) RLVP =
ΔTb = K b m nA + nB
5.2 = 0.52(m) 432 100
nA = ;n B =
5.2 18 100
m= = 10 100
0.52
 RLVP = 100
mole 432 / 18 + 100 / 100
= 10
500 / 1000 1
500  10 = = 0.04 .
mole = =5 25
1000
20 20 9. (1)
=5M = = 4gram / mol ΔTb = K b m
M 5
1
Tb − Tbo = 0.52  
4. (2)  10 
PA0 − PA n B Tb − 373 = 0.052  Tb = 373.052K
=
PA nA
10. (2)
At 100°C, V.P. of water = atmospheric
nsolute = 1 n H 2O = 2
Pressure = 760 mm of Hg
 P°A = 760 mm of Hg P = P° × solute
P 1 1
760 − 570
30 = Xsolute = =
 = M P 1+ 2 3
570 360
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