Professional Documents
Culture Documents
Cet Sail Chemistry
Cet Sail Chemistry
CAIL!
S
with
SCIENCE
VOLUME 2: SCIENCE
III. Chemistry
CET sail with
SCIENCE
Topic Outline
III. Chemistry
1. Unit conversion
2. Elements, compounds, and mixtures
3. States of Matter
4. Periodic Table
5. Electron Configuration
6. Chemical Reactions
7. Stoichiometry and Balancing Equations
8. Gas Laws
E T
CAIL!
S
1 CET Sail: Chemistry 2023
I. UNIT CONVERSION
International System of Units (SI)
commonly known as the metric system
the international standard for measurement
made up of 7 base units that define the 22 derived units with special names
and symbols
SI Base Units
time t second s
mass m kilogram kg
thermodynamic
T kelvin K
temperature
I. UNIT CONVERSION
Image retrieved
from nist.gov
3 CET Sail: Chemistry 2023
I. UNIT CONVERSION
Conversion Factor
a fraction in which the numerator and denominator are the same quantity
expressed in different units
this fraction is always equal to 1
may be multiplied to any given quantity without changing its value
does not affect the number of significant figures of the quantity being
multiplied to
Example:
1 in = 2.54 cm may be written as a conversion factor in two ways:
or
(canceling the unit in from the numerator and denominator leaves us with cm)
(the given quantity 10.00 in has 4 significant figures, so the final answer must
also have 4 significant figures, i.e., 25.40 cm)
4 CET Sail: Chemistry 2023
I. UNIT CONVERSION
Dimensional Analysis
the use of conversion factors in problem solving
allows for a systematic way of tracking units
Example 1:
An average adult has 5.2 L of blood. What is the volume of blood in cubic
meters?
Relevant conversions:
1 L = 1000 mL
1 mL = 1 cm³
100 cm = 1 m³
Example 2:
The density of silver is 10.5 g/cm³. What is its density in kg/m³?
Relevant conversions:
1000 g = 1 kg
100 cm = 1 m
5 CET Sail: Chemistry 2023
A. Pure Substance
substances that contain only one type of particle and have a fixed constant
structure
due to constant composition, it also has a fixed boiling and melting points.
B. Mixture
consists of different kinds of elements and compounds combined
physically and not chemically. Meaning, we can separate its
components using simple means
It does not have specific properties (e.g. boiling point and melting
point). These properties ultimately depend on what component is
dominant in the mixture.
7 CET Sail: Chemistry 2023
assumes the
assumes the
shape and fixed volume
shape of the part
volume of its and shape
of its container
container rigid - particles
particles can
particles can locked into
move/slide past
move past one place Similar to a gas
one another
another Cloud of ionized
particles
not easily not easily
Electrons
compressible compressible compressible
separated from
lots of free space little free space little free space
the nuclei
between particles between between
Found in flames,
particles particles
lightning, and
does not flow auroras
flows easily flows easily easily
particles can particles can rigid - particles
move past one move/slide past cannot
another one another move/slide past
one another
From: https://www.science-sparks.com/what-is-matter/
10 CET Sail: Chemistry 2023
From: https://www.britannica.com/
11 CET Sail: Chemistry 2023
From: https://sciencenotes.org/periodic-table-groups-and-periods/
12 CET Sail: Chemistry 2023
Transition Metals
Big block in the middle of the table
All are metals with varying properties (e.g. Iron, Copper,
Gold, Titanium, etc.)
Metalloids
Diagonal line/staircase on the right side
Have properties between metals and non-metals
Mainly used in semiconductors and electronics (Silicon)
Halogens
2nd to the last column
Reactive and generally toxic/dangerous
Chlorine, bromine, iodine, etc.
Noble Gases
Last column
Complete electron shells
Very Unreactive; rarely participate in reactions
14 CET Sail: Chemistry 2023
From: https://sciencenotes.org/periodic-table-trends/
Periodic Trends
Ionization Energy:
Energy needed to remove an electron from the atom
Electronegativity:
Strength of attraction between electrons and the nucleus
Atomic radius:
General size of the atom
Metallic/nonmetallic character:
How “metallic” an element is (shiny, conductive, malleable, and ductile)
15 CET Sail: Chemistry 2023
From: https://sciencenotes.org/electron-affinity-trend-and-definition/
Periodic Trends
Electron Affinity:
Energy released when an atom gains an additional
electron/how readily an atom receives an electron
GENERALLY follows electronegativity trend
16 CET Sail: Chemistry 2023
V. ELECTRON
CONFIGURATION
What is an Orbital? Shell? Subshell?
Orbital
It is a likely region where electrons would be found around a nucleus
Has an associated energy level. It is like the potential energy
between the negative electron and the positive nucleus
Subshells
Are made of multiple orbitals in the same energy level
Shells
Are made of subshells
SHELLS contain SUBSHELLS which contain ORBITAL.
Quantum Numbers
There are 4 values that can describe the properties of an electron in
an atom: n, l, mₗ, and mₛ
From: https://byjus.com/chemistry/quantum-numbers/
17 CET Sail: Chemistry 2023
V. ELECTRON
CONFIGURATION
1. Principal Quantum Number (n)
Designates principal electron shell of a specific electron
Can be a positive integer
2. Angular Momentum Quantum Number/Azimuthal Quantum Number (l)
Designates the shape of an electron subshell (s, p, d, or f)
Subshells fall under an electron shell
s: l = 0
p: l = 1
d: l = 2
f: l = 3
Can take any values from 0 to (n-1)
3. Magnetic Quantum Number (mₗ)
Describes the orientation of a given orbital and the number of orbitals in
one subshell
E.g. a p orbital may be aligned along the x-axis, y-axis, or the z-axis.
Therefore, there are 3 unique p orbitals
For an orbital with a value l, ml takes a value from -l to l
E.g. a p orbital with l = 1 can have mₗ of 1, 2, or 3
Note: Each shell has its own set of subshells and orbitals, so 2 shells can
have 2 different sets of p orbitals.
18 CET Sail: Chemistry 2023
V. ELECTRON
CONFIGURATION
s, p, d, and f, Orbitals
From: https://byjus.com/chemistry/quantum-numbers/
19 CET Sail: Chemistry 2023
V. ELECTRON
CONFIGURATION
4. Spin Quantum Number (mₛ)
Gives the quantum spin of an electron
Independent of the previous 3 values
Either +½ or -½. Nothing else
Rules
1. Aufbau Principle
The “building up” rule
Electrons fill the orbitals
from lowest to highest
energy
s, p, d, and f are the
subshells indicated with
quantum number l
1, 2, 3, … are from the
principal quantum number
n, indicating the electron
shell
From: https://www.chemistrylearner.com/aufbau-
principle.html
20 CET Sail: Chemistry 2023
V. ELECTRON
CONFIGURATION
2. Hund’s Rule of Maximum
Multiplicity
When filling orbitals in the same
energy level, one electron must fill
all the orbitals BEFORE a second
can fill it
The electrons also must share the
same spin (up or down) when From: https://www.chem.ucalgary.ca/courses
filling the orbitals /351/mechanistic_etext/Ch01/ch1-2-2.html
V. ELECTRON
CONFIGURATION
Assigning Electron Configurations
1. Given an atom, find the number of electrons present. This is usually equal
to the number of protons aka the atomic number on the periodic table.
2. Fill up the orbitals following the pattern below until you reach the correct
no. of electrons.
The big number is n, the shell
The letters, s, p, d, and f are the subshells in a given shell
The exponent/superscript shows the maximum number of electrons in
the orbital
I.e. 2p⁶ can hold up to 6 electrons. 4d¹⁰ can hold up to 10, and so on
From: https://www.chem.fsu.edu/chemlab/chm1045/e_config.html
22 CET Sail: Chemistry 2023
V. ELECTRON
CONFIGURATION
3. Noble Gas Notation: As a shortcut, a large part of the electron
configuration can be shortened by using the electron configuration of a
noble gas.
Noble gases usually have full p orbitals
Instead of writing down the full configuration, everything until np6 can be
shortened into a noble gas form like [Ne] for 1s²2s²2p6
Example: Iodine
Longer version: 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁵
Noble Gas notation: [Kr]5s²4d¹⁰5p⁵
[Kr] is a shorthand for the electron configuration from 1s² to 4p⁶
4. Ions
Add (anion) or remove (cation) an electron from the count when assigning
electron configuration
Example:
Neutral Fluorine: 1s²2s²2p⁵
Fluorine anion: 1s²2s²2p⁶
23 CET Sail: Chemistry 2023
VI. CHEMICAL
REACTIONS
Chemical Reaction - is an interaction between molecules in which the bonds
are broken within reactant molecules, and new bonds are formed within
product molecules in order to form a new substance.
The rate of reaction depends on and is affected by factors like pressure,
temperature, the concentration of reactants.
Causes chemical change, i.e. color change, effervescence
It can be seen that the pure element reactant replaces an element in the
aqueous compound.
Chemical Equation
a written representation of a chemical reaction or a physical process
chemical species on the left side are reactants; right side, products
the physical state of each reactant and product is specified in parentheses
solid – (s)
liquid – (l)
gas – (g)
aqueous (i.e., dissolved in water) – (aq)
Stoichiometry
derived from ancient Greek words stoicheion (element) and metron
(measure)
refers to the use of numerical relationships between reactants and
products in a chemical reaction to determine desired quantitative data
Example:
Balance the chemical equation for the combustion of butane:
Avogadro’s Number (N A)
the number of atoms in exactly 12 grams of carbon-12, determined
experimentally
named in honor of Italian scientist Amadeo Avogadro (1776–1856)
equal to 6.022 x 10²³ (i.e., has no unit)
34 CET Sail: Chemistry 2023
Molar Mass
mass of one mole of a substance, expressed in g/mol
used to convert between moles and grams
the same as molecular mass and molecular weight (Note: mass and weight
are used interchangeably in Chemistry)
How many grams of NaOH are required to fully consume 3.10 g of H₂SO₄?
36 CET Sail: Chemistry 2023
Balancing Na:
Balancing O and H:
37 CET Sail: Chemistry 2023
Step 3: Convert moles of H₂SO₄ to moles of NaOH using the mole ratio.
Step 4: Convert moles of NaOH to grams of NaOH using its molar mass.
(final answer is expressed in 3 s.f. since the given mass of H₂SO₄ in the
problem is also 3 s.f.)
38 CET Sail: Chemistry 2023
Based on the kabobs analogy, mushrooms are the limiting “reagent” (LR)
while the skewers and beef are the excess “reagents” (ER).
39 CET Sail: Chemistry 2023
Since less NH3 is formed from N2, N2 is the limiting reagent (LR).
Charles’s Law
volume is directly proportional to temperature
Avogadro’s Law
volume is directly proportional to amount of substance
Note that the units for P, V, and T will depend on the unit of the gas
constant R.
Note: the product of volume and pressure gives units of energy (joules, calories)
43 CET Sail: Chemistry 2023
REFERENCES
Burdge, J., & Overby, J. (2012) Chemistry: Atoms first. McGraw-Hill
Higher Education.
https://byjus.com/chemistry
https://sciencenotes.org
https://www.chem.purdue.edu/gchelp/atoms/states.html
https://www.diffen.com/difference/Compound_vs_Mixture
ttps://www.khanacademy.org
https://www.livescience.com/28507-element-groups.html
https://www.science-sparks.com/what-is-matter/
https://www.scienceworld
About Us.
CET Sail is a non-profit, student-run project intended to help
senior high school students prepare for UPCAT 2024. Our target
demographic is those especially who have difficulty in Math &
Sciences and those who may not have immediate access to
reviewers due to financial reasons, yet are avidly preparing for
their examination.