重 庆 特 璞 滤 油 机 有 限 公 司

Chongqing TOP Oil Purifier CO., LTD

TP-800B microcomputer rapid sulfur

analyzer

Company: Chongqing TOP Oil Purifier Co., Ltd Web: http://www.topoilpurifier.com;www.toptester.com.cn

Add: No1 Jianlong North Rd, Jiulongpo District, Chongqing China Zip:400039
Tel: 0086-23-68677712 Fax: 0086-23-88901306 Email: sales3@topoilpurifier.com

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1. Overview

Smart a cervix sulfur, mainly used for determination of total sulfur in coal, steel, and

various mineral content. Therefore, the equipment is available for coal, electric

power, metallurgy, and geological exploration departments laboratory use.

The instrument is according to GB/T214-2007 "method for determination of the

total sulfur in coal" coulomb titration principle design. This method is based on

iodine coulomb titration agent, all the testing process USES the microcomputer

automatic control, and by the microcomputer to a variety of correction and the test

data, the Chinese show the percentage content of sulfur in coal, sample weight, date,

time, number, and print the results. Each time for about 5 minutes. Than the method

currently used hona ralf suess card weight analysis method and high temperature

burning neutralization method is rapid, accurate and intuitive. This machine use

color touch screen input data, intuitive and easy to operate, intelligent human

nature, etc, and is now in general use laboratory sulfur ideal measuring instrument.

2.The main technical indicators

Sulfur measurement range: 0-100%

Combustion analysis sample time: about 3 ~ 7 minutes

Temperature control, temperature measurement accuracy of 1.0, and external WRP

(S value) 10 - platinum platinum-rhodium thermocouple, heating body for silicon

tubes.

Heating speed: about 20 minutes from room temperature to 1150 ℃

Electrolytic cell: volume is 400 ml, electrolytic platinum electrode area of 10 mm * 15

mm, instructs the platinum electrode area of 5 mm x 10 mm

The stability of the instrument: boot after 20 minutes, the machine circuit at steady

state

Power supply: 220V + 10%, 50 Hz.

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3.Conditions of use

Ambient temperature: 5 ~ 40 ℃

Relative humidity: 85% or less

Installation environment: indoor should not have the intense heat, cold or corrosive

air, should as far as possible away from strong electromagnetic field equipment, do

not share a circuit with other high-power electrical equipment.

Carrier gas: dry acidic oxides of purify air, flow rate of 1000 ml/min.

Coal sample: particle size is less than 0.2 mm, each weighing about 50 + 5 mg.

Reagent, potassium iodide, potassium bromide, ice acetic acid are analytically pure;

Tungsten trioxide (or tungsten trioxide), sodium hydroxide as the chemical pure;

Color silica gel for industrial products.

4.The preparation of electrolyte and coal samples

Preparation of electrolyte; First said take 6 grams of potassium iodide, 6 grams of

potassium bromide, after waiting for it in 250 ml of distilled water, then add 10 ml

ice acetic acid. Electrolyte can be repeated use, with the length of time according to

the number of repeated use and the sample is high and low in sulfur and calm, but

should be 1 to 2 times before every experiment measurement (i.e., waste sample),

make a iodine iodine ion in the electrolyte on the electrode potential of the

numerical correction to the instrument, the PH of the electrolyte in 1 ~ 3, you can

use, but the PH value is less than 1, should be discarded.

Coal sample preparation: on the porcelain boat said take 50 + 2 mg of coal sample,

according to 0.1 mg, the thin covering a layer of tungsten trioxide or tungsten

trioxide, attention should be directly in the porcelain boat on weighing, cannot use

other instruments weighing in porcelain boat again, to ensure the accuracy of

weighing, ensure the accuracy of weighing is the premise to guarantee the accuracy

of the results.

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5.The installation of the instrument

The instrument is put on the workbench. Will open the instrument side cover, silicon

tubes in the furnace, and both ends are placed in (in furnace and the oven), the

steps of refractory baffle carefully pick good silicon tubes, lead by load line on the

receiving terminal. Insert the reducer silicon tubes, and put on the steps of the

furnace, should and must be seen from the mouth reducer is in place, then tighten

the top silk with a fixed reducer.

Put the thermocouples inserted into the furnace surface thermocouple hole, fixed

gently. Thermocouple wire thermocouple on the positive and negative side,

respectively. (negative side) to distinguish the thermocouple

The electrolytic cell of the air to purify the air in the socket.

Air pipe connection. According to the air purification device schematic will purify

device inlet with latex tube and electrolytic cell cover the outlet connection; The air

outlet on the purification plant latex tube connected to the furnace; Use the left side

reducer of furnace body, silicone tube and electrolytic cell inlet connection.

Deliver and install to quartz boat. To deliver great twist into the magnetic stripe.

Make rods on the oven door and directly in order to ensure a smooth landed on a

straight line. Then adjust the bar directly from high temperature furnace.

Connect the power cord: it is better to open, power cords, 220 v power supply,

grounding line.

6.Test steps

Open the host power supply, put the instrument to heat up.

For furnace temperature to 900 ℃, can open air pump, will put liquid electrolyte by

pipe to the electrolytic cell, and then put fluid pipe clamp good, check the

electrolysis pool of rubber plug must fort tight, close two-way valve again, to check

up on the gas tightness of electrolytic cell. Float down to near the bottom, such as

flowmeter indicates good air tightness, otherwise to eliminate leakage point.

Open the stirrer, stirring speed adjustment, in the case of ensure not lose step makes

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stirring speed as far as possible big, in principle, the higher the speed, the more

conducive to the analysis results are accurate.

Description: out-of-step phenomenon refers to the stirring rod rotation caused by

the rotating magnetic field are not synchronized with the blender stirring rod

jumping up and down. Experiments such as appear out of step phenomenon,

electrolytic phenomenon will then happened ─ electrolyte quickly become red,

with sulfur content screen fast counting.

Open the two-way valve, adjust knob of the flow meter, gets the flow rate of 1000

ml/min.

Keep ventilation state waiting for furnace temperature reach the set temperature, to

dry gas path, prevent moisture absorption sour gas in the gas path.

When temperature rose to a preset temperature, can begin experiment:

The first thing to do first sample 1 ~ 2 waste, the purpose is to balance the

electrolyte and instrument, a sign of balance is the instrument counting sulfur

content display screen appears. As soon as possible in order to not affect balance

and the formal experiment, suggest to return a coal sample between 1% ~ 2%

dedicated to do sample. Without weighing waste samples, but it must be like formal

test done by the instrument and interruptions.

Waste sample test is completed, can begin formal experiment. Such as two

experimental time interval greater than 5 minutes, advice and burning waste sample

at a time.

Test completely, can shut down the host power supply directly.

Close the air pump

Open the electrolysis pool of rubber plug, loose open fluid tube, release the

electrolyte, keep arrange another time to use again.

Suggestions for electrolytic cell with distilled water to clean.

Disconnect the instrument power brake.

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7. Operation method

Turn on the power switch and the instrument enters the main interface first.

The diagram below:

Directly click the button to enter the interface of test parameters

input. As shown in figure:

Click the item that needs to be modified to input parameters, and then press

"ok" to enter the test interface. As shown in figure:

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The rest of the work is done automatically by the instrument. When the test is

finished, the test data will be printed automatically and the test results will be

displayed. As shown in figure:

The "Up" key allows you to view the previous record.

"Down" to see the next record.

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 "Analyze" directly enters the next test input interface.

"Print" prints the current display.

"Return" to the main screen.

8.Equipment maintenance

 The instrument should be protected from dust and corrosive gases and used in

a dry environment. If it is not used for a long time, it should be covered with a

plastic cover and taken out and connected to the power supply regularly to

bake the moisture in the instrument.

 When the instrument is moved, it should be kept in case of vibration and

damage.

 A small amount of loose absorbent cotton should be added to the air path,

which is generally added in the pipeline on the right side of the two-way valve,

in order to prevent the flying ash from entering the glass molten plate of the

electrolytic cell with the air flow and causing blockage. When black precipitates

appear on sintered glass melting plate and its pipeline, it should be cleaned in

time. The preparation method of washing solution is: use 5 grams of potassium

dichromatate and 10 ml of water, heat and melt to cool down and slowly add

100 ml of concentrated sulfuric acid. The washing solution can wash the black

precipitates on the melting plate.

 If sintering glass plate is cleaned, the flow rate of the flow meter instructions still

amounted to less than 1000 ml/min, or 1000 ml/min can be obtained, but the

fuse board without bubbles or very little bubble, need to check each part of the

electromagnetic pump to the electrolytic cell is flat, including the connection of

the latex tube, silicone tube, gas purge line of rubber plug and the place such as

electrolytic cell.

 Do not touch the platinum pole of the electrolytic tank by hand, otherwise it will

prevent contamination. Once the platinum indicator electrode is contaminated,

the terminal control will fail, which often leads to overtitration. Use day long or

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 because of other reason the surface is stained, can use alcohol or acetone to

scrub, also can use toothpaste to grind its surface, rinse with clean water finally.

 The discoloration silica gel installed in the purification device shall be replaced in

time after complete discoloration to prevent water vapor from entering the

flowmeter and resulting in inaccurate indication.

 When adding the electrolyte and washing the cell, do not sprinkle the solution

on the plug and socket of the agitator, otherwise the terminal control will fail. At

this time, use ethanol or acetone to scrub the electrode. The plug of the cell shall

be reliably connected to the socket of the instrument.

 Standard calibration is carried out every 3-5 days to check whether the

combustion tube is broken or other parts are leaking air.

9.Troubleshooting of common faults

Fault condition Occurrence reason and elimination method

 Power not connected
1.Turn on the power, the  If a fuse is blown or an instrument fuse is
LCD screen is not bright. blown, replace it with a fuse of the same
specification.
 30A fuse burnt out or in bad contact; Replace.
 If the solid state relay is damaged, replace it.
 Silicon tubes rupture (approximately 10
normal Ω), for replacement.
2.After starting, there is no
 The connection clip of silicon carbon pipe is
furnace flow, combustion
burnt out and replaced.
furnace does not heat up.
 The connection line of silicon carbon pipe is
burnt out and open.
 Open, repair or replace the thermocouple.
 The instrument is not properly grounded,
regrounded.
3.Furnace temperature
 Thermocouple connection wire is loose,
display value big
reconnect to fix.
deviation.
 If the thermocouple burns out, replace it.
 The power supply voltage is unstable, add the
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 ac voltage regulator (>5KW).
 Furnace power contact is bad, reconnect and
fix.
 > 20 Ω silicon tubes has been aging,
4.The furnace heats resistance, change of silicon tubes.
slowly.  The power supply voltage is unstable, add the
ac voltage regulator (>5KW).
 The molten plate of the cell is blocked.
 Electromagnetic pump leather bowl is broken,
replace leather bowl.
5.Gas flow goes down.
 If the discoloration silica gel absorbs too much
water in the drying tube, replace the
discoloration silica gel.
 The sample rod is deformed, replace the
6.The sample is not in sample rod.
place.  The sample motor burns out, replace the
motor.
 The gap between the magnetic steel of
7.The agitator motor turns agitator and the top surface is too large.
on the agitator rod.  The agitator agitator magnetic force
weakened, should be replaced.
 If the printer plug is not inserted properly,
check whether the connector of the host
socket is normal;
8.The print is abnormal.  The computer board to the back panel of the
print line line break (multi - strand line has a
broken, that is, abnormal;
 The printer is broken.
 Gas path blocked, gas flow is not enough,
carry out the elimination.
 Electromagnetic pump suction force negative
pressure is too small, check the
9.The test results are electromagnetic pump leather bowl.
inaccurate  If the sample is not in place, please check
according to no.7.
 Low furnace temperature, reset furnace
temperature.
 Electrolyte failure, reformulation.
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  Contamination of electrolytic cell indicating
electrode or electrolytic electrode, clean with
toothpaste.
 Reduce pipe aging or fracture, replace
reducing pipe.
 The reducing pipe is connected with the
silicon pipe of the electrolytic cell and
ruptured. Replace the silicon pipe.
 The decomposition temperature is not
enough, adjust the furnace temperature.
 Correction coefficient is too high, reset the
correction coefficient.

10.Table: precision of total sulfur determination

The precision of total sulfur determination is specified in table 1 of GB/

t214-2007 as follows:

Reproducibility critical
Total sulfur mass fraction Repeatability limit
difference
St /% St,ad /%
St,d /%

≤1.5 0.05 0.15

1.50(do not contain)～

0.10 0.25
4.00

＞4.00 0.20 0.35

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