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Pearson
Pearson
A covalent bond occurs when atoms share electrons. The resulting cluster of atoms is called a molecule, and the
compound is considered to be molecular.
An ionic bond results from a transfer of one or more electrons from one atom to another. This creates oppositely
charged ions that group together into large macroscopic lattices as opposed to small clusters. For this reason,
ionic compounds are not considered to be molecular.
Generally, covalent bonds occur between two nonmetal atoms, whereas ionic bonds occur between a metal and
a nonmetal atom.
1 – mono
2 – di
3 – tri
4 – tetra
5 – penta
6 – hexa
7 – hepta
8 – octa
9 – non
10- dec
The use of the prefixes mono, di, and tri is also a sign that those compounds contain covalent bonds.
Those prefixes are not used in ionic compounds to specify the number of anions in the formula. However, there
are a few polyatomic anions that have prefixes in their name, such as dichromate.
How many grams are in 1.80 mol of Sodium Chloride (NaCl), Please express the answer in grams and a
breakdown of how the answer was derived.
Problem:
2. Use the given number of moles (1.80 mol) and the molar mass of NaCl to calculate the mass in grams:
- Mass = 105.192 g
So, there are 105.192 grams in 1.80 mol of Sodium Chloride (NaCl). Learn more about the Sodium
Chloride here.
Problem:
How many water molecules are in a block of ice containing 2.25 mol of water (H2O)?
Express the number of molecules numerically.
Problem:
A formula unit is the empirical formula used to communicate the chemical formula of ionic compounds. As
ionic compounds form giant lattice structures instead of molecules like molecular covalent compounds, we
represent their composition by the lowest ratio between the ions.
We are asked how many formula units make up 27.4 g of MgCl^2. To calculate this, we first convert the mass
of MgCl^2 to moles:
n = m/M
n = moles
m = mass
M = molar mass
The molar mass of MgCl^2 is obtained by adding the atomic molar masses of each atom. The atomic molar
masses are obtained from the periodic table:
n = m/M
n = 27.4 g / 95.21 g/mol
n = 0.288 mol
We can now convert the moles of MgCl^2 to formula units using Avogadro's number:
n = moles
NA = Avogadro’s number (6.022 x 10^23 formula units / mol)
Number of particles = n x NA
To learn how to convert grams to moles and to use the mole to find the number of atoms in a sample.
The mole (abbreviated mol) is a counting unit used to simplify calculations that would otherwise involve very
large numbers. The mole is equivalent to the number of carbon atoms in exactly 12g of isotopically pure 12C,
or 6.02×1023. This number is known as Avogadro's number in honor of Amedeo Avogadro.
Avogadro's number can be used as a conversion factor between moles and atoms, as shown here:
The molar mass of a substance is the mass of one mole of a substance and is written in units of grams per mole.
The molar mass of an atom is equivalent to its atomic mass, whereas the molar mass of a substance is
equivalent to its formula weight.
Problem:
An empirical formula expresses the simplest ratio of the atoms involved. The compound P4O10 has a P:O ratio
of 4:10. However, this ratio can be simplified to 2:5. Therefore, the empirical formula for P4O10 is P2O5.
Another example is hydrogen peroxide, which has the formula H2O2 and an empirical formula of HO.
One way that chemists analyze new or unknown compounds is to determine the percentage composition of
elements experimentally, which yields the empirical formula.
What is the empirical formula for the compound P4O6? (GCF) --- P2O3
A compound is 80.0% carbon and 20.0% hydrogen by mass. Assume a 100.- g sample of this compound.
Carbon = 80.0 g
Hydrogen = 20.0 g
6.66 / 6.66 = 1 C
19.84 / 6.66 = 3 H
A molecular formula expresses the number of each kind of atom in a molecule. For example, the molecular
formula for propene, C3H6, indicates three carbon atoms and six hydrogen atoms per molecule. This also
means that one mole of propene contains three moles of carbon and six moles of hydrogen. An empirical
formula expresses the mole ratio of the elements. The empirical formula for propene is CH2, indicating twice as
much hydrogen as carbon. When analyzing unknown compounds in a lab, it is often possible to identify the
mole ratios, and, thus, the empirical formula, but not the molecular formula.
Notice that the molecular mass of propene, 3(12) + 6(1) = 42 amu, is a multiple of the empirical formula mass,
1(12) + 2(1) = 14 amu.
An unknown compound contains only carbon, hydrogen, and oxygen (CxHyOz). Combustion of 5.50 g of this
compound produced 8.07 g of carbon dioxide and 3.30 g of water.
c. If 5.50 g of the unknown compound contained 0.183 mol of C and 0.367 mol of H, how many moles of
oxygen, O, were in the sample?
0.183 mol
d. What is the empirical formula of a substance that contains 0.183 mol of carbon, 0.367 mol of hydrogen, and
0.183 mol of oxygen?
(find smallest)
C = 0.183/0.183 = 1
H = 0.367/0.183 = 2
O = 0.183/0.183 = 1
Answer: CH2O
e. Determine the molecular formula for the unknown if the molecular mass is 60.0 amu, and the empirical
formula is CH2O? Express as a chemical formula, please help with the steps.
The empirical formula given is CH2O, which represents the simplest whole-number ratio of atoms in the
compound.
Explanation:
Now, let's calculate the molar mass of the empirical formula CH2O:
The given molecular mass is 60.0 amu. To find the multiple of the empirical formula that gives us this
molecular mass, we divide the given molecular mass by the molar mass of the empirical formula:
CH2O
C = 1 x 2 = C2
H = 2 x 2 = H4
O = 1 x 2 = O2
So, the molecular formula for the unknown compound is: C2H4O2
A. When a chemical reaction occurs, atoms rearrange to form new compounds, but no new atoms are created
nor are any destroyed. This concept is called conservation of mass. Mass conservation can be seen in a balanced
chemical equation, where the numbers of each kind of atom are the same on both sides of the reaction arrow.
Balancing equations with polyatomic ions. When balancing chemical equations with polyatomic ions, it may
help to balance the ion as a whole. For example, the ion PO43− can be treated as a unit and balanced in both the
reactants and the product, or you can break it down and balance each atom separately.
B. Phosphoric acid reacts with magnesium hydroxide to produce magnesium phosphate and water via the
following reaction:
?H3PO4+?Mg(OH)2→?Mg3(PO4)2+?H2O
Balance the equation, then enter the coefficients, in order, in the answer box. (2,3,1,6)
C. You carefully weigh out 19.00 g of CaCO3 powder and add it to 76.95 g of HCl solution. You notice
bubbles as a reaction takes place. You then weigh the resulting solution and find that it has a mass of 88.16 g.
The relevant equation is:
CaCO3(s)+2HCl(aq)→H2O(l)+CO2(g)+CaCl2(aq)
Assuming no other reactions take place, what mass of CO2 was produced in this reaction? (answer next page)
For example, the percent composition of water, H2O, is 11.2% hydrogen and 88.8% oxygen. Therefore, a 100-g
sample of water contains 11.2 g of hydrogen atoms and 88.8 g of oxygen atoms.
The periodic table will be useful when doing this problem. You can access a periodic table by clicking the
"Tools" link in the upper right corner of this page.
a. A hydrocarbon is a compound that contains mostly carbon and hydrogen. Calculate the percent composition
(by mass) of the following hydrocarbon: C6H14
= mass of C + mass of H
= 86.118 g
Explanation:
Percentage means a number, or a ratio represented in the form of fractions of 100.
b. A certain metal hydroxide, M(OH)2, contains 32.8 % oxygen by mass. What is the identity of the metal M?
Hydrates are solid compounds that contain water molecules. When hydrates are heated, the water molecules
evaporate, producing the anhydrous form of the compound. The formula of a hydrate may be written in two
different ways. For example, aluminum chloride hexahydrate can be written as [Al(H2O)6]Cl3 or as
AlCl3⋅6H2O. The first formula more accurately shows the bonding arrangement, whereas the second formula
makes it easier to see that the anhydrous form of the compound is aluminum chloride.
Magnesium sulfate heptahydrate, MgSO4⋅7H2O, is also called epsom salt. Epsom salt is often used in bath
salts as well as in gardening.
b. If 15.0 g of MgSO4⋅7H2O is thoroughly heated, what mass of anhydrous magnesium sulfate will remain?
Express your answer to three significant figures and include the appropriate units.