O The enthalpy of Combustion of methane, arojhite, and dé arcoyen at 298 K ane = 240°% kImot™!, “393-5 kT mot, ond ~ 285° kTmoto' eek ectvely Coltulate the 1 enthatoy of formation of we ‘ iD —— Qitege preecess » FOS of heat % absorbed by a tem and 394 7 of work ts done the ee ushat «the Change i irilerengl crerge for. the prlocem. | eC eis 5 The tceaélion of Cynamide , NH CN C9), Worth deoxy: in ¢ was carried ont. im a bomb’ calorimeter and ‘at tod fourd te ce -449°7 KI mot at 299K. Gletate a en thalty change for the teaaction at 24ekKk, NHCN (CQ) + 3 0, cH 7 No@ + Co, Ce) +HOW Ocatelate the maunbere of kg of heat nececcarcy fo tease —lhe bempercetarce off C0. 0 g of alienreeen dito 95°C te @ 55% © Mola Aeat pace of Nie es Os aypen nies. kon) ys te ale See oO Caleulata He enthalpy Change oH Frcoexing of Ov mol of wsatesc at L0°0°C tee pe Bois Aa 6-03 kImot! at OC. Us t G tote = 193 J mo" : \ pene Cy Eu 089") SO Poo ml VK | oe ul ee i _iaa© Enthal yy of Combuction of Carbon ta My &% ~ 34935 kT mot!. Calculate te seat reoloased “pan formation of 35°24 oF Coy dean Carbon amd ee ae —______ @ Enthapies of formation of CDQ s COs C4), NoOl and No Oy Cp we ~ 10, ~ 99 3 Aes £1, md 97 kJ mot”! reespeclively Fend “lhe value of AH dore de rteaction : NoOs CQ) + 8 CD ba) ——+ Net eee) (Gente (ates dias ete tlarc) enthalpy of foremation of CHOH WO freon the Follousing ate CHgOH (LY) + -% Oo t® % (Dp tq) + 20W; AH? 21-26 kgotn) ‘ C Cartaphite) + O& (p —+ 605 G) 5 Acth =~ 343 KS eno! ; aie se Hala) Ap Hee (@ Le Hyd L EA kT mol). Se 6h enthalpy wud for the teoaction : Ny Cg) + 34, Cg) ——7 NH % > ~99- 98 k Teoh"! at 298K. Caleale Be volus of aitarenal enercay Change (R= 34 aK! moll), aThe heat of Co mbealton of. C4 @p at consent volume and at 298K har been fourd te be -885 ky mola. Caleula the enthalp of ti Cormbuslion under Constant frcesuarte conditions (R= $314 T mark!) ® rhe enthalpy chanyp, tore phe treanaction of liquid canter Le steam , Alay % 40°38 kImol"! at 373K ec ety ene ee ree @ what uw ent reepy change fore He conversion of One otam of water te tee at 243 Ke ond one atmospheric freesenne) | AWS, = 6025 kJ mot" | ® Cat ealale entrtep Charge ushen 10 moles of an ideal ps ehh ree vercsbly and feather mally treom an @ initial volume of HO litte fe 100 Litre at O00 K. Soe aes eat Caleulate the tompercatarce at ushich liquid ewaterc usill be in ep wilébreivern tesith_ uaiter vapour | Ay A023 bo mec! ord ASvy = 0109 Tw’ (6) Fore the reaction, BOC, EA,O0 2 80, te etek the enthalp 4 of teedétion & 49°A kT eP and He enbrcepy of reaction 4 336 TK. Calculate AC» at MOK ond preediet” phe rare Sensibility of the "eaction. ,(Atay fore estore i AOTB UT enel"land Abvap @ oh 109 TK mol, Calealate the Tonporalare at ushich iputd teatee sill be tn eguclzbrium with wale vepoure. @ foe te renctton + 2NO op + og > NOs C4) the enthaloy and entiCops changes arto ~ BO KF mol! and -145 TK! tegheclively. Coleulale the Jempercala ne telous eashech thi readion - “ Abontaneous. | @ ® Clu (ae the ie enucy change of te rtoadGon ¢ | © Contapnsto + 0,04) ——% Cy (4) 1 AH =~ 200 kT mot” and AC = 37 Ko mol’ ot 2DK. Predeet ushethere oe reeaclion is _dpontancous ore not at 900 K . Th the rceaction Ny Gp + SH, <= 2 NHGCA at 299K. Exthapy and entteopy chan. ove. ~92°4 ki end = t9e-2 a reospectivel - Olealale es ConstanE KR. (Given RSe OIA LTE Ke! rot!) & Caleulate the eguilibritam Geet ee the Pitan reaction ot 299 1K ond 1 bare preerdurce — Ct) + HOt) —— CO wy +9 Cg) faiven, ApH" C10) =— 296+0 kT mol). Ay Weg) = —NO°5 kT mol! AS? fore the woactian = —252LE TK 'mal”' and R= $l. Tk nel! CHint & o or frcoblam no Gud D> AG = Rtn twhertse., Ko Oe Constant.