waston of wwork done in Case of adéobatice erceble eampan Séon § -%) honk ‘ h. 2 ns 10. of moles of ye ] _ Ra univercsal, tonyban ts Be O25 Gee Lent enpocity ob conalant eestn ela Kat ccs HE capt rere To feral voheet T) = Initeal Temnpercatntee . SS ee «. Bezal “foremnd of the Firat haus 5 Laus > ~ Pie sco, Se 0, ¢d0 udiz 0 re tuobeeremal: priodedd or Rs ATi= Oo 4020 é *Greopical representation of yo rucous thermo $—— Meobaruia proce. : AUsotherernal prrocew 5 a Adiabatic. proc Msochoru'e preocor. $e ee a Tt tk dined os Be tert heat 2 Con- Henk of the | eystisn ob Vtortint “freestulieg. or. Z me aldo be dexfened os the dum of Srterneal werergy 0) and fiCeie.rc0 ~ vO Lime GB (PY) ener- Ye of” & system. [Charny in ential (44) | 526 on eqmal te heat cobtorbed ott .evalved at domatant Preeteerwe ' at | vi | LJ ae_ Ci I I grieot absérebed. ore evolved at, consant” volume. = 44, ofr Yh 2 ere eg car |) oe naan eee eee A myy= AU + Ang RT | rs | | usherce ANg = Cher th no. 6£ ‘oles of gpseois | ne prodecté ands teeactanls - ; ey aA la) | -b b Bl Q Sang. at ge aaa then, re flea) - ai] ‘ entre 2» ushen Abs rer i Teadliors tones’ place om a belosed veAdel ot fixed volume; te Ay =O. seo We DIF: reaction trvelves ones + dolide) ore aqui Or delition but. no gpdebu > rapt wot fodiick, G68 “Anes o ® wien ttooction nt got pucous sheet tt Gnd freedacti bet dheere neembere of moles / E capa = ' Eau) at cn tp = ae "De e ' > Oa NE Lily Pea ’us qtecatere tha, thernimbere Of molds of, Op devi reeoctaents © FO Plly paw Pela Gd Sin.) ve e(le)-) 24, 70. \Cam—It lax AHA , cf An, > negative A NO. df mols’ of qaavow products ve Lod te Hei number “of moles of gadeow eadlants. cor hy Oo HP em Op: 4) Ath, 2 ) CD ee ethereal Dr gy of ah ond 40 # FW [ign oF a0 | a) of AU = potdlive,’ Intotnal ~ enerdgyr juste er oa absorbed ot Conant volume . ) Sor Endo thermic t2 badlivn, & AD + neopleve . Le G47 Focotharmic. xa reeacti ons « Lanterenal enewgy af He Aytern decteeadés. of AK DEP AW = posrtive, Heat fs: absorbed » at, tomlant prtesturce. eg at Encle Ere mic. reeodle nN, © Ane’ regatire, Beak ts re _ Preomtte Aystem at consont apreedtace. SAT Face there mie Tone Drs“Graphical Ro 2 pitede nlatiay | mes, He- He Ss Ate pe ? (Negal: ve) 3 pees a Ww Freog ress, ob} raaition (yerdntie €02aChdy reogreem of tteaclion | @® Encother mia roattidy Theemochemscal eg ceelion.s Ga vbalan ced - Cherrical ey cation -roton tre YlLortetoes of The dcbleremt tteaéten Bee plete He amount. of host evolved oe cited ete Called Wo remochantast egesliora. Withee cinpett Gant convenlork 2 | &d for eather mia teeaclions, AH = | : tndvcalee- te and. pied te for & . NEPAL Ve ane fre endo thermia Meacli on dH = spot ve. B dniew Olbere U9 ¢ee mentioned, AN valuon arte or. He etardared tae Of the tubstinees (te 299 K A bare” prcetbectca) ” 2 geen ae ; OTe cs cMacents of déffercent Avbslances repre Boe the no. of “proles rconeted, amd: foremed Lis % oot chan 9¢ reepreaerted tn the equation, Pr prysccal étata2 mutt be mentioned for ce¥fe reat: bubs tines, as heat evolved .. ote abdorebed defends a llOng the tw-ebfterenta of tha .dubstances’ atte Pret ed ore devided home number, the valuo of AN malliglied “or divided” by the Game ruby O rp the ttedction 4 tavertsel » the dayn of ay Changes but) the magnitude OAL VAL the Wire. Enthalyy of 10 oft teaacléon / heat of, reedaen The ambunt of Aedt gral or. absorbed Th a themécal tteaction ee the rumbere of mmoles of- the weactant, oo ceprce sented by the Chenceal equation have com sltely fected % called We, reat of nee Te i& "denoted by “Hee tymbel. > AH . Ctardared —enthal va Cheange - A TPO aie in ite mosk, stxble darem ab 25°C ore 248K under a preefsuree of 1 bare. &, Asgde to bee tr le Raines atte - ; pipet en gee Chan ob a arlene en “ll the teeaclante and the frteducts, arco ny these Gtardard state % known ar the _dtandantd enthalpy Change. MH ts Nenoted Ri 8 nee HW orugin of @ enthalpy. cheng a | ; Bathe seen ac a tenction = . neg edlased cr the E te He ae o reea tents] = [ire rine to weet bonds 4> iPfercent Ay pes of enthalpies ig = 1 Bnthalpy of formation + te ts the enthalty change ce heat evolved on - pbsortbed when 1 mole of the substanea formed Freon ty elements undere geren Conde tidra of Tarte ne and Heys Ge ts ree, prea.serted b Aly on A P ¢ | f a Slander enthalpy of Loremalion oof CO hich Stas ae. |g us defened ar the teat Change ee ea formation of 1 mole of dubstance tr the a statz from Clements, allo taken en A btandartd “state. © 14 tn reepree sented Aa ote A, # oe 4 ‘ ¢ e | mf Bice» reelale ont | Standard & enthalsy chante fore sas ee, An. HE = | Sum of standarcel Po of the dtand.\ . erthal pyies of formmale|~ \ret enthulpies of | fale \ on of ears Prtrathon of f Yea cta nts, Hi te a YFP Ceiba ets) » A 1” (teeter) aie un; P : | . Fore a nertcal ~rteact®on, $ ea eRe rl ed | pale x AH Ce) + dx Apt oo Lek AA) + bean | |fuel ¥ 0 Calculate the standard enthalpy Change CAH) on) - Ctardard avtarenal * eneregy' change £4’) for He | following reaction’. Lo O.H50y (0. — FL MO'LY O @ | We oct 25°C fore HyOy. (0 eT 488 KT/ommle and yO LO = ~286 kKTfrol and Re #9 Th an cain. ® @ En thaley of Combudtion o ‘ : Meet The enthalpy of. combedion Of gubs tan ee. oO defenedt as the eat change shen £ mole. of substance complete becten en one ’ | f+ uw fee hee dente 4 Ate ore AnH Standard entropy “oof Melia ti Tt the amourt of eat evolved, when male oh dubslan ee oe btan darted: conditions & f compute ly buat te form the products alia a “ted Lond Lom. Lat pee ee | SE ig teh regent by Qh Vas ACS, ey ce ; ¢ 3) ro lads 3% CO), » Sarai Alle = 110° kTmol"!.! § eas et. hobs ia, Ho & tre because Pitan + heat evolved darts tnmrbuition |Bort value ofa ful gor. food % me Valor fee, valua of a fuel orc Food % tre | amount Ee of heat cn caloreces ore you les reduced treom “the Complete Lombust? on of one prom. “Of the fut rc foroc. : t Quel on 3. Sealeulite the enbhalp ¥ . | op beet of methane, | Ben that the enthalpies of. Combyslzon © | methane , grape and ys n are es Ad fret, 04 3°4 kT /evots 225° Ht kTmet' ieee ve ly: c Oeae.titz te -enthalp of yeraton of ney Ge ven ste @ the 0 to | HD OY AB 5 AO CHOY © Entra of dub lémalion > (Au a le eel ogee Hre -enthalh change, shan Chan derceat! onta th vapours atk a ferege- woe Sih Se mater cele , st = ees. 15.08), SCS) lg HH t+E2 34k | ¢ 9 5 me a Sub > nestor i O Glee the enthalpy cD Wewcce) aot change 3 > lege FS Bye 2 nonmol boileng pose on dequid state + salle? of heat cs eakaased; per of sodium, (Atore Sa 23 a. rh-s) eed ee id aaah. Naeem aee eee ee cf a. uot, thet th ith volume, of dolution Bib 1ODni, i, dons wh onde Dut oe dpece fee feat ae Ate ae oe: es heat change derecng rvveing . 4 De erty cheng fore the reeacleon. \ is never an acid. in newbratued be o bate, Aer ntt tteaction % —_ | HF Cag) + on (24) ————» WOlL), ah ~ “57g Cleulote the hoot evolved. Lore bre Follousing reeset } A fercime nt, — ® 0:50 mole of HCL solution t& nutreld oe O50 mole f NadH solution, 0°50. mole FUND, Solution t% muced woh 0°30 wok oh KOH caption, (® AOD mL of 02 CM) HEL ake maced . LoMth 100 mL eh OD (0M) Nadie Solutio n | | AOD wl of 0-2 (M) HyeSy a BO wl ef 0-10) Koy Adleation. a 7 a Set Laus of constant heat he rrinainy 2 Bs eer react ov > hes fue tm one= tO Gusitions OGluiate He enthliry of foremation of ethane frepm the following ah mec + OG) — Cy CQ) 5 Ag H'= 393’ SI, (Hay) + 400g) > OW 5 4eW*a-285-8 ag Colle Ug) + $05Cq)—¥ 2 COPY BHLOLW 5 Aott?= 156049. © From the therenochemieal ee Ox, Cp —+ 2H @ 5» AW a2 os eee Bert) —> 2c1tp 5 Aa = 245-2 kJ. Het ‘p Hit Alp 5 Sea ep HOH 43h Fb Caleulate He ulin dattd entha Loy of. foremali or of- BCL ta) ond Bond energy (0k, Bend £ En vel = The amount of mee reequi to break a bond w ute « called | beliocen the ators tn the | dhe bord ayeocialion entoY 4 eg reson A ye? (een of Baan Faas Lum of bond enbulj) : . of tteacart <4 OF fitod ee : Colertate the enthalpy ae Toe. He ttantGon Hy? + Cty @ ete @ tL the bond enthel~ Deu, O-cL and H— a bond are 430, 49 ond 427 kJ mou kogpeileve ly.