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Chemistry Class 11 Notes
Chemistry Class 11 Notes
Chemistry Class 11 Notes
2. A ring of copper weighs 7.5382 g and its density id 8.2 g/cm3. Calculate the
volume of copper in the ring.
3. Add the numbers 28.521, 6.32 and 0.126 and give the result up to correct place of
decimal.
8. Given the abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5%
respectively. Calculate the average atomic mass of Fe.
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Class work Practice:
11. An organic compound with molecular mass 30 g/mol contains 80% carbon and
rest hydrogen. Calculate its empirical and molecular formula.
12. An aromatic organic compound contains 92.31% C and rest hydrogen. Calculate
the empirical and molecular formula of the compound if its molar mass is 78
g/mol.
13. A compound on analysis was found to contain 57.8% C, 3.6% H and rest oxygen.
The vapor density of the compound is 83. Determine its empirical and molecular
formula.
14. An organic compound was found to contain 48% C, 8% H, 28% N and rest
oxygen. Calculate the empirical formula of the compound.
15. Mothballs contain 93.71% C and rest H. if its molecular mass is 128 g/mol, then
calculate its molecular formula.
16. Calculate the empirical formula of the compound containing 26.6% potassium,
35.4% chromium and rest oxygen. [K = 39, Cr = 52]
17. Calculate the mole fraction of benzene[C6H6] in a solution which is 30% by mass
in CCl4.
18. The molality of ethyl alcohol in water is 1.55 m. How many grams of ethyl alcohol
is dissolved in 2 L of water?
19. The hemoglobin from red blood corpuscles of most mammals contain
approximately 0.33% of iron by weight. The molecular weight of hemoglobin is
67200. How many iron atoms are present in each molecule of hemoglobin?
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Class work Practice:
22. Calculate the molarity and normality of a solution containing 3.15 g of oxalic acid
dihydrate dissolved in 250 mL of the solution.
23. A sample of NaOH weighing 0.38 g is dissolved in water and the solution is made
up to 50 mL in a volumetric flask. What is the molarity of the resulting solution?
24. How many moles of NaOH are present in 27 mL of 0.15 M aqueous solution?
25. A solution of ethanol in water is 1.6 molal. How many grams of ethanol is present
in 500 g of the solution.
26. 250 mL of H2SO4 solution contains 24.5 g of it. If the density of the solution is
1.98 g/cm3, the determine (a) molarity (b) molality.
27. Concentrated nitric acid used in laboratory is 68% nitric acid by mass in aqueous
solution. What is the molarity of such a sample? [ density of the solution is 1.504
g/mL]
29. Calculate the volume of hydrogen gas at STP produced by 5 moles of zinc in the
following reaction:
Zn + H2SO4 → ZnSO4 + H2
30. Calculate the number of moles of hydrogen gas present in 0.224 L of it at STP.
31. Two elements X (at. wt = 75) and Y ( at. wt = 16) combine to yield a compound.
The percentage by mass of X in the compound was found to be 75.08. determine
the formula of the compound.
32. What amount of lime will obtained by the thermal decomposition of 1500 g of
CaCO3?
CaCO3 → CaO + CO2
33. Calculate the amount of MgCl2 obtained in the following reaction from 17 g of
HCl.
MgO +2HCl → MgCl2 + H2O
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Class work Practice:
34. Calculate the amount of lime obtained by heating 200 kg of 95% pure CaCO3.
35. Calculate the amount of oxygen in grams required to completely burn 570 g of
octane. [C8H18]
36. How many moles of phosphine [PH3] will be obtained in the hydrolysis of 3 mol
calcium phosphide [Ca3P2]?
38. Define the terms: molarity, molality, mole fraction.Which of these concentration
terms are temperature dependents
39. State the law of multiple proportions, Avogadro’s hypothesis.
Topic-Structure Of Atom
2. Give the symbol of element which is isoelectronic with Cl- and S2-.
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Class work Practice:
5. Calculate the energy of 1 mole quanta of radiation whose frequency is 5 × 1010 s-1.
6. Neon gas is generally used in the sign boards. If it is emitted strongly at 616 nm,
then calculate:
i. The frequency of emission.
ii. Distance travelled by the radiation in 30 s.
iii. Energy of quantum and,
iv. The number of quanta producing 2 J energy.
7. Calculate the frequency and wave number of a radiation with wavelength 480
nm.
9. What is the ratio between the energies of two radiations, one with wavelength
6000 Å and other with 2000 Å.
12. Calculate the shortest and longest wavelengths in hydrogen spectrum of Lyman
series.
13. Calculate the velocity of an electron in cm/s placed in the 3rd orbit of H-atom.
14. The energy of first Bohr orbit of H-atom is -2.18 × 10-18 J atom-1. What is the
energy associated with 5th orbit?
16. What is the wavelength of radiation emitted when the electron in hydrogen atom
undergoes transition from n=4 to n=2 energy level?
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Class work Practice:
17. The ionization energy of hydrogen atom is 13.6eV. What will be the ionization
energy of He+ and Li2+ ions?
18. Light of wavelength 12818 Å is emitted when the electron of hydrogen atom drops
from 5th to 3rd orbit. Find the wavelength of the photon emitted when the electron
falls from 3rd to 2nd orbit.
19. Calculate the number of lines in the spectrum of hydrogen, when the electron
enters from 7th shell to 2nd shell.
20. When light of 470 nm falls on the surface of potassium metal, electrons are
emitted with a velocity of 6.4 × 104 m/s. what is the minimum energy required to
remove one mole of electrons from potassium metal?
21. Threshold wavelength of a metal is 230 nm. What will be the kinetic energy of
photo-electrons ejected when the metal is irradiated with wavelength 180 nm?
[ h = 1.66 × 10-34 Js]
22. The energy requires to remove an electron from surface of sodium metal is 2.3
eV. What is the longest wavelength of radiation with which it can show
photoelectric effect?
23. Calculate the wavelength of a sub-atomic particle of mass 9 × 10-27 g moving with
a velocity of 106 m/s.
24. A proton ( mass = 1.66 × 10-27 kg) is moving with a kinetic energy of 5 × 10-27 J.
what is the wavelength of the proton?
26. Calculate the wavelength of a CO2 molecule moving with a velocity of 440 m/s.
27. The kinetic energy of an electron is 4.55 × 10-25 J. Calculate its wavelength.
[ h = 1.66 × 10-34 Js, mass of electron = 9.1 × 10-31 kg]
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Class work Practice:
29. The uncertainty in position and velocity of a particle are 10-10 m and 5.27 × 10-24
m/s respectively. Calculate the mass of the particle. [ h = 1.66 × 10-34 Js]
30. Calculate the uncertainty in velocity of a cricket ball of mass 150 g if the
uncertainty in its position is of the order 1Å. [ h = 1.66 × 10-34 kg m2 s-1]
32. How many electrons in an atom may have the following quantum numbers?
a) n = 4, ms = -1/2 c) n = 5 l = 3 ms = 1/2
b) n = 3 l = o
33. One unpaired electron in an atom contributes a magnetic moment of 1.1 B.M.
Calculate the magnetic moment in;
a) Mn c) Fe e) Cu
b) Cr d) Ni f) V
34. Calculate the angular momentum and orbital angular momentum of the
following:
a) 3s b) 4p c) 3d
35. Calculate the number of radial nodes, angular nodes and total number of nodes
in:
a) 3s b) 3p c) 4d
36.State the following principles:
Heisenberg Uncertainity principle, de-Broglie principle, hund’s rule, pauli’s
principle.
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Class work Practice:
4. Define the following terms. How do they vary in the periodic table
a) ionization enthalpy b) electron gain enthalpy
c) electro negativity d) atomic radii.
5. Give reason:
a) Successive ionization enthalpy of an element keeps on increasing.
b) Boron has a lower first ionization enthalpy than beryllium.
c) Oxygen has lower first ionization enthalpy than nitrogen
d) Noble gases have the highest ionization enthalpies.
e) Halogens have very high negative electron gain enthalpies.
f) Noble gases have large positive electron gain enthalpies
g) Electron gain enthalpy of O or F is less negative than sulphur in the group 16.
h) Electron gain enthalpy of F is less negative than Chlorine in the group 17.
i) First ionization enthalpy of nitrogen is greater than oxygen
j) Electron gain enthalpy of Nitrogen is positive whereas Oxygen has a negative value.
Explain.
k)
6. How does valence vary along a period?
7. Name the most electronegative element.
8. b) i) Identify the most reactive element in group group-1 and group-17.
ii) Identify the element with the highest ionization enthalpy element and highest negative
value of electron gain enthalpy.
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Class work Practice:
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Class work Practice:
Element i H1 i H 2 eg H
I 520 7300 -60
II 419 3051 -48
III 1681 3374 -328
IV 1008 1846 -295
V 2372 5251 +48
VI 738 1451 -40
Which of the above elements is likely to be:
a) the least reactive element b) the most reactive element
c) the most reactive nonmetal d) the least reactive nonmetal
e) the metal which can form a stable binary of the formula MX2(X = halogen)
f) the metal which can form a predominantly stable covalent halide of the formula
MX (X = halogen)?
2. Predict the formulae of the stable binary compounds that would be formed by the
combination of the following pairs of elements:
a) lithium and oxygen b) magnesium and nitrogen
c) aluminium and iodine d) silicon and oxygen
e) phosphorus and fluorine f) element 71 and fluorine
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Class work Practice:
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What conclusion about the compound Na4XeO6 (of which XeO64 is a part) can be drawn
from the reaction.
8. Consider the reactions:
(i) H 3 PO2 (aq) 4 AgNO3 aq 2 H 2O(l )
H 3 PO4 (aq) 4 Ag ( s) 4 HNO3 (aq)
(ii) H 3 PO2 (aq) 2CuSO4 (aq) 2 H 2O(l )
H 3 PO4 (aq) 2Cu ( s) H 2 SO(aq)
(iii)
C6 H 5CHO (l ) 2Ag ( NH 3 ) 2 aq 3OH aq
C6 H 5COO (aq) 2 Ag ( s) 4 NH 3 (aq) 2 H 2O(l )
(iv) C6 H 5CHO (l ) 2Cu 2 (aq) 5OH aq
No change observed.
What inference do you draw about the behavior of Ag+ and Cu2+ from these reactions?
9. Balance the following redox reactions by ion-electron method:
(i) MnO4 ( aq ) I ( aq )
MnO2( s ) IO31( s )
(in basic medium)
(ii) MnO4 (aq) SO2 ( g )
Mn 2 (aq) HSO4 aq
(in acidic solution)
2
Fe3 (aq) H 2O(l )
(iii) H 2O2 (aq) Fe (aq)
(in acidic solution)
(iv) Cr2O72 (aq) SO2 ( g )
Cr 3 (aq) SO42 aq
(in acidic reaction)
2
v) MnO 4 ( aq ) Sn ( aq ) Mn2( s ) Sn4( s )
10. Balance the following equations in basic medium by ion-electron method and oxidation
number methods and identify the oxidizing agent and the reducing agent.
a) P4 ( s) OH (aq)
PH 3 ( g ) H 2 PO2 (aq)
b) N 2 H 4 (l ) ClO3 (aq)
NO ( g ) Cl (aq)
ClO2 (aq) O2 ( g ) H (aq)
c) Cl 2O7 ( g ) H 2O2 (aq)
Direction: In the following Questions, the Assertion and Reason have been put
forward. Read the statements carefully and choose the correct alternative from the
following:
(a) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation
for assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
11. Assertion: Among halogen fluorine is the best oxidant.
Reason: Fluorine is the most electronegative atom.
12. Assertion: In the reaction between potassium permanganate ions act as oxidizing agent.
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Class work Practice:
is
a) 4-oxo-2, 3-dimethyl pent-2-en-1-oic acid
b) 2-carboxy-3-methyl pent-2-en-3-one
c) 4-carboxy-3-methyl pent-3-en-2-one
d) 2,3-Dimethyl-4-oxo-pent-2-en-1-oic acid
2. The IUPAC name for
a) 1-Chloro-2-nitro-4-methylbenzene b) 1-Chloro-4-methyl-2-nitrobenzene
c) 2-Chloro-1-nitro-5-methylbenzene d) m-Nitro-p-chlorotoluene
3. Write IUPAC name of the following organic compound:
CH3 – C(CH3)2 – CH = CH2
4. Give the IUPAC name of the following compound:
a)
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Class work Practice:
b)
8. Give IUPAC name of the following compounds:
(i) (ii)
9. (a) Write IUPAC name of the following:
(i) (ii)
(iii)
7. In the organic compounds:
1 2 3 4 5 6
C H 2 C H C H 2 C H 2 C C H , the pair of hybridized orbital’s involved in the
formation of C2 – C3 bond is:
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Class work Practice:
(i) sp – sp2 (ii) sp – sp3 (iii) sp2 – sp3 (iv) sp3 – sp3
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