Professional Documents
Culture Documents
client F ترجمه S15K1695997169
client F ترجمه S15K1695997169
The surface composition of perovskite films is very sensitive to film processing and can deviate from the
optimal, which generates unfavorable defects and results in efficiency loss in solar cells and slow
response speed in photodetectors. An argon plasma treatment is introduced to modify the surface
composition by tuning the ratio of organic and inorganic components as well as defect type before
deposition of the passivating layer. It can efficiently enhance the charge collection across the
with argon plasma treatment yield enhanced efficiency to 20.4% and perovskite photodetectors can
reach their fastest respond speed, which is solely limited by the carrier mobility.
Efficient perovskite solar cell was achieved using a small hole transport material, SpiroOMeTAD, after
oxygen plasma treatment. It was demonstrated that the plasma treatment of hole transport layer for
the solids state perovskite solar cell was enhanced power conversion efficiency. Reason for enhancing
the cell performance of solar cell was good match of homo energy level between Perovskite and Spiro-
OMeTAD. It leads to transfer well hole carrier at Active/HTL interface. This study obtained highly
improved performance by a current density of 25.4 mA/cm2 , an open-circuit voltage of 1.02 V, and a fill
In conclusion, we have demonstrated not only a novel approach Spiro-OmeTAD to enhance photovoltaic
performance, but also a useful treatment system to introduce the correlation between CH3NH3PbI3 and
HTL of perovskite solar cell. Specifically, our research underlines that using oxygen plasma of HTM and
MAPbI3 well-matched hole conductors is key to enhance performance. A central finding of our study is
that HTM based on the spiroOmeTAD after 15min was obtained the highest efficiency of 15.6%, with
higher FF and Voc values than the other time. These results will induce useful and cost-effective of HTM
for solar cells industry in the future. We believe that the present findings apply existing and new HTM
for organic solar cell to achieve high-efficiency and low-cost solar cells.
This work introduces a novel method of low-temperature (70 °C) ambient-air plasma treatment
for the rapid fabrication of mesoporous titania/polysiloxane thin films in perovskite solar cells.
wet coating compatible with plasma post-treatment, leading to a significant and rapid (1 min)
removal of the organic part of the polysiloxane binder, together with its transformation into
in a perovskite solar cell resulted in a power conversion efficiency of ∼12%, demonstrating for
the first time the feasibility of such a cold plasma processing approach for perovskite solar cell
manufacture.
This contribution presents a method for the fabrication of n−i−p perovskite solar cells using an
photoanode. Since research trends are shifting away from improving the efficiency of solar cells
and toward ensuring suitable properties for industrialization, particularly in terms of the stability of
devices and design for low-cost production processes, the method herein constitutes an important
improvement in fabrication methodology that may find commercial success in the manufacture of
flexible and printed electronics that require roll-to-roll lines. Processing of m-TiO2 by low-temperature
(70 °C) plasma is the most rapid ambient-air method reported for the manufacture of m-TiO2 in
perovskite solar cells. The competitive processes associated with flexible and printed electronics include
time-consuming (tens of minutes or longer) UV treatments, which take significantly longer times at
higher operating costs than plasma treatment. The low operational costs of RPS40 plasma arise from the
technically unique coplanar setup of metallic electrodes enclosed in robust Al2O3 ceramics. This
facilitates the generation of surface plasma of ultra-high-power density, on the order of ∼160 W/ cm3.
The volume power density is extremely high since the thickness of the plasma is low, at ∼0.2 mm. This is
among the highest reported power densities for ambient-air plasmas with homogeneous, diffuse
attributes and cold (∼70 °C) properties. Rapid plasma treatment of TiO2/polysiloxane leading to
TiO2/SiO2-like surfaces by means of RPS40 plasma is revealed to be a nontoxic, sustainable, and highly
feasible process, with potential for integration into the manufacture of low-cost devices, particularly
those for which the highest PCE is not a key parameter for commercial success.
Perovskite solar cells (PSCs) have received great attention due to their excellent photovoltaic properties
especially for the comparable efficiency to silicon solar cells. The electron transport layer (ETL) is
regarded as a crucial medium in transporting electrons and blocking holes for PSCs. In this study, CO2
plasma generated by plasma-enhanced chemical vapor deposition (PECVD) was introduced to modify
the TiO2 ETL. The results indicated that CO2 plasma treated compact TiO2 layer exhibited better surface
hydrophilicity, higher conductivity, and lower bulk defect state density in comparison with the pristine
TiO2 film. The quality of the stoichiometric TiO2 structure was improved and the concentration of
oxygen-deficiencies induced defect sites was reduced significantly after CO2 plasma treated for 90 s. The
PSCs with TiO2 film treated by CO2 plasma for 90 s exhibited simultaneously the improved short-circuit
current (Jsc) and fill factor (FF). As a result, PSC based TiO2 ETL with CO2 plasma treatment affords a
power conversion efficiency (PCE) of 15.39%, outperforming that based on pristine TiO2 (13.54%). These
results indicate that the plasma treatment by PECVD method is an effective approach to modify ETL for
We have introduced the CO2 plasma to modify the TiO2 films using PECVD system. The CO2 plasma
method can not only improve the quality of the stoichiometric TiO2 structure, but also reduce the
concentration of oxygen-deficiencies induced defect sites. The 90 s CO2 plasma treated TiO2 film
exhibited the better surface hydrophilicity, the higher conductivity, and the lower bulk defect state
density in comparison with the pristine TiO2 film. Compared to PSC based on pristine TiO2, the PSCs
with CO2 plasma treated TiO2 shown the higher JSC and FF due to the reduced electron recombination
and enhanced electron transport. Corresponding, the PCE was significantly enhanced from 13.54% to
15.39%. These results indicated that the plasma treatment by PECVD method is an effective approach to