Llniversity cf the Phitrippines Diiirnan MatE 21 LE 1 Samplex

UP Materiais Science SccieS AY 202? - ?023

References:
Askeland R., Fulay P. & Wright W. (2012) Science and Engineering of Materials. 6th ed
Callister W. & Rethwisch D. Material Science and Engineering. Sth ed.

l" Write True if the statement is true, otherwise, encircle the word/ that
makes the statemefit incarrect then write the correct answer above

1 tlrturi"4@ilin"=e:is the response to imposed stimuli. T(\'tk-

/{:\ Structure is the a of a material's internal
(3, Atomic structu grains, plases, and volume lr* w8^ vrrrw
fi\
zH
lasticity is an
eat capacity is an
roPertY. l11+'Mi i\'&
property. T(u,( t1l)-
q,rL Jhlt ttats\ e

+6 have glassy and elastic"propedies,

nical model shows the ene the electrons can
Dc,h . rat-umr-t rh€,(, \
the smallest repeated Urf ,Y U,,U
Single crystals are frai 9s
10. Chain reaction, in polymerization refer to the reaction between
reactive groups eliminating a in the process.
11. Frenkel defects are more I when the displaced ion is larger than the
host material.
1i.,'' ,..r..
gMs\^"1
r$
"-
' I rli.j
t.t^^Mf
ll. Encircle the
1. Which has a h re?
whx^ {
2. Higher U

CI
3
- graphite
4,,]:: .
llinity
oorcelain

{lry w,,;twl^u"
}^rr
"'
6 R ftnrfur h ^.MqP
Higher crystallinity
7. Effect of tem vacancies
lncrease -
 University of the Philippines Diliman LE I Samplex
lr4atE 21

@ LIP Materials Science SocietY AY 2022 - 2023

lll, Give what is asked

1. Quantum numbers. Draw the possible orbitals when n = 2

..::;.,",

2. Quantum numbers. Give the quantum numbers of the encircl electrdh:,r

.l ...
Orygen 11.*
yr{
,.

Lfr
tt TI I T
j
1s 2s a

3. Crystal Structure. Determine the structure based on the

description.
a. The coordination number its anions in the FCC lattiee
b. Compounds with this formulae of AXz. Anions are located at
tetrahedral positions.
c. Cornmon in metals a one whole atom in the middle of the unit
cell.
d. The crystal diamond. t t1
4. CrystallograPhic the indices for the directi ons shown in [C
the following
Hu{D c ol
-- 9;tie wfrrlrue
A
{
I tt\ - c lil ,fi,| 1- \
A, [D-l r t0 r.l
_i-
B
L
2
I},
c; H.,t-t+ul 0: Ito =[]tul
D
fe -.lt r cl T 'f lD21
,l
L

1 I Cr[0 E li D: tl I
2

+-f

5. Polymer. sketch repeat strt*ctures for the fotlowing polymers

a. PolYchlorotrifluoroethYlene
b. PolY(vinYl alcohol)
 Llniversity of the Philippines Dilirnan MatE 2i LE I Samplex
UP Materials Science Society l *1"* tN *a\"mt\ AY 2A??'-2023
P yf,,,rtg\Z(, (Lv*zY-> "
d.,w,
6. Defects. Explain the process gl-dgpiXg
tnh' Lv,4-t- r)n/tf ,a t;)-rL'r f,-t
trthh aS" Y 6o
prv L(4? f
7. Surface atoms. Why are surface atoms in a higher energy state than internal
atoms? How do materials reduce this energy? -b gqr
Fr& at*w h.*r, d.atfit'y
ir*lrr wlriz,h \nilW ll^ov'^ r^ta''atrlr2 -

IV. P
1 the

2. ionic of .31
andO= How about for GaAs 1.81 and ens = 2.18?

3. Calculate the radius of a vanad ,g iven that V has a BCC crystal struct ure,
a density of 5.9691cm3, aftd weight of s0]rymet

4 The accompanying ftgurE-:,Shows three different crystallographic planes for a unit

cell of a hypothetical.metal..The circles represent atoms. Determine the crystal
structure and solve foijk,;itomic weight when the density of this metal is 8.95
t.,r,..-,:'
g/cm3.
-r.
i Tll -xl
I
E i:
c
{
i
c
og
!r)

t
I
.:
ti
l,
iL
t".-0.30 nrn i i
i*0.40 nm-|
--0.35 nrrl---
i00r) ( 1l,o) {10I)
5 Calculate the degree of polymerization if 6,6-nylon has a molecular weight of
120,0009/mol
6 Calculate the fraction of atom sites that are vacant for lead at its melting
temperature of 327C (600 K). Assume an energy for vacancy formation of 0.52
eViatom.

Lr.rr '
Ptf
 University of the Philippines Diliman MatE 21 LE I Samplex

@
Answer Key
UP Materials Science SocietY AY 2A2? -2073

l. True or change

1. Performance >> property

2. True
3. lnvolves >> does not involve
4. Extensive >> intensive
5. True
6. Polymers >> gtass L?.
7. Wave-mechanicat >> Bgfrr atomic m€tP l*wl
8. Repeating unit >> unit cetl
9. lsotropic >> anisotropic or single crystal >>
10.Chain reaction >> steP-growth

Il. Encircle the correct answer

1. Ni has stronger bonds
2. GaAs has covalent bonding
3. SiO+ is ionic
4. Porcelain is a ceramlc and it partictes
5. Bronze
b Lowe r crysta ll nity
7 ncre ase
*ti, ,,: :::;. ..
:Iit::!i rlr:,
''jjll:::::i':x i:1
ii:li
.i. :'
!-:
.;J:;1.!,
l:i:

Give what IS asked, '::=

HG.
w

1.
L5 2s 2p* 29 2P,
2 n =2',1 ='!; mr = -1; ms = -112
:.:,::1,,: "
3
a. NaCl structure
b. Fluorite structure
c. BCC
d. Tetrahedral
4
a [o-0, o-1,0:1]
 University of the Philippines Diliman MatE 21LE 1 Samplex

@ UP Materials Science Society LY 2A22 -2423

[0, -1, -1]

IOml
It i o] multiplied
b by 2
l21ol
c. U12)

F
I

-C
rl
a.
LF

b.
 University of the Philippines Diliman MatE 2l LE I Samplex

@ UP Materials Science Society AY 2AZ? - ?023

= Z ? 5. :.)n+o .,
 University of the Philippines Diliman I
@ IIP Materials Science Society
MatE 21 LE
AY2022 -2023
Samplex