Bahan baku 18,000.00 ton/tahun 18,000,000.

00 kg/tahun
Hari kerja 330 hari
Jam operasi 24 jam/hari
Kapasitas per hari 54,545.45 kg/hari
Basis 1 hari
Satuan massa Kilogram (kg)
Satuan mol Kilomol (kmol)
Konversi 90 %

KOMPOSISI
As. Palmitat C16H32O2 99 %b
C18H36O2 1 %b
Isobutanol C4H10O 99 %b
H2O 1 %b
As. Sulfat H2SO4 98 %b
H2O 2 %b
Natrium Hidroksida NaOH 48 %b
H2O 52 %b
rasio mol as. palmitat : isobutanol 1 : 5
as. sulfat (katalis) 0.11 %b

Berat Molekul
kmol/hari kg/hari C16H32O2
massa (C16 & C18) 0.00 C18H36O2
C16 99% 194.25 49,728.05 C20H40O2
C18 1% 1.77 502.30 C4H10O
C4H10O 99% 971.25 71,989.12 NaOH
H2O 1% 40.36 727.16 H2O
H2SO4
Na2SO4
C22H44O2
0.9
 C16H32O2 C4H10O --> C20H40O2
m 194.25 971.25 -
r 174.83 174.83 174.83
s 19.43 796.43 174.83
4,972.80 59,031.08 54,545.45

C18H36O2 C4H10O --> C22H44O2

m 1.77 796.43 -
r 1.77 1.77 1.77
s - 794.66 1.77
58,900.20 601.36
 Kapasitas panas cairan
Cp, J/mol.K
Komponen A B C
C16H32O2 86.3 3.52 -0.01
C18H36O2 99.01 3.59E+00 -7.25E-03
C20H40O2 -169.97 5.35E+00 -1.06E-02
C4H10O 96.15 4.95E-01 -1.56E-03
NaOH 87.64 -4.84E-04 -4.54E-06
H2O 92.05 -4.00E-02 -2.11E-04
H2SO4 26 7.03E-01 -1.39E-03
Na2SO4 233.51 -9.53E-03 -3.47E-05
C22H44O2 -119.365 5.77E+00 -1.26E-02

kapasitas panas gas

Cp, J/mol.K
Komponen A B C
Berat Molekul C16H32O2 -54.49 1.80E+00 -1.34E-03
256 kg/kmol C18H36O2 7.51 1.70E+00 -9.28E-04
284.48 kg/kmol C20H40O2 -10.69 1.95E+00 -1.14E-03
312 kg/kmol C4H10O 71.17 -3.91E-01 3.15E-03
74.12 kg/kmol NaOH 22.25 1.42E-01 -2.43E-04
39.997 kg/kmol H2O 33.93 -8.42E-03 2.99E-05
18.015801 kg/kmol
98.0778 kg/kmol H2SO4 9.49 3.38E-01 -3.81E-04
142.0402 kg/kmol Na2SO4 23.35 4.01E-01 -5.08E-04
340.58 kg/kmol C22H44O2 -69.046 2.5211 -2.10E-03
nilai ∆Hf standar komponen(kJ/mol)
 H2O C4H10O -282.92
- kmol/hari C16H32O2 -723.06
174.83 kmol/hari C20H40O2 -806
174.83 kmol/hari H2O -241.8
3,149.62 kg/hari C22H44O2 -819.27
C18 -733.5
H2O
- kmol/hari
1.77 kmol/hari C16H32O2 C4H10O -->
1.77 kmol/hari m 194.25 971.25
31.81 kg/hari r 174.83 174.83
s 19.43 796.43
4,972.80 59,031.08

C18H36O2 C4H10O -->

m 1.77 796.43
r 1.77 1.77
s - 794.66
58,900.20
 T(K) 303.15
l.K
D
0.00
5.90E-06
7.84E-06
2.20E-06
1.19E-09
5.35E-07
1.03E-06
-3.47E-05
1.03E-05

p, J/mol.K
D E
5.37E-07 -9.20E-11
1.76E-07 3.64E-12
2.55E-07 -
-5.63E-06 3.33E-09
1.81E-07 -4.80E-11
-1.78E-08 3.69E-12

2.13E-07 -4.69E-11
2.99E-07 -6.67E-11
1.08E-06 -2.75E-10
C20H40O2 H2O
- - kmol/hari
174.83 174.83 kmol/hari
174.83 174.83 kmol/hari
54545.45 3,149.62 kg/hari

C22H44O2 H2O
- - kmol/hari
1.77 1.77 kmol/hari
1.77 1.77 kmol/hari
601.36 31.81 kg/hari
Komponen Input (kg/hari) Output (kg/hari)
C20 312.00 0.00 54,545.45
C22 340.58 0.00 601.36 Komponen
C16 256.00 49,728.05 4,972.80 C20
C18 284.48 502.30 0.00 C22
C4 74.13 72,002.70 58,900.20 C16
H2O, c4 18.02 727.30 727.30 C18
H2SO4 98.08 13,390.38 13,390.38 C4
H2O, as.sulf 18.02 273.27 273.27 H2O
H2O rx 18.02 0.00 3,181.43 C4
H2O rx2 18.02 0.00 31.81 H2O
total 136,624.01 136,624.01 H2SO4
Selisih 0.00 H2O, as.sulf
H2O rx1
H2O rx2
Reaktor total
Aliran Masuk Aliran Keluar (kg/hari) Selisih
Komponen Massa (kg/hari) Komponen Massa (kg/hari)
Aliran 1 Aliran 5
C16 49,728.05 C20 54,545.45 Tref
C18 502.30 C22 601.36 T in
Subtotal 50,230.35 C16 4,972.80 T out
Aliran 2 C4 58,900.20
C4 13,102.50 H2SO4 13,390.38 6,172.25
H2O 132.35 H2O 4,213.81
Subtotal 13,234.85 Subtotal 136,624.01 Komponen
Aliran 3 C20
H2SO4 13,390.38 C22
H2O 273.27 C16
Subtotal 13,663.66 C18
Aliran 12 C4
C4 58,900.20 H2O
H2O 594.95 C4,R
Subtotal 59,495.15 H2O,R
Total 136,624.01 Total 136,624.01 H2SO4
selisih 0.00 H2O, as.sulf
H2O rx1
H2O rx2
Input (kg/hari) Output (kg/hari)
0.00 54,545.45 ∆H Reaksi -41.82
0.00 601.36 -41,820.00
49,728.05 4,972.80 ∆H Reaksi -7,311,188.20
502.30 0.00 Qreaksi = - ∆H Reaksi
13,102.50 58,900.20 Qreaksi (1) 7,311,188.20
132.35 727.30 ∆H Reaksi -44.65
58,900.20 -44,650.00
594.95 ∆H Reaksi -78,838.06
13,390.38 13,390.38 Qreaksi = - ∆H Reaksi
273.27 273.27 Qreaksi (2) 78,838.06
0.00 3,181.43
0.00 31.81 7,390,026.26
136,624.01 136,624.01
0.00 0.00

25.00 oC 298.15 K H2O Output

30.00 oC 303.15 K
107.00 oC 380.15 K

INPUT
BM (kg/mol) massa (kg/hari) laju alir (kmol/hari) ∫Cpdt (kJ/kmol) Q (kJ/hari) Massa (kg/hari)
312.00 0.00 0.00 3,467.10 0.00 C20 54,545.45
340.58 0.00 0.00 3,790.50 0.00 C22 601.36
256.00 49,728.05 194.25 3,243.50 630,049.67 C16 4,972.80
284.48 502.30 1.77 54,975.77 97,070.17 0.00
74.12 13,102.50 176.77 818.75 144,734.31 C4 58,900.20
 18.02 132.35 7.34 377.46 2,772.24 H2O 727.30
74.12 58,900.20 794.66 818.75 650,629.94 H2SO4 13,390.38
18.02 594.95 33.02 377.46 12,462.17 H2O, as.sulf 273.27
98.08 13,390.38 136.53 698.52 95,366.80 H2O rx1 3,181.43
18.02 273.27 15.16 377.46 5,724.12 H2O rx2 31.81
18.02 0.00 0.00 377.46 0.00
18.02 0.00 0.00 377.46 0.00

Qin + Qsupply =
1,638,809.42 Qsupply
Qs - 0,05 Qs =
0.95 Qs =
Neraca Panas Reaktor Qs =
Aliran Masuk Aliran Keluar (kj/hari) Qloss =
Komponen Energi (kJ/hari) Komponen Energi (kJ/hari)
Aliran 1 Aliran 5
C16 630,049.67 C20 10,459,440.85
C18 97,070.17 C22 114,559.15
Subtotal 727,119.84 C16 1,075,936.82 P
Aliran 2 C4 11,129,419.02 Ts
C4 144,734.31 H2SO4 1,618,032.42 L
H2O 2,772.24 H2O 1,443,322.57
Subtotal 147,506.55 Subtotal 25,840,710.84
Aliran 3
H2SO4 95,366.80 Qreaksi (1) 7,311,188.20 Qsupply =
H2O 5,724.12 Qreaksi (2) 78,838.06 33,254,660.71
Subtotal 101,090.93 Qloss 1,662,733.04
Aliran recycle Subtotal 9,052,759.30
C4 650,629.94
H2O 12,462.17
Subtotal 663,092.11
Qsupply 33,254,660.71
Subtotal 33,254,660.71
Total 34,893,470.13 Total 34,893,470.13

selisih 0.00
kJ/mol
kJ/kmol
kJ/kmol

kJ/hari
kJ/mol
kJ/kmol
kJ/kmol

kJ/hari

3,486.51

OUTPUT
Laju Alir (kmol/hari) Q (kJ/hari) ∫Cpdt (kJ/kmol)
174.83 10,459,440.85 59,828.01
1.77 114,559.15 64,880.67
19.43 1,075,936.82 55,389.23
0.00 0.00 0.00
794.66 11,129,419.02 14,005.26
 40.36 249,116.31 6,172.25
136.53 1,618,032.42 11,851.42
15.16 93,602.07 6,172.25
176.55 1,089,708.46 6,172.25
1.77 10,895.74 6,172.25

Qout + dHrx + Qloss

25,840,710.84 7,390,026.26 0,05 Qsupply
31,591,927.67
31,591,927.67
33,254,660.71
1,662,733.04

1.00 atm
147.92 oC
2,119.71 kJ/kg

m L
m 2,119.71
m 15,688.31
m 282,703.29
T ref 25.00 oC
T in 107.00 oC
T out 30.00 oC

Input
Komponen BM (kg/mol) massa (kg/hari)
C20 312.00 54,545.45
C22 340.58 601.36
C16 256.00 4,972.80
C4 74.12 58,900.20
H2O 18.02 4,213.81
H2SO4 98.08 13,390.38
136,624.01

Qin = Qout + Qpendingin

### 1,510,096.03 Qpendingin
24,330,614.81 Qpendingin

Neraca Panas Cooler I

Aliran Masuk Aliran Keluar (kg/hari)
Komponen Energi (kJ/hari) Komponen
Aliran 4 Aliran 5
C20 10,459,440.85 C20
C22 114,559.15 C22
C16 1,075,936.82 C16
C4 11,129,419.02 C4
H2SO4 1,618,032.42 H2SO4
H2O 1,443,322.57 H2O
Subtotal 25,840,710.84 Subtotal

Qpendingin
Subtotal
Total 25,840,710.84 Total

Selisih 0.00
 298.15 K
380.15 K
303.15 K

Input O
laju Alir (kmol/hari) ∫Cpdt (kJ/kmol) Q (kJ/hari) komp massa (kg/hari)
174.83 59,828.01 10,459,440.85 C20 54,545.45
1.77 64,880.67 114,559.15 C22 601.36
19.43 55,389.23 1,075,936.82 C16 4,972.80
794.66 14,005.26 11,129,419.02 C4 58,900.20
233.84 6,172.25 1,443,322.57 H2O 4,213.81
136.53 11,851.42 1,618,032.42 H2SO4 13,390.38

Q= m Cp dT
24,330,614.81 m 792.07 15.00
m= 2,047.85 36,902.20

er I
Aliran Keluar (kg/hari)
Energi (kJ/hari)
Aliran 5
606,136.81
6,692.84
63,004.97
650,629.94
95,366.80
88,264.67
1,510,096.03

24,330,614.81
24,330,614.81
25,840,710.84
 Output
laju Alir (kmol/hari)∫Cpdt (kJ/kmol) Q (kJ/hari) Q (kJ/hari)
174.83 3,467.10 606,136.81 -606,136.81
1.77 3,790.50 6,692.84 -6,692.84
19.43 3,243.50 63,004.97 -63,004.97
794.66 818.75 650,629.94 -650,629.94
233.84 377.46 88,264.66 -88,264.66
136.53 698.52 95,366.80 -95,366.80

C K
suhu ref 25.00 298.15
suhu air in 28.00 301.15
suhu air out 43.00 316.15
suhu 35.50 308.65
Cp air pendingin 792.07
REAKSI

H2SO4 2NaOH → Na2SO4 2H2O

M 136.53 273.06 0.00 233.90 kmol/hari
R 136.53 273.06 136.53 273.06 kmol/hari
S 0.00 - 136.53 506.95 kmol/hari

MASSA (NaOH,air) 52% H2O

10,921.43 11,831.55 5,679.15

Komponen BM Input Output

C20 312.00 54,545.45 54,545.45
C22 340.58 601.36 601.36
C16 256.00 4,972.80 4,972.80
C4 74.12 58,900.20 58,900.20
H2SO4 98.08 13,390.38 0.00
H2O 18.02 4,213.81 0.00
NaOH 40.00 10,921.43 0.00
H2O naoh 18.02 11,831.55 11,831.55
Na2SO4 142.04 0.00 19,392.49
H2O rx 18.02 0.00 9,133.14
total 159,377.00 159,377.00
Selisih 0.00

Neutralizer
Aliran Masuk Aliran Keluar (kg/hari)
Komponen Massa (kg/har Komponen Massa (kg/hari)
Aliran 5 Aliran 7
C20 54,545.45 C20 54,545.45
C22 601.36 C22 601.36
C16 4,972.80 C16 4,972.80
C4 58,900.20 C4 58,900.20
H2SO4 13,390.38 Na2SO4 19,392.49
H2O 4,213.81 H2O 20,964.69
Subtotal 136,624.01 Subtotal 159,377.00
Aliran 6
NaOH 10,921.43
H2O 11,831.55
Subtotal 22,752.99
Total 159,377.00 Total 159,377.00
selisih 0.00
Komponen BM Input Output
C20 312.00 54,545.45 54,545.45 REAKS
C22 340.58 601.36 601.36 H2SO4 2NaOH
C16 256.00 4,972.80 4,972.80 m 136.53 273.06
C4 74.12 58,900.20 58,900.20 r 136.53 273.06
H2SO4 98.08 13,390.38 0.00 s 0.00 0.00
H2O 18.02 4,213.81 0.00 0.00
NaOH 40.00 10,921.43 0.00
H2O 18.02 11,831.55 11,831.55
Na2SO4 142.04 0.00 19,392.49
H2O rx 18.02 0.00 9,133.14 nilai ∆Hf standar komponen
total 0.00 159,377.00 159,377.00 H2SO4
Selisih 0.00 0.00 NaOH
Na2SO4
H2O
T ref 25.00 oC 298.15 K
T in 30.00 oC 303.15 K
T out 30.00 oC 303.15 K ∆H Reaksi
Massa 48% NaOH 52% H2O
10,921.43 5,242.29 5,679.15 ∆H Reaksi
131.07 315.23 Q reaksi = - ∆
Q reaksi
10,921.43

Input
Komponen BM (kg/mol) massa (kg/hari) laju Alir (kmol/ha∫Cpdt (kJ/kmol) Q (kJ/hari) Q (kJ/hari)
H2O 18.02 11,831.55 656.58 377.46 118,986.11 118,986.11
H2SO4 98.08 13,390.38 136.53 698.52 95,367.97 -95,367.97
NaOH 40.00 10,921.43 273.06 431.48 56,552.60 56,552.60
Na2SO4 142.04 0.00 0.00 -3,609.17 0.00 0.00

Qpendingin + Qout = Qin + Qrx suhu ref 25.00

Qpendingin 2,254,072.57 1,685,634.74 97,658,599.12 suhu air in 28.00
Qpendingin ### suhu air out 43.00
suhu 35.50
Q= m Cp dT Cp air pendin 75.33
98,227,036.95 m 75.33 15.00
m= 86,925.83 1,566,403.38

Neraca Panas Neutralizer

Aliran Masuk Aliran Keluar
Komponen Energi (kJ/hari) Komponen Energi (kJ/hari) triggerwarning
Aliran 5 Aliran 7 Qpendingin +
C20 606,136.81 C20 606,136.81 Qpendingin
C22 6,692.84 C22 6,692.84 Qpendingin
C16 63,004.97 C16 63,004.97
C4 650,629.94 C4 650,629.94
H2O 88,264.67 H2O 439,137.47
H2SO4 95,366.80 Na2SO4 488,470.53
Subtotal 1,510,096.03 Subtotal 2,254,072.57
Aliran 6
NaOH 56,552.60 Qpendingin 97,090,161.29
H2O 118,986.11 Subtotal 97,090,161.29
Subtotal 175,538.71

Qreaksi 97,658,599.12
Subtotal 97,658,599.12
Total 99,344,233.86 Total 99,344,233.86
Selisih 0.00
 REAKSI DARI NERACA MASSA
--> Na2SO4 2H2O
0.00 233.90 kmol/hari
136.53 273.06 kmol/hari
136.53 506.95 kmol/hari
0.00 0.00

Hf standar komponen (kJ/mol)

4 -909.30
-63.00
4 -1,267.00
-241.80

-715.30 kJ/mol
-715,300.00 kJ/kmol
-97,658,599.12 kJ/mol
Q reaksi = - ∆H Reaksi
97,658,599.12 kJ/mol

Output
Komponen massa (kg/hari) laju Alir (kmol/hari)∫Cpdt (kJ/kmol) Q (kJ/hari) Q (kJ/hari)
H2O 20,964.69 1,163.41 377.46 439,137.47 -439,137.47
H2SO4 0.00 0.00 -557.93 0.00 0.00
 NaOH 0.00 0.00 431.48 0.00 0.00
Na2SO4 19,392.49 136.53 -3,577.80 -488,470.53 488,470.53

298.15
301.15
316.15
308.65

gak kanggo ojok diwoco

Qin = Qout + Qrx
1,685,634.74 2,254,072.57 97,658,599.12
98,227,036.95
 Output
Komponen BM Input
ringan berat
C20 312.00 54,545.45 54,545.45
C22 340.58 601.36 601.36
C16 256.00 4,972.80 4,972.80
C4 74.12 58,900.20 58,900.20
H2O 18.02 20,964.69 594.95 20,369.74
Na2SO4 142.04 19,392.49 19,392.49
total 159,377.00 159,377.00
Selisih 0.00

Dekanter
Aliran Masuk Aliran Keluar
Komponen Massa (kg/hari) Komponen Massa (kg/hari)
Aliran 7 Aliran 8
C20 54,545.45 C20 54,545.45
C22 601.36 C22 601.36
C16 4,972.80 C16 4,972.80
C4 58,900.20 C4 58,900.20
H2O 20,964.69 H2O 594.95
Na2SO4 19,392.49 Subtotal 119,614.77
Subtotal 159,377.00 Aliran 9
H2O 20,369.74
Na2SO4 19,392.49
Subtotal 39,762.23
Total 159,377.00 Total 159,377.00

selisih -

densitas g/cm3 urutan dari tinggi ke rendah

C20 0,862 Na2SO4
C22 0,9 H2O
C16 0,8534 C22
C4 0,797 c20
H2O 0,996 c16
Na2SO4 2,664 c4
T ref 25 oC 298.15 K
T in 30.00 oC 303.15 K
T out 30 oC 303.15 K

INPUT
massa (kg/hari) laju Alir (kmol/hari ∫Cpdt (kJ/kmol) Q (kJ/hari)
C20 54,545.45 174.82516025641 3,467.10 606,136.81
C22 601.36 1.7656899985319 3,790.50 6,692.84
C16 4,972.80 19.425017804688 3,243.50 63,004.97
C4 58,900.20 794.66004007016 818.75 650,629.94
H2O 20,964.69 1163.6835675527 377.46 439,239.83
Na2SO4 19,392.49 136.52816878602 -3,577.80 -488,470.53

OUTPUT
massa (kg/hari) laju Alir (kmol/hari ∫Cpdt (kJ/kmol) Q (kJ/hari)
Na2SO4 19,392.49 136.53 - 3,577.80 - 488,470.53
H2O 20,369.74 1,130.66 377.46 426,774.75
Subtotal
C20 54,545.45 174.82516025641 3,467.10 606,136.81
C22 601.36 1.76568999853192 3,790.50 6,692.84
C16 4,972.80 19.4250178046875 3,243.50 63,004.97
C4 58,900.20 794.660040070156 818.75 650,629.94
H2O 594.95 33.0238737150793 377.46 12,465.07
1,326,464.56
 Dekanter
Aliran Masuk Aliran Keluar
Komponen Energi (kJ/hari) Komponen Energi (kJ/hari)
Aliran 7 Aliran 8
C20 606,136.81 C20 606,136.81
C22 6,692.84 C22 6,692.84
C16 63,004.97 C16 63,004.97
C4 650,629.94 C4 650,629.94
H2O 439,239.83 H2O 12,465.07
Na2SO4 488,470.53 Subtotal 1,338,929.64
Subtotal 2,254,174.92 Aliran 9
H2O 426,774.75
Na2SO4 488,470.53
Subtotal 915,245.28
Total 2,254,174.92 Total 2,254,174.92

SELISIH -
488,470.53

488,470.53
426,774.75
915,245.28
Komponen BM Input Output
C20 312.00 54,545.45 54,545.45
C22 340.58 601.36 601.36
C16 256.00 4,972.80 4,972.80
C4 74.12 58,900.20 58,900.20
H2O 18.02 594.95 594.95
total 119,614.77 119,614.77
Selisih 0.00
C20
C22
nilai ∆Hf standar komponen (kJ/mol) C16
H2SO4 -909.30 C4
NaOH -63.00 H2O
Na2SO4 -1,267.00
H2O -241.80

Heater
Aliran Masuk
Komponen
Aliran 8
C20
C22
C16
C4
H2O
Subtotal

Qsupply
Subtotal
Total
 T ref 25.00 298.15 K
T in 30.00 oC 303.15 K
T out 200.00 oC 473.15 K

Input Output
∫Cpdt (kJ/kmol) laju alir Q (kJ/hari) ∫Cpdt (kJ/kmol) laju alir
3,467.10 174.83 606,136.81 133,443.01 174.83
-4,885.51 1.77 8,626.30 144,257.07 1.77
3,243.50 19.43 63,004.97 123,255.40 19.43
818.75 794.66 650,629.94 32,153.17 794.66
-3,577.80 33.02 118,156.24 13,469.67 33.02

Heater Qin +
Aliran Masuk Aliran Keluar 1,446,554.27
Energi (kJ/hari) Komponen Energi (kJ/hari) Qsupply - 0,05 Qsupply =
Aliran 8 Aliran 8 0.95
606,136.81 C20 23,329,196.40
8,626.30 C22 254,713.26
63,004.97 C16 2,394,238.38
650,629.94 C4 25,550,837.62 P
118,156.24 H2O 444,833.53 Ts
1,446,554.27 Subtotal 51,973,819.19 Hv
HL
53,186,594.66 Qloss 2,659,329.73 L
53,186,594.66 Subtotal 2,659,329.73 Qsupply =
54,633,148.92 Total 54,633,148.92 53,186,594.66

selisih 0.00
ut
Q (kJ/hari)
###
254,713.26
2,394,238.38
###
444,833.53

Qsupply = Qout + Qloss

Qsupply = 51,973,819.19 0,05 Qsupply
- 0,05 Qsupply = 50,527,264.92
Qsupply = 50,527,264.92
Qsupply = 53,186,594.66
Qloss = 2,659,329.73

4.5 bar
147.92 C
2742.88 kJ/kg
623.17 kJ/kg

m L
m 2,119.71
m. = 25,091.45
m. = 452,029.47
 Output (kg/hari)
komponen BM(kg/kmol) Input (kg/hari) Residu Destilat
C20 312.00 54,545.45 54,204.60 340.85
C22 340.58 601.36 579.14 22.21
C16 256.00 4,972.80 4,778.07 194.73
C4 74.12 58,900.20 1,244.50 57,655.70
H2O 18.02 594.95 9.94 585.01
TOTAL 119,614.77 119,614.77

yg masuk ke dalam
cooler yg teruapkan

Flash Distilasi

Aliran Masuk Aliran Keluar

Komponen Massa (kg/hari) Komponen Massa (kg/hari)
Aliran 10 Aliran 11
C20 54,545.45 C4 1,244.50
H2O 594.95 H2O 9.94
C22 601.36 C20 54,204.60
C16 4,972.80 C22 579.14
C4 58,900.20 C16 4,778.07
Subtotal 119,614.77 Subtotal 60,816.26
Aliran 12 (recycle)
C4 57,655.70
H2O 585.01
C20 340.85
C22 22.21
C16 194.73
Subtotal 58,798.51
Total 119,614.77 Total 119,614.77
T ref 25 oC 298.15 K
T in 200 oC 473.15 K
T out 200 oC 473.15 K

input
komponen massa (kg/hari) laju Alir (kmol/hari) ∫Cpdt (kJ/kmol) Q (kJ/hari)
C20 54,545.45 174.83 133,443.01 23,329,196.40 - 23,329,196.40
C22 601.36 1.77 144,257.07 254,713.26 - 254,713.26
C16 4,972.80 19.43 123,255.40 2,394,238.38 - 2,394,238.38
C4 58,900.20 794.66 32,153.17 25,550,837.62 - 25,550,837.62
H2O 594.95 33.02 13,469.67 444,717.02
total 51,973,702.67

output

komponen massa (kg/hari) laju Alir (kmol/hari) ∫Cpdt (kJ/kmol) Q (kJ/hari)

C20 57,655.70 184.79 133,443.01 24,659,457.31 - 24,659,457.31
C22 585.01 1.72 144,257.07 247,788.16 - 247,788.16
C16 340.85 1.33 123,255.40 164,108.47 - 164,108.47
C4 1,244.50 16.79 32,153.17 539,862.68 - 539,862.68
H2O 594.95 33.02 13,469.67 444,717.02
total 26,055,933.64

Qloss 25,917,769.04
 Flash Distilasi
Aliran Masuk Aliran Keluar
Komponen Energi (kJ/hari) Komponen Energi (kJ/hari)
Aliran 10 Aliran 11
C20 23,329,196.39 C4 539,862.68
H2O 444,717.02 H2O 444,717.02
C22 254,713.26 Subtotal 984,579.70
C16 2,394,238.38 Aliran 12
C4 25,550,837.62 C20 24,659,457.31
Subtotal 51,973,702.67 C22 247,788.16
C16 164,108.47
Subtotal 25,071,353.94
Qloss 25,917,769.04
Total 51,973,702.67 Total 51,973,702.67

selisih - 0.00
 (P = 1 atm)
Output (kg/hari)
Komponen BM (kg/kmol) Titik Didih (C) Input (kg/hari) Distilat
C20 312.00 397.00 54,545.45 0.00
C22 340.58 350.00 601.36 0.00
C16 256.00 351.00 4,972.80 0.00
C4 74.12 107.90 58,900.20 58,900.20
H2O 18.02 100.00 594.95 594.95
TOTAL 119,614.77 119,614.77

Komponen F (kmol/hari) zF D (kmol/hari) yD

C20 174.8252 0.1708 0.0000 0.0000
C22 1.7657 0.0017 0.0000 0.0000
C16 19.4250 0.0190 0.0000 0.0000
C4 794.6600 0.7763 58,900.2022 0.9900
H2O 33.0239 0.0323 594.9515 0.0100
TOTAL 1,023.6998 1.0000 59,495.1537 1.0000

P
Komponen Mol zi T bub (K) Psat (atm)
C20 174.8252 0.1708 7.42561E-06
C22 1.7657 0.0017 7.63956E-05
388.0938
C16 19.4250 0.0190 1.47503E-04
C4 -58,105.5421 0.7763 1.28826E+00
H2O 33.0239 0.0323 #NUM!
TOTAL -57,909.53 1
zi T dew (K) Psat (atm)
0.1708 1.79015E-01
T dew > T bub 0.0017 5.74856E-01
598.24
T bub (C) T dew ( C) 0.0190 5.64973E-01
114.94 325.09 0.7763 8.18632E+01
0.0323 #NUM!
TOTAL 1.0000
ANTOINE
No Komponen A B C
1 C20 4.1310E+01 -6.9075E+03 -9.9500E+00
2 C22 -7.9750E-01 -5.9182E+03 8.9492E+00
3 C16 3.4660E+01 -5.2645E+03 -8.8600E+00
4 C4 1.0928E+02 -6.3060E+03 -3.6947E+01
 5 H2O 2.9861E+01 -3.1522E+03 -7.3037E+04

HITUNGAN T BUB HITUNGAN T DEW

Komponen xW.Ki Komponen yD/Ki
C20 1.27E-06 C20 9.54E-01
C22 1.32E-07 C22 3.00E-03
C16 2.80E-06 C16 3.36E-02
C4 1.00E+00 C4 9.48E-03
TOTAL 1.00E+00 TOTAL 1.00E+00
ERROR 3.48E-05 ERROR 5.36E-05

PRES TEMP TOTAL KVL ISOBU-01 TOTAL KVL N-HEX-01 TOTAL KVL ETHYL-01
bar C
1.01325 0 0.0018525 1.6803E-11 1.7659E-10
1.01325 15 0.0065325 1.6803E-11 1.8541E-09
1.01325 30 0.0196387 1.6803E-11 1.5426E-08
1.01325 45 0.0515852 1.6803E-11 1.0380E-07
1.01325 60 0.1207845 1.6803E-11 5.6940E-07
1.01325 75 0.2562989 1.6803E-11 2.6170E-06
1.01325 90 0.4996981 1.6803E-11 1.0315E-05
1.01325 105 0.9055615 1.6803E-11 3.5550E-05
1.01325 120 1.5404240 1.6803E-11 0.000108915
Output (kg/hari)
Residu
54,545.45
601.36
4,972.80
0.00
0.00
119,614.77

W (kmol/hari) xW
174.8252 -0.0030
1.7657 0.0000
19.4250 -0.0003
-58,105.5421 1.0034
0.0000 0.0000
-57,909.5263 1.0000

1.00 atm
Ki zi.Ki
7.43E-06 1.27E-06
7.64E-05 1.32E-07
1.48E-04 2.80E-06
1.29E+00 1.00E+00
#NUM! #NUM!
1.00003
Ki zi/Ki
1.79E-01 9.54E-01
5.75E-01 3.00E-03
5.65E-01 3.36E-02
8.19E+01 9.48E-03
#NUM! 0.00E+00
1.00005

D E
0.0000E+00 0.0000E+00 mmHg
-2.5746E-02 1.0847E-05 mmHg
2.3000E-03 -3.6100E-13 mmHg
1.4462E-02 -3.9500E-13 mmHg
 2.4247E-09 1.8090E-06 mmHg

KOEFISIEN Ki
Komponen c
C20 K1 8.32E-07
C22 K2 9.49E-07
C16 K3 5.19E-07
C4 K4 2.13E-03
H2O K5

TOTAL KVL N-BUT-01

1.5504E-10
1.7685E-09
1.5830E-08
1.1135E-07
6.2937E-07
2.9486E-06
1.1750E-05
4.0690E-05
0.000124697
T T^2 T^3 T^4
-6.13E-07 3.70E-08 -6.87E-10 4.03E-12
-7.00E-07 4.23E-08 -7.86E-10 4.61E-12
-3.72E-07 2.21E-08 -4.02E-10 2.28E-12
-1.58E-04 3.22E-05 -5.21E-07 9.61E-09
 (P = 1 atm)
Output (kg/hari)
Komponen BM (kg/kmol) Titik Didih (C) Input (kg/hari) Distilat
H2O 18.02 100.00 594.95 25.82
C4 74.12 107.90 58,900.20 10,518.28
C16 256.00 351.00 4,972.80 4,036.52
C20 312.00 354.62 54,545.45 8,363.50
C22 340.58 381.50 601.36 219,687.88
TOTAL 55,146.81 280,948.77

MENCARI TDEW TBUB P

Komponen F (kmol/hari) zi T bub (K) Psat (atm)
H2O 33.0239 0.0323 1.58333002
C4 794.6600 0.7763 1.22243776
C16 19.4250 0.0190 386.5820 0.00012961
C20 174.8252 0.1708 0.00000658
C22 1.7657 0.0017 0.00006831
1,023.70 1
zi T dew (K) Psat (atm)
0.0323 119.34915065
T bub (C) T dew ( C) 0.7763 81.91606956
113.43 325.14 0.0190 598.2919 0.54660083
0.1708 0.17928069
0.0017 0.57558003
TOTAL 1
Antoine
No Komponen A B C
1 H2O 29.8605 -3.1522E+03 -7.3037E+00
2 C4 109.2803 -6.3060E+03 -3.69E+01
3 C16 34.6559 -5.2645E+03 -8.8645E+00
4 C20 41.3100 -6,907.50 -9.95
5 C22 -0.7975 -5.9182E+03 8.9492E+00

MENCARI PHI

T (C)
240
Komponen Zi P (atm) T (K) Psat (atm)
H2O 0.0323 32.990132

1 513.15
C4 0.7763 24.914936
C16 0.0190 1 513.15 0.047057
C20 0.1708 0.010029
C22 0.0017 0.048734

MENCARI V, L, x, y
Komponen F (kmol/hari) V (kmol/hari)
H2O 33.0239 26.8061
C4 794.6600 645.0405
C16 19.4250 15.7677
C20 174.8252 141.9089
C22 1.7657 1.4332
0.00
Komponen x
H2O 0.001196
C4 0.038029
C16 0.083784
C20 0.869441
C22 0.007570
TOTAL 1.000022

Komponen y
H2O 0.0394645
C4 0.9474988
C16 0.0039426
C20 0.0087201
C22 0.0003689
TOTAL 0.9999950
Output (kg/hari)
Residu
5.99
2,439.76
936.29
1,939.95
50,957.44
280,948.77

1.00 atm
Ki zi*Ki
1.58333002 0.05107717
1.22243776 0.94893294
0.00012961 0.00000246
0.00000658 0.00000112
0.00006831 0.00000012
1.00001381
Ki zi/Ki
119.34915065 0.00027029
81.91606956 0.00947632
0.54660083 0.03471511
0.17928069 0.95257200
0.57558003 0.00299665
1.0000304

D E
2.4247E-09 1.8090E-06 mmHg
1.4462E-02 -3.9480E-13 mmHg
2.3028E-03 -3.6120E-13 mmHg
0.0000E+00 0.0000E+00 mmHg
-2.5746E-02 1.0847E-05 mmHg

Ki phi
32.990132 -0.038268

0.812
 24.914936 -0.909469
0.047057 0.079842
0.812
0.010029 0.860721
0.048734 0.007201
0.00003

L (kmol/hari)
6.2178
149.6196
3.6574
32.9163
0.3324
 (P = 1 atm)
Output (kg/hari)
Komponen BM (kg/kmol) Titik Didih (C) Input (kg/hari) Distilat
H2O 18.02 100.00 594.95 585.01
C4 74.12 107.90 58,900.20 57,655.70
C16 256.00 351.00 4,972.80 194.73
C20 312.00 354.62 54,545.45 340.85
C22 340.58 381.50 601.36 22.21
TOTAL 119,614.77 119,614.77

MENCARI TDEW TBUB P

Komponen F (kmol/hari) zi T bub (K) Psat (atm)
H2O 33.0239 0.0323 1.58333002
C4 794.6600 0.7763 1.22243776
C16 19.4250 0.0190 386.5820 0.00012961
C20 174.8252 0.1708 0.00000658
C22 1.7657 0.0017 0.00006831
1,023.70 1
zi T dew (K) Psat (atm)
0.0323 119.34915065
T bub (C) T dew ( C) 0.7763 81.91606956
113.43 325.14 0.0190 598.2919 0.54660083
0.1708 0.17928069
0.0017 0.57558003
TOTAL 1
Antoine
No Komponen A B C
1 H2O 29.8605 -3.1522E+03 -7.3037E+00
2 C4 109.2803 -6.3060E+03 -3.69E+01
3 C16 34.6559 -5.2645E+03 -8.8645E+00
4 C20 41.3100 -6,907.50 -9.95
5 C22 -0.7975 -5.9182E+03 8.9492E+00

MENCARI PHI

T (C)
200
Komponen Zi P (atm) T (K) Psat (atm)
H2O 0.0323 15.315216

1 473.15
C4 0.7763 12.058741
C16 0.0190 1 473.15 0.010608
C20 0.1708 0.001637
C22 0.0017 0.009984

MENCARI V, L, x, y
Komponen F (kmol/hari) V (kmol/hari)
H2O 33.0239 32.4720
C4 794.6600 777.8697
C16 19.4250 0.7607
C20 174.8252 1.0925
C22 1.7657 0.0652
1,023.70 812.2742861
Komponen x
H2O 0.002610
C4 0.079415
C16 0.088279
C20 0.821721
C22 0.008043
TOTAL 1.000067

Komponen y
H2O 0.0399766
C4 0.9576441
C16 0.0009365
C20 0.0013450
C22 0.0000803
TOTAL 0.9999825
y (uap)
x (liq)
Output (kg/hari) Distilat (uap)
Residu Residu (liq)
9.94
1,244.50
4,778.07
54,204.60
579.14
119,614.77

1.00 atm
Ki zi*Ki
1.58333002 0.05107717
1.22243776 0.94893294
0.00012961 0.00000246
0.00000658 0.00000112
0.00006831 0.00000012
1.00001381
Ki zi/Ki
119.34915065 0.00027029
81.91606956 0.00947632
0.54660083 0.03471511
0.17928069 0.95257200
0.57558003 0.00299665
1.0000304

D E
2.4247E-09 1.8090E-06 mmHg
1.4462E-02 -3.9480E-13 mmHg
2.3028E-03 -3.6120E-13 mmHg
0.0000E+00 0.0000E+00 mmHg
-2.5746E-02 1.0847E-05 mmHg

Ki phi
15.315216 -0.037366

0.793
 12.058741 -0.878229
0.010608 0.087342
0.793
0.001637 0.820376
0.009984 0.007963
0.00008

L (kmol/hari)
0.551874796193473
16.7903418926455
18.6643509805264
173.732688015003
1.70046371067695
211.43
 T ref 25.00
T in 200.00
T out 30.00

input
BM(kg/kmol) komponen massa (kg/hari) laju Alir (kmol/hari)
74.12 C4 57,655.70 777.87
18.02 H2O 585.01 32.46

output
komponen massa (kg/hari) laju Alir (kmol/hari)
C4 57,655.70 777.87
H2O 585.01 32.46

Qpendingin 24,799,123.41

Kondensor
Aliran Masuk Aliran Keluar
Komponen Energi (kJ/hari) Komponen
Aliran 11 Aliran
C4 25,010,974.94 C4
H2O 437,285.18 H2O
Subtotal 25,448,260.12 Subtotal

Qpendingin
Total 25,448,260.12 Total

selisih 0.00

Q= m
24,799,123.41 m
m=
 oC 298.15 K
oC 473.15 K
oC 303.15 K

input
∫Cpdt (kJ/kmol) Q (kJ/hari)
32,153.17 ### ###
13,469.67 437,285.18 ###

Qin =
output ###
∫Cpdt (kJ/kmol) Q (kJ/hari) Qpendingin=
818.75 636,882.81 636,882.81
377.46 12,253.91 649,136.71

KEBUTUHAN AIR PENDING

C K
Aliran Keluar suhu ref 25.00 298.15
Energi (kJ/hari) suhu air in 28.00 301.15
Aliran suhu air out 43.00 316.15
636,882.81 suhu 35.50 308.65
12,253.91 Cp air pending 792.07
649,136.71 m 31,309.20

24,799,123.41
25,448,260.12

Cp dT
792.07 15.00
2,087.28 37,612.79
Qout + Qpendingin
649,136.71 Qpendingin
###
 T ref 25
T in 200
T out 30

input
BM(kg/kmol) komponen massa (kg/hari) laju Alir (kmol/hari)
312.00 C20 57,655.70 184.79
340.58 C22 585.01 1.72
256.00 C16 340.85 1.33

58,581.56

output
komponen massa (kg/hari) laju Alir (kmol/hari)
C20 57,655.70 184.79
C22 585.01 1.72
C16 340.85 1.33
total 58,581.56

Qpendingin = Qin - Qout

###

Cooler 2
Aliran Masuk Aliran Keluar
Komponen Energi (kJ/hari) Komponen
Aliran 12 Aliran
C20 24,659,457.31 C20
C22 247,788.16 C22
C16 164,108.47 C16
Subtotal 25,071,353.94 Subtotal

Qpendingin
Subtotal
Total 25,071,353.94 Total

selisih -
 oC 298.15 K
oC 473.15 K
oC 303.15 K

input
∫Cpdt (kJ/kmol) Q (kJ/hari)
133,443.01 ### ###
144,257.07 247,788.16 - 247,788.16
123,255.40 164,108.47 164,108.47
total ###

output
∫Cpdt (kJ/kmol) Q (kJ/hari)
3,467.10 640,699.52 640,699.52
3,790.50 6,510.88 - 6,510.88
3,243.50 4,318.55 4,318.55
total 638,507.20

Qpendingin +Qout = Qin + Qrx

Qpendingin 651,528.95 ### 0.00
Aliran Keluar Qpendingin ###
Energi (kJ/hari)
Aliran Q= m Cp dT
640,699.52 ### m 75.33 15.00
6,510.88 m= 21,610.28 389,417.19
4,318.55
651,528.95

24,419,824.99
24,419,824.99
25,071,353.94
suhu ref 25.00 298.15
suhu air in 28.00 301.15
suhu air out 43.00 316.15
suhu 35.50 308.65
Cp air pending 75.33