Science - Chemical compounds in plants that are ● FOOD SCIENCE important to promote healthful reactions - The study of the chemical, physical and in the body but are not classified as microbiological nature of foods and any nutrients required for life and growth transformation that food undergoes as reflected in its characteristics and ● GENETICALLY MODIFIED properties ORGANISM(GMO) - Plant or animal foods developed by ● FOOD genetic manipulation to alter nutrient - physiological: any substance which levels or other characteristics when taken into the body provides energy, builds and repairs tissues and ● DISPERSION regulates bodily processes - Mixture produced by scattering one - biological: any substance when eaten material in another and this could be sustains life and nourishes the body homogeneous and heterogeneous - socio-cultural: any substance that satisfies the human senses as well as ● PROBIOTIC FOOD emotional needs. - Foods which contain a live microbiological culture either as a result ● NATURAL FOOD of fermentation or as an intentional - A food product made without chemical addition by the manufacturer; healthful or artificial additives for normal intestinal function; prevent harmful bacteria from causing disease ● ORGANIC FOOD - Agricultural products grown and ● PREBIOTICS processed without using growth - Non-digestible carbohydrates that act as hormones, antibiotics, or food for probiotics petroleum-based or sewage sludge-based fertilizer LESSON 2: Physical & Chemical Properties of Food ● FOOD QUALITY ➔ The changes food undergo during - Collective term for all the attributes or cooking and processing can be characteristics of a food which explained by their physical properties determine whether it is acceptable or not ★ States of Matter 1. Solids – substances that do not flow ● FOOD ADDITIVE under moderate stress; state of matter which is in comparatively low energy - A substance added intentionally or state; molecules move slowly within a unintentionally to food that becomes defined space part of the food and affects its character 2. Liquids – substances which exhibit flow properties ● FUNCTIONAL FOOD 3. Gasses– the distance between - Food or beverage that imparts a molecules is extremely great; molecules physiological benefit that enhances move constantly and relatively faster overall health, helps prevent or treat a than molecules in liquids; have the ability to increase in volume and disease or condition, or improves develop pressure as heat is applied. physical/mental performance FDS: LECTURE
★ Dispersion Systems in Food
1. True Solutions - a uniform liquid mixture containing a solute and a solvent 2. Colloidal Systems - a two-phase system in which particles called micelles (discontinuous phase) have diameters between 1 millimicron and 0.1 micron - the dispersing medium may be gas, liquid or a solid substance containing Chemical Composition of Food either gas, liquid, or solid micelles ● Table 2. Chemical Composition of Food ➢ Four common types of colloidal systems in food: 1. Sol – a liquid gel; the mixture can be poured like true solutions - Ex. Hot gelatin before it sets; dilute starch in hot water 2. Gel – resembles solid in that it has shape and cannot be poured - Ex. Gelatin (solidified sol); starchy puddings; custards 3. Foam – gas is dispersed in liquid or solid medium - Ex. Liquid foam - (beating egg whites, whipping of cream, aerating carbonated drinks) - Solid foam – (marshmallows, gelatin sponge, leavened breads, baked sponge cakes 4. Suspensions – these rarely occur in foods; with particles greater than 0.1 ➔ WATER micron in diameter - The most abundant compound in food - Ex. Raw starch granules dispersed in ➔ CARBOHYDRATES cold water - Hydrates of carbon - General formula Cx (H20)y ● Table 1. Examples of colloidal ➔ PROTEINS systems in foods: - Polymer of amino acids linked together by peptide bonds ➔ FAT - A triglyceride, which is an organic esters of 3 molecules of fatty acids combined w/ one molecule of glycerol FDS: LECTURE
- Used as food ingredient for their thickening,
➔ VITAMINS gelling, and stabilizing properties - General term given to a group of organic ➔ ORGANIC ACIDS substances that are present in food in - Organic compounds w/ acidic properties. minute quantities ➔ TANNINS - It is essential for normal health & growth - Compounds in tea, coffee, wine, grapes, ➔ MINERALS peas and lentils, which can denature protein - An inorganic element that remains ash and bind iron. when food is burned - Considered as phytochemicals that are - Classified as either water (B-complex antioxidants vitamins and Vitamin C) or fat soluble ➔ ESTERS (vitamins A, D, E, K) - A chemical compound derived from an acid ➔ PIGMENTS (organic or inorganic) in w/c at least one - In plants, include chlorophyll and –OH (hydroxyl) group is replaced by an –O carotenoids w/c are fat soluble and alkyl (alkoxy) group. flavonoids and tannins w/c are water ➔ KETONES soluble - Compound containing the carbonyl group - In animals, hemoglobin in blood and (C=O) derived from oxidation of a secondary myoglobin in the muscle alcohol. LESSON 3: Heat in Food Preparation Common Pigments found in Food ➢ HEAT - A form of energy due to the vibratory or kinetic movement of molecules; its intensity (hotness) is measured by degrees Centigrade or Celsius and degrees Fahrenheit ➢ COOKING - Refers to the process and techniques of using food or combinations of foods as to achieve a product w/c is edible, palatable, aesthetically pleasing, nutritious and microbiologically safe w/ application or removal (by freezing) of heat. ➢ CONDUCTION - The direct transfer of heat via metals or any heat conducting materials containing the food. ➔ ENZYMES - Copper has the highest rate of conductivity - Organic catalysts that are produced by while glass is the poorest living cells that is responsible for the most ➢ CONVECTION of the chemical reactions and energy - Transfer of thermal energy from electricity, transformation in both plants and animals gas, or solid fuel to the vapor molecules of ➔ GUMS the air w/c in turn heat the food or the - A diverse group of polysaccharides usually utensil it comes in contact with isolated from seeds and is highly viscous FDS: LECTURE
➢ RADIATION C. EFFECT OF ACID
- Transfer of heat from a red coil of the griller, ➢ Chlorophyll changes into undesirable olive toaster or stove to the food green color ➢ MICROWAVE ➢ Too acidic jelly will result to syneresis - Method of heat transfer that uses ➢ Viscosity and texture are affected such as electromagnetic waves generated by the vinegar and citric acid reduce the thickness magnetron (a special vacuum tube); these of the hot starch paste and the firmness of waves penetrate the food disturbing the the cooled paste; this is why accurate molecular structure; causing friction and measurement of acid in starch-thickened developing heat that cooks food in a products like pie filling is critical, otherwise relatively short time. the product becomes “runny” D. PHYSICAL AND MECHANICAL TREATMENT Physio-Chemical Changes in Food During ➢ Agitation and stirring Preparation ➢ Whipping or beating – introduces air into a A. EFFECT OF HEAT TREATMENT mixture resulting in tenderness and greater ➢ PROTEIN – heat causes coagulation and stability as foam cakes eventual denaturation of protein in foods ➢ Kneading – allows alignment of the gluten like meat, eggs, poultry network resulting in tenderness in baked ➢ FATS – fats can be removed or absorbed; products and allows gas produced by the overheating results in the formation of yeast during fermentation to get trapped in acrolein w/c is the characteristics flavor of the gluten network w/c is responsible for burnt oil; reheating oil causes lowering of the volume of the read when baked the smoke point and reversion of flavor ➢ STARCH- with water when heated, results in LESSON 4: Assessment of Food Quality an increased in viscosity in the process called gelatinization (moist cooking) and ❖ FOOD MICROBIOLOGY therefore, is useful as thickener or binder; - Study of microscopic organisms and their - with (dry heat), such as roasting or toasting, activities, their characteristics and their starch is changed to dextrin in the process beneficial and harmful effects to food and of dextrinization man ➢ SUGAR ❖ FOOD INFECTION - sucrose added w/ water raises boiling point - An illness resulting from ingestion of food - At 160˚C, the sucrose concentration is containing large numbers of living bacteria 100%; at temperatures above 160˚C or other microorganisms (melting point of sugar) sugar melts and ❖ FOOD INTOXICATION sucrose changes color from white to brown - Caused by the ingestion of toxins or B. EFFECT OF COLD poisonous substances produced by ➢ Temperature change of food from room to pathogenic microorganism cold to frozen affects both the functional ❖ FOODBORNE ILLNESS and eating qualities of food such as - A disease of an infectious or toxic nature difficulty in separating egg white from the caused by the consumption of food and yolk; meat improves tenderness and flavor water when frozen; softening of fruits and ❖ OUTBREAK vegetables occur during cold storage and - The occurrence of two or more cases of a freezer burn occurs similar illness resulting from ingestion of a common food FDS: LECTURE
❖ FOOD SAFETY 2. Disaccharides
- The overall quality of food fit for - sugars composed of two consumption monosaccharide units. Upon hydrolysis - Sanitary quality; freedom from pathogenic they yield two molecules of microorganisms; toxins and other biological monosaccharides. hazards; absence of physical and chemical Examples: contaminants, and safe level of food ● Sucrose = glucose + fructose additives ● Maltose = glucose + glucose ❖ MICROORGANISMS ● Lactose = glucose + galactose - Unicellular (one-celled) living things. ➔ Sucrose (Table Sugar, Cane Sugar, ❖ CONTAMINATION Beet Sugar) - The unintended presence of harmful ● Found in many fruits and vegetables substances in food or drink ● Hydrolyzed into one molecule of ❖ CROSS-CONTAMINATION glucose and fructose - The transfer of germs or microbes from one ● Commercially prepared as sugar food item to another via a nonfood surface cane or sugar beets or equipment ➔ Lactose (Milk Sugar) SUGAR AND SUGAR COOKERY ● Primarily found in dairy products Classification of Sugar ● See lactose intolerance (Page 219) A. Classification According to Chemical ➔ Maltose (Malt Sugar) Form ● Hydrolyzes 2 molecules of glucose B. Classification According to Source C. Classification According to Market Form ● Found in cereals and starches Classification According to Chemical Form ➔ Syrup 1. Monosaccharides – carbohydrate - sugary solutions varying in viscosity, molecules that cannot be broken down carbohydrate concentration, and to simpler carbohydrates by hydrolysis flavor Examples: A. Cane Syrup – made by boiling the ● Glucose (or grape sugar) sugar cane sap to a concentrated ● Fructose (or fruit sugar/levulose) solution ● Galactose B. Molasses – the residue that remains ➔ Glucose (Grape Sugar, Physiologic after sucrose crystals have been Sugar) ● Found in fruits and plant saps removed from the concentrated juice ● Hydrolyzed from maltose, lactose or of sugar cane or beet sucrose C. Refiner’s Syrup – the liquor that ➔ Fructose (Levulose, Fruit Sugar) remain after crystallization of ● Found in fruits, honey or plant saps. sucrose during the refining process ● Present in sugar mixtures like molasses D. Sorghum Syrup – made from and invert sugar sorghum, a cane plant that grows ● Hydrolyzed form of sucrose and inulin easily in temperate climates ● Sweetest of natural sugars E. Maple Syrup – made by ➔ Galactose evaporating sap of sugar maple tree ● Does not occur in free nature but is hydrolyzable from lactose or milk sugar to a concentration containing no more than 35% water FDS: LECTURE
F. Corn Syrup – a viscous liquid 5. Caramelization
containing maltose, dextrin, dextrose - results when sugar is heated and other polysaccharides; can 6. Hygroscopicity (moisture absorption) control crystallization in candy - sugars can attract and retain making and has moisture– moisture containing properties; prepared by *fructose absorbs the most moisture partial hydrolysis of starch with acid 7. Texture G. High Fructose-Corn Syrup (HFCS) - the texture of many processed food – differs from the conventional corn relies on sweeteners syrup because it contains fructose *without sugar, soft drinks feel flat in and levulose in a high range of the mouth 42–90%. 8. Fermentation H. Honey – comes from nectars of - carbohydrates ferment (ex. flowers that is collected, modified manufacture of beers, wines, and concentrated by the honeybees; cheeses, yogurts, and certain locally known as “pulut pukyutan” breads) -*strained honey – sold in the local 9. Preservation market; a thick syrup separated from - high concentrations of sugar act as the comb preservative by preventing the I. Invert Sugar – an equal mixture of growth of microorganisms; increase glucose and fructose, created by the osmotic pressure by dehydrating hydrolyzing sucrose; it resist the bacteria or yeast cells crystallization and yields a smooth Manufacture of Sugar melt–in–the–mouth texture ● Cane sugar, which is the sole source Characteristics of Sugar of table sugar in the Philippines, is 1. Sweetness manufactured by extracting the juice - sugars differ in their ability to from crushed sugar cane sweeten bland foods or minimize ● The juice is then purified, by heating sour tastes w/ lime. The purified juice is evaporated into a concentrated syrup until crystals are formed. 2. Solubility ● The crystals are washed, - sugar’s ability to dissolve in water redissolved, decolorized and recrystallized in several stages: brown, light brown, golden or yellow, - rise in temperature increases off-white and finally to pure white solubility of sugar refined sugar. 3. Crystallization Market Forms of Sugar - important in candy making 1. Crystalline (or granulated sugar) - - crystal formation determines the most common form of table sugar finished product’s quality Ex. dextrose and table sugar 4. Browning Reactions 2. Sanding Sugar - coarsely - involve sugar and protein due to granulated for decorative purposes Maillard reaction FDS: LECTURE
3. Superfine Sugar- specially
screened, uniformly fine–grained 3. Maillard Reaction – non–enzymatic sugar for rapid solution browning that occurs when a protein 4. Powdered (or confectioner’s and a sugar are heated or stored sugar)- machine–ground from together for some time. granulated sucrose; small quantities Ex. crust of a cake of cornstarch are added to prevent 4. Effect of sugars on Freezing and caking Boiling Points 5. Lump Sugar – prepared by pressing *Colligative Property: the higher the wet sugar crystals into a loaf form, concentration of sugar, the greater hardened and then cut into cubes or the effect on freezing and boiling tablets points 6. Brown Sugar – partially purified 5. Fermentation product of crystals varying from very - glucose is highly fermentable by light to very dark brown yeast, sucrose, invert sugar, corn 7. Raw Brown Sugar (or moscovado syrup, and fructose sugar) – unrefined product - lactose is acted upon by lactic acid separated from molasses; crystals bacteria to produce lactic acid are dark, coarse and sticky because - starch yields maltose which is they contain some molasses fermentable by carbohydrate; further 8. Panutsa – a crude form of sugar; enzyme action by the yeast sugar cane extract is evaporated produces carbon dioxide and water into a brown syrup concentrate and (leavening agents of bread) molded in polished, small–halved Functions of Sugar in Food Preparation, coconut shells Principles, Application 9. Washed Sugar- sucrose crystal A. Sweetening Agent which is one step short of the *provides sweetness to food complete refining process *has the function of altering other basic tastes (reduces the sharp Chemical Reactions of Sugar tartness or acidity of a food and it 1. Hydrolysis – uptake of sugar tones down saltiness) (sucrose) of a molecule of water and B. Main Ingredient the resultant splitting into two *sugar in confections like candies component monosaccharides and icings, acts as the structural Hydrolysis or inversion of sucrose: foundation of the product C. Preserving Agent *in highly sugared products (candied 2. Caramelization – series of chemical fruits, jams, jellies); has a reactions which take place when dry dehydrating effect on spoilage of sugar is heated to intense microorganisms temperatures yielding polymers *binds with water resulting in a ranging in size from trisaccharides to reduced availability of the water for oligosaccharides. microbial activity * the product is called caramel FDS: LECTURE
D. Colorant and Flavoring Agent *examples are protein gels like
*brown sugar, molasses, maple custards and in starchy sauces or syrup, caramelized sugar, and honey puddings provide distinct color and subtle *excess sugar, however, results in a flavor to food runny or liquefied product *caramelized sugar provides a Alternative Sweeteners golden brown color and flavor - non–nutritive substances providing E. Texture Modifier minimal to zero calories *due to crystallization, aeration, Sweeteners Approved by US FDA: foaming, and its viscosity and 1. Saccharin hygroscopicity (fudges, *500x sweeter than sucrose with a bitter marshmallows, taffy, frozen aftertaste desserts, sponge cakes, and icings) *Ex. Sweet–n–Low F. Peptizing Agent 2. Aspartame *in batters and doughs, sugar in *180x sweeter than sucrose; a synthetic increasing amounts prevents gluten combination of two development resulting a tender, amino acids (aspartic acid and moist product phenylalanine) G. Volume and Structure Improver *it is metabolized to phenylalanine and *in jellies, cakes, and cookies, sugar should not be is part of the framework and volume consumed by individuals with of the product phenylketonuria or PKU *in jelly, it precipitates pectins and *Ex. NutraSweet, Spoonful, Equal together they form the network for 3. Acesulfame–K gel formation *130x sweeter than sucrose with a bitter *in yeast breads, sugar is the food aftertaste for the yeast growth and indirectly it *Ex. Sunette, Sweet One contributes to the volume because of 4. Sucralose the accompanying formation of *a modified form of sucrose but 600x gaseous carbon dioxide which sweeter leavens the bread *Splenda *in pound cakes and cookies in 5. Neotame which the irregular crystal surfaces *8 000x sweeter than sugar and has no of the sugar are able incorporate air calories as it is whipped or beaten with *made from amino acids (aspartic acid and plastic fat phenylalanine) but not H. Humectant metabolized to phenylalanine *because of its hygroscopic ability, products with added sugar, Criteria for an item to be considered as a especially fructose and invert sugar, food keep food moist and soft I. Tenderizing Effect *delays gel formation and results in a more tender product