Question 1

In _________________ reaction, a conjugated diene is treated with an unsaturated compound called

dienophile to yield a cyclic system. (A) Diels-Alder reaction (B) Wittig reaction (C) Wurtz reaction (D)
Kolbe electrolytic reaction

ANS: A

Question 2

The terminal alkynes on hydroboration give _________________________. (A) alkanes (B) alkenes (C)
aldehydes (D) ketones

ANS: C

Question 3

Reactions that lead to the attachment of alkyl group to a molecular fragment are called
____________________________. (A) Acylation reaction (B) Addition reaction (C) Nucleophillic reaction
(D) Alkylation reaction

ANS: D

Question 4

__________________ involves elimination of the halogen atom together with a hydrogen atom from an
adjacent carbon atom. (A) Dehydrohalogenation (B) halogenation (C) hydrohalogenation (D)
Dihydrohalogenation

ANS: A

Question 5

Alkyl halides are converted into alkenes by _______________ by treating with a strong base. (A)
hydrogenation (B) dehydrogenation (C) alkylation (D) acylation

ANS: B

Question 6

Rapid decolourization of bromine solution serves as a test for the presence of the
___________________ in a compound. (A) C-C (B) C=C (C) C???C (D) C=O

ANS:B

Question 7
Pyrolysis of alkanes particularly where petroleum is concerned is known as ______________- (A)
Cracking (B) Refining (C) Fractional distillation (D) Combustion

ANS: A

Question 8

When alkene reacts with borane, addition to the C=C takes place to yield organoborane a compound
with a carbon-boron bond, the reaction is known as ____________________. (A) hydrogenation (B)
halogenation (C) hydroboration (D) hydrohalogenation

ANS: C

Question 9

In _____________ compounds, the molecules are formed by the sharing of electron pairs between the
constituent atoms. (A) non-covalent (B) electrovalent (C) ionic (D) covalent

ANS: D

Question 10

Which of the compounds is \[Sp^{2}\] hybridized. __________ (A) alkene (B) alkanone (C) alkane (D)
alkyne

ANS: A

Question 11

______________ compound has a benzene ring with a methyl group at position one. (A) Aniline (B)
Phenol (C) Toluene (D) Anisole

ANS: C

Question 12

A benzene ring with $$ OCH_{3}$$ t position one, F at position two and $$CH_{3}CH_{2}$$ at position
four is --------------. (A) 4-ethyl-2-fluorotoluene (B) 2-fluoro-4-ethyl toluene (C) 2-fluoro-4-ethylanisole (D)
4-ethyl-2-fluoroanisole

ANS: D

Question 13

A benzene ring with a methyl group at position one and nitro group at position three is ------------. (A) o?
^'nitrobenzene (B) p?^'nitroxylen (C) o?^'nitroaniline (D) p?^'nitrotoluene

ANS: D
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Question 14

The name of this compound $$HO_{2}C?^'CO_{2}H$$ is ____________ (A)ethanedioic acid (B)

hexanedioc acid (C) propenoic acid (D) octadecanoic acid

ANS: A

Question 15

The decarboxylation of carboxylic acid yields which of the following compound________. (A) alkenes (B)
alkanes (C) alkylhalides (D) alkynes

ANS: B

CHM102_PRACTICE_SET 2

Question 1

Which of these theoretical concept enables realistic modelling of molecular structure?___ (A)
hydrogenation (B) substitution (C) ionization (D) hybridization

ANS: D

Question 2

____________ is how a sigma (??) bond is formed. (A) edge-on overlap of p orbitals (B) sideways overlap
of p orbitals (C) edge-on overlap of pure s and p orbitals (D) sideways overlap of s and p orbitals

ANS: C

Question 3

The relationship between bond length and bond order is ___________- (A) Bond order increases as
bond length decreases (B) Bond order increases as bond length increases (C) Bond order decreases as
bond length decreases (D) Bond order decreases as bond length increases

ANS: A

Question 4
____________ determines the number of hybrid orbitals generated. (A) Number of protons (B) Number
of electrons (C) Number of atomic orbitals (D) Number of shells

ANS: C

Question 5

All these are methods of preparation of alkenes EXCEPT _________ reaction method (A) Retro Diels-
Alder (B) Dehydration of alcohols (C) Wittig (D) Cannizaro

ANS: D

Question 6

In allene the central atom is----------- hybridized and the terminal atoms are -------------- hybridized (A) \
[Sp^{2},Sp^{3}\] (B) Sp, \[Sp^{2}\] (C) Sp, \[Sp^{3}\] (D) \[Sp^{2}\],Sp

ANS: B

Question 7

The addition of ozone to an alkyne produces _________. (A) Ozonide (B) ozonede (C) Ozonade (D) None
of the above

ANS: A

Question 8

The reaction between an alkyl halide and sodium metal to form an alkane is called _______ reaction. (A)
Wittig (B) Diels-Alder (C) Kolbe (D) Wurtz

ANS: D

Question 9

A benzene ring with a methyl group at position one and nitro group at position three is _________ (A) p?
^'nitrotoluene (B) p?^'nitroxylen (C) o?^'nitrobenzene (D) o?^'nitroaniline

ANS: A

Question 10

The first product in fractionation of petroleum is called _________. (A) Gasoline (B) Natural gas (C) Light
petrol (D) Paraffin

ANS: B

Question 11
Increase in number of carbon atoms results in the following effects EXCEPT ________. (A) Surface area
increases (B) Boiling point increases (C) Melting point increases (D) Intermolecular forces increases

ANS: C

Question 12

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A catalyst mixed with a selective inhibiting agent is called ________ catalyst. (A) Acidic (B) Basic (C)
Neutral (D) poisoned

ANS: D

Question 13

The hydrohalogenation of alkynes is in accordance with ________. (A) Hund's rule (B) Sayzeff rule (C)
Markownikoffs rule (D) Anti markownikoffs rule

ANS: C

Question 14

A reaction in which the double bond is completely broken and alkene molecule is converted into two
smaller molecules is called _______. (A) Hydroxylation (B) Epoxilation (C) Ozonolysis (D) Hydroboration

ANS: C

Question 15

Wittig reaction is applicable to __________. (A) Benzene (B) Carbonyl compounds (C) Alcohols (D) Alkyl
halides

ANS: B

CHM 102_PRACTICE_SET 3

Question 1

The amount of energy required to break a particular bond is called ______________ . (A) bond
dissociation energy (B) bond energy (C) kinetic energy (D) potential energy
ANS: A

Question 2

The average distance between the nucleus of atoms which are covalently bond together is __________.
(A) bond height (B) bond circumference (C) bond length (D) bond diameter

ANS: C

Question 3

The number of hybrid orbitals generated is always _________ the number of atomic orbitals combined.
(A) greater than (B) less than (C) equal to (D) proportional to

ANS: C

Question 4

________ can be defined as an atom or group of atoms in a molecule which exhibits characteristic
chemical properties (A) hybridization (B) functional group (C) covalent bond (D) ionic bonding

ANS: B

Question 5

__________ best describes the functional group of an alkene. (A) C?"EURC (B) C???C (C) C=C (D) None of
the above

ANS: C

Question 6

Hydrocarbons can be classified as _______________. (A) alkane,alkene,alkyne (B) amine,amide,imine (C)

ester,ketone,aldehyde (D) aliphatic,alicyclic,aromatic

ANS: D

Question 7

Saturated hydrocarbons contain the carbaon and hydrgen atoms linked to each other by ________
bonds. (A) double (B) triple (C) multiple (D) single

ANS: D

Question 8

__________ provide the backbone to which various functional groups maybe attached to yield an
enormous variety of organic compounds. (A) iupac nomenchlature (B) hydrocarbons (C) sigma bonds (D)
structural formula
ANS: B

Question 9

Compounds having carbon-nitrogen single bond are called amines and are of 3 types which are
_________. (A) saturated,unsaturated,polysaturated (B) primary,secondary,tertiary (C)
nuclear,extended,parallel (D) polar,bipolar,non-polar

ANS: B

Question 10

_________ compound formds the backbone in aromatic compounds to which various functional groups
are derived (A) aliphatic (B) alkyne (C) carboxyl (D) benzene

ANS: D

Question 11

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_________ is the functional group in this compound $$CH_{3}?"EURCH=CHOH$$ (A) alkyne (B) imine (C)
alkene (D) aromatic

ANS: C

uestion 12

In naming alkyl halides, a ----------- is introduced to the alkane names (A) Prefix (B) Attachment (C) Suffix
(D) None of the above

ANS: A

Question 13

An alkyl group that has three carbon atoms bonded to the carbon atom taken as point of attachment is
called__________ (A) Secondary (B) Tertiary (C) Quartenary (D) Primary

ANS: B

Question 14
In iupac nomenchlature of alkenes, the _______ group is given the lowest possible number. (A)
functional (B) parent (C) methyl (D) None of the above

ANS: A

Question 15

When 1,5- dihalogen derivatives of alkanes are treated with sodium or zinc , the product formed is
__________. (A) alkyne (B) alkyl halide (C) cycloalkane (D) alkene

AND: C

CHM 102_PRACTICE_SET 4

Question 1

_____________ is formed when bromoethane is treated with potassium hydroxide in alcoholic solution
(A) ethene (B) ethyne (C) ethane (D) alkylhalide

ANS: A

Question 2

A benzene ring with a nitrogen heteroatom is called __________. (A) furan (B) Thiophene (C) Quinoline
(D) Pyridine

ANS: D

Question 3

Hydroboration can be described as __________. (A) Hund's addition (B) Sayzeff addition (C) Anti
markownikoffs addition (D) Markownikoffs addition

ANS: C

Question 4

________ is the process where finely powdered coal is hydrogenated in presence of catalyst such as tin
and lead to give a mixture of liquid hydorcarbons. (A) bergius process (B) fischer-tropoch (C) pyrolysis
(D) None of the above

ANS: A

Question 5

Terminal alkynes on hydroboration give _________. (A) Alkanes (B) Ketones (C)Alkyl halides (D)
Aldehydes

AND: D
Question 6

The following are methods of preparation of acetylene EXCEPT ___________. (A) Acylation of ethyne (B)
Alkylation of ethyne (C) Dehydrohalogenation of dihalides (D) Dehalogenation of tetrahalide

ANS: A

Question 7

The lobes of \[Sp^{3}\] are separated by ________ (A) Orbital (B) Node (C) Antinode (D) None of the
above

ANS: B

Question 8

The number of hybrid orbitals generated is determined by __________ combined. (A) Number of shells
(B) Number of protons (C) Number of atomic orbitals (D) Number of electrons

ANS: C

Question 9

The catalyst required for the hydrogenation of unsaturated hydrocarbons at moderate temperature and
pressure is__________ (A) Palladium (B) Nickel (C) Vanadium v Oxide (D) Iron

ANS: A

Question 10

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The benzene derivative formed when an incoming substituent occupies position three is ___________.
(A) Ortho (B) Meta (C) Para (D) None of the above

ANS: B

Question 11

Alkanes are also known as ______________________. (A) Paraffins (B) Olefins (C) Asphalt (D) Cetanes
ANS: A

Question 12

A benzene ring with hydroxyl group on carbon 1 is called __________________. (A) Phenol (B) Toluene
(C) Benzaldehyde (D) Aniline

ANS: A

Question 13

Intermolecular forces depend on the following except _________________. (A) Bond lenght (B) Number
of electrons (C) Surface area of molecule (D) Dipole moment

ANS: A

Question 14

_______________________ is a process of converting aliphatic or alicyclic compounds to aromatic

hydrocarbons.

ANS: aromaturation

Question 15

Catalytic aromatization in the presence of platinum is sometimes referred to as ________________.

ANS: platforming or hydroforming

CHM 102_PRACTIC_SET 5

Question 1

Catalytic aromatization in the presence of platinum is sometimes referred to as ________________.

ANS: platforming or hydroforming

Question 2

_____________ is a process of decomposing an organic substance by heating it to high temperature in

the absence of oxygen.

ANS: pyrolysis

Question 3

Pyrolysis of alkanes particularly where petroleum is concerned is known as ______________.

ANS: cracking
Question 4

The shape of alkenes is influenced by the presence of the ______________ which is the site of most of
the chemical reaction.

ANS: double bond

Question 5

The carbon atoms in double bond formation are Sp?? hybridized with bond angle of ___________.

ANS: 120 degree

Question 6

Alkyl halides are converted into alkenes by ____________________ by treating with a strong base.

ANS: dehydrohalogenation

Question 7

The ease of hydrohalogenation of alkyl halides is ___________________________.

ANS: tertz>sec>p

Question 8

Rapid decolourization of bromine solution serves as a test for the presence of the ______________ in a
compound.

ANS: carbon-carbon double bond

Question 9

____________________ states that addition of a hydrogen halide to an unsymmetrical alkene takes

place in such a way that the negative part of the reagent goes to that carbon atom of the alkene which
carries the lesser number of hydogen atoms.

ANS: markownikoffs

Question 10

Alkyl halides in which the halogen atom is attached to a __________________________ carbon atom
and both adjacent position have hydrogen atoms yield a mixture of alkenes.

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ANS: non terminal

Question 11

When alkene reacts with borane, addition to the c=c takes place to yield organoborane, a compound
with a carbon-boron bond the reaction is known as ________________________.

ANS: hydroboration

Question 12

In _______________ compounds the molecules are formed by the sharing of electron pairs between the
constituent atoms.

ANS: Covalent

Question 13

_________________________ increases with the increasing size of the bonded atoms.

ANS: bond length

Question 14

______________ bonds are formed by the edge on overlap of pure ( s and p ) or hybrid orbitals.

ANS: sigma

Question 15

_______________ can be defined as the average distance between the nuclei of the atoms which are
covalently bound together.

ANS: bond length

CHM 102_PRACTIC_SET 6

Question 1

A ______________________ can be defined as an atom or a group of atoms in a molecule which

exhibits characteristic chemical properties.

ANS: Functional group

Question 2

Reactions that lead to the attachment of alkyl group to a molecular fragment are called
___________________.

ANS: alkylation

Question 3

The ____________________ provide a backbone to which various functional groups maybe attached to
yield an enormous variety of organic compounds.

ANS: hydrocarbon

Question 4

The compounds containing carbon and oxygen linked by a double bond called carbonyl group can be
classified as _______________.

ANS: aldehydes or keytones

Question 5

The carbon - nitrogen double bond is characteristic of the class of compound known as
______________.

ANS: imines

Question 6

In aromatic compounds ____________ forms the backbone to which various functional groups can be
derived.

ANS: benzene

Question 7

______________________ are the compounds that have identical molecular formulas but differ in the
ways in which the atoms are bonded to each other.

ANS: isomers

Question 8

Compounds that differ from each other in their molecular formulas by the unit - CH?,,-are called
members of a ______________________.

ANS: homologous series

Question 9

The iupac name for the this compound NH?,,-CH?,,-CH?,,-CH?,,-CH?,,- NH?,, is __________________.

ANS: 1, 4, diamine butane

Question 10

Aromatic compounds containing hetero atoms such as O, N or S in the aromatic ring are called
__________________ compounds.

ANS: heterocyclic

Question 11

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In ______________ process of synthetic petroleum, finely powdered coal is hydrogenated in the

presence of catalysts such as tin and lead to give a mixture of liquid hydrocarbons.

ANS: bergius

Question 12

The quality of a diesel fuel is expressed in terms of a number called _____________ number.

ANS: octane

Question 13

The carbon atoms in alkanes are Sp??? hybridized with a bond angle of ______________.

ANS: 109.5 degrees

Question 14

The molecular rearrangement of one compound into another compound or into more than one
compound is called _______________________.

ANS: isomerization

Question 15
Give the iupac nomenchlature for this structure CH?,?-CH?,,-CH(CH?,?)-CH(CH?,,)(CH?,?)-CH?,,-CH?,,-
CH?,? is __________________________.

ANS: no answer

CHM 102_PRACTICE_SET 7

Question 1

The iupac name for the structure CH?,?-CH(CH?,?)-C???C-CH?,? is _____________________.

ANS: no answer

Question 2

Seperating the crude petroleum into useful components is called ___________________.

ANS: refining

Question 3

_______________________ is used to increase the branched chain content of lower alkanes produced
by cracking.

ANS: isomerization

Question 4

The first step in refining is ______________________.

ANS: fractional distillation

Question 5

The iupac name for the structure CH?,?-CH(CH?,?)-CH(CH?,,)(CH?,?)-CH?,,-CH(CH?,?)-CH(CH?,?)-CH?,,-

CH?,? is _____________________.

ANS: no answer

Question 6

When a concentrated solution of Na??? or K??? salt of a carboxylic acid is electrolysed to form an
alkane, it is called ______________________ method.

ANS: Kolbe's electrolytic

Question 7
Alkanes or cycloalkanes can be prepared by hydrogenation of unsaturated hydrocarbons using
___________________ as catalyst.

ANS: platinum or palladium

Question 8

The products formed during cracking of alkane depend upon structure of alkane, the pressure employed
and ____________________.

ANS: the presence or absence of a catalyst

Question 9

______________________________reaction involves elimination of the halogen atom together with a

hydrogen atom from an adjacent carbon atom.

ANS: dehydrohalogenation

Question 10

In addition reactions of alkene, the pie bond is broken and the electron pair comprising it, is used in the
formation of two new _____________ bonds.

ANS: sigma

Question 11

The iupac nomenchlature for the structural compound CH?,?-CH(OH)-CH?,,-CH(CH?,?)-CH?,? is

_______________________________________.

ANS: no answer

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Question 12

The iupac nomenchlature for the structural compound Cl(CH?,,)-CH(I)-CH?,,-CH(CH?,?)-CH?,,(Br) is

________________________________.

ANS: no answer
Question 13

In ___________________________ reaction, a conjugated diene is treated with an unsaturated

compound called the dienophile to yield a cyclic system.

ANS: diels-alder

Question 14

Reactions that lead to the attachment of an alkyl group to a molecular fragment are called
______________________.

ANS: alkylation

Question 15

The process by which enols are converted into aldehydes or ketones is called
_________________________________.

ANS: keto-enol

CHM 102_PRACTICE_SET 8

Question 1

The terminal alkynes on hydroboration give _________________.

ANS: aldehydes

Question 2

When alkenyl borane formed after the addition of borane to alkynes, is treated with ethanoic acid to
yield cis-alkenes, the reaction is known as _______________________________________.

ANS: hydroboration

Question 3

_________________________________ can also be carried out by reacting ethyne and grignard

reagent, followed by the action of an alkyl halide.

ANS: alkylation

Question 4

The reaction between an alkyl halide and sodium metal to form an alkane is called _______ reaction.

ANS: wurtz
Question 5

The process of Aromatization involves three processes which include cyclisation, isomerization and
_________________.

ANS: dehydrogenation

Question 6

Hydrogenation of an alkene can be carried out by using nickel catalyst but relatively higher temperature
and pressure are required for this reaction known as ___________________________ reaction.

ANS: sabatier senderen's

Question 7

Alkanes with six or more carbon atoms when heated strongly under pressure in the presence of a
catalyst gives _________________________________.

ANS: aromatic hydrocarbon

Question 8

The number of hybrid orbitals generated is determined by __________ combined.

ANS: atomic orbitals

Question 9

Alkanes undergo mainly ______________________ reactions.

ANS: substitution