Sec: XII-PASS_IIT_IR Date:18-09-2023

Time: 3 Hrs. CTA– 02 Max.Marks:180

JEE-ADVANCE 2022 P-2 MODEL
KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9
2 2 2 6 11 8 4 1 A,B,D
10 11 12 13 14 15 16 17 18
A,B A,B A,C A,B,C,D A,B,D C D B A

CHEMISTRY
19 20 21 22 23 24 25 26 27
30 9 6 1 56 1 4 5 2,3,4
28 29 30 31 32 33 34 35 36
1,3 1,4 1 3 1,4 3 3 3 4

MATHEMATICS
37 38 39 40 41 42 43 44 45
7 100 5 6 2 2 7 8 BC
46 47 48 49 50 51 52 53 54
AD BCD BC AC AB D B D A

Solutions
1.
F.B.D of 2 kg block

When 2 kg block just leaves the contact

N=0
20 1
Kx + 0 = 20  x =  m
40 2
Applying WET for the whole system

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
9 Wsf = k
w
1 1  1  2  1
 50    40     0   5 [V  0]  V = 2 2 m/s
2

2 2  
2  2
2.

FB = buoyant force Fs = surface tension force

mg + 4a
   4a     d  g  a 2 h = mg.  h =  2.3 cm
dga 2
3.

1 2
Time taken to reach the ground is given by h = gt . ...(1)
2
Since horizontal displacement in time t is zero …….. (2)
 t = 2v/f
2gv 2
h=
f2
4.

String will taut when A waves a distance of (.7 - .25) m

At that Pt VA  2gh and Now B starts on using with same velocity as A.
Let us suppose it is u.
 Tdt = mB u  0 ... 1
  Tdt = m A  u- VA  ...  2 
mA VA 6
From (1) and (2) u = 
mA +mB 5

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
6
  Tdt = 3 5 = 3.6 N-s
5.
 GM 
 2  ms  ms  R
2

 R 
 2 R 3 4 2 R 3
M=  2
G TG
M = 6  10 kg
41

M = nms
 6 10   n  2 10 
41 30
| n = 3 1011
So
x = 11
6.

Velocity at lowest point

mg 1  cos 600   mv2 (from energy conservation)
1
2
v= g
For completing the loop.
v = 5g   r   g
4
r= m
5
7.
dy 1
aA  
dt 2 2
a B  8a A by constrained relation
a B  4m/s2
8.
Motion of rod is purely translational net torque about C.M of the rod should be equal to zero
 
F1  F2   a 
2 2 
F1  a 
 1  
F2  /2
For translational motion of rod
F2  F1  ma`
F1  ma` 
1  
F2  F2 

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
ma` 2aF2
2a /     1m 
F2 ma`
9.

For equilibrium
d A vg  d B vg  d F vg+d F vg
dA  dB
 dF   Option (D) is correct
2
To keep the sting tight
d B > d F and d A < d F

10.

For the striker 02   2   2  0.2 10  s  s 1 m

2

2 2
 1   1  1 1
From A to B SAB       4  2m
2 2 2 2
1
Similarly SAB  m
2
 1 1 
 The striker stops at the point C having coordinates  , .
2 2 2
11.
V0  3ωRiˆ

 ωR  ωR
VP  3ωR  cos 60 0  ˆi+ sin 60jˆ
 2  2

11ωR ˆ 3ωR ˆ
 i+ i
4 4

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
12.

f = 0, If sin = cos    45

f towards Q, sin> cos    45

f towards P, sin< cos    45

13.
(A) Absolute velocity of ball = 40 m/s (upwards)

 40 
2

hmax = hi = ff =10 +
2 10
h = 90 m

 30 
2

(B) Maximum height from lift = = 45 m

2  10
(C) The ball unless meet the elevator again when displacement of ball = displacement of lift
40 t - 1/2 10  t 2  10  t  t = 6s.
(D) with respect to elevator Vball = 30 m/s downward Vball with respect to ground = 30 – 10 = 20m/s

14.
dv dk 
mv   t v dv = t dt
dt dt m
v2  t 2
 v  t
2 m 2
dv
 constant  F = constant
dt
dx
 t  x  t2
dt
15. Conceptual

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
16.
QP = 2 - 5 = - 3 rad/s
QP = 3 - 5 = - 2 rad/s
 /2 1
Time when Q particle reaches at P = t1   sec.
3 6
5 / 2 5
t2   sec.
3 6
 1
Time when R particle reaches at P = t1   sec.
2 2
5 3
t2   sec.
2 2
3
Common time to reaches at P is sec.
2
17.

GM
 P  v0 
R

v1 R2 2
 
v2 R1 1

(Q) L = mvR
L1 m1 v1 R1 2 2 1
      1
L2 m2 v2 R 2 1 1 1

GMm
(R)KE =
R
K1 m1 R 2 2 1
    8
K 2 m 2 R1 1 1
3/2
T R  1
 S 1   1  
T2  R 2  8

18.

As we know
v2
ac =  centripetal acceleration 
R

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
2 2
v v
 R=
From figure; g sin  = R gsinθ

v0 v 2  v0 
 g.   since sin θi =  R  v3
v R  v
19.

20. As in case of n+2 we can see that ΔiH, is very less means e− is removed from 1st group have low Δi
H1 & then from 2nd ΔiH2 is high because e− is removed from next lower shell.
So, n + 2 = 11 = (Na) = 1s2 2s2 2p6 3s1
n + 3 = 12 = Mg = 1s2 2s2 2p6 3s2
n=9=F
(n + 1) = 10 = Ne
Therefore, n = 9.
21. Deflected by the charged comb if it is a polar molecule.
∴ Polar: HF, H2O,NH3,H2O2,CHCl3,C6H5Cl
(attracted)
Non polar. : O2,CCl4,C6H6
Therefore, when a charged comb is brought near their flowing stream, six compounds will show
deflection.
22.
nT  1  x 
PV  n  R  T
160 100  1  x   8.0 1000
16
 1 x
8
x 1
23. Concentration of H2O2 is expressed in terms of volume strength, i.e. volume of O2 liberated by H2O2
at NTP. Molarity is connected to volume strength as

So, for 5M H 2O2

x  5 11.2  56

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
24. According to de-Broglie's hypothes,
nh
mvr 
2π
h n2
 λ, r  a0
mv z
n λ
 
z 2πa0
n 2πa0
  1
z 2πa0
25. H2C2O4 + 2NaOH → Na2C2O4 + 2H2O
meq of H2C2O4 = meq of NaOH
50 × 0.5 × 2 = 25 × NNaOH × 1
∴ MNaOH = NNaOH = 2 M;
Since n-factor is 1
Now, 1000 ml solution = 2 × 40 gram NaOH
∴ 50 ml solution = 4 gram NaOH.
26. The outermost shell and one shell prior to it in d subshell, has total 5 electron so it will be placed in
fifth group in transition element or 'd' block of periodic table.
27.
2X  Y  k
P
t 0 2 1 0
t  50 2 0.5 1
2 X  Y  P
t 0 2 1 0
t  50 2  2  0.5 1  0.5

28.

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
⇒n=4
n = 4, l = 2, m = 0 belongs to 4d orbital no. of angular nodes in an orbital = value of l no. of radial
node in 4d = 1 Since it is a unielectronic species, there will be no shielding and the nuclear charge
felt will be 2e.
29.

0.693
30. (A) t1/ 2 
K
(B) Rate ∝ (conc. of reactant)
2.303 R
(C) K  log 0
t R
R R
Kt  log 0  Kt  log 0  mn  y
R R
 kt
(D) C  C0e  a 0  x  a 0e kt
x Q
a 0  a 0e kt  x  1  e Kt  
a P0

31. If AB4 molecule is a polar molecule, a possible geometry of AB4 is Square pyramidal.

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
32. The vapour pressure of A,B, and C at different times are as follows:

33. In general, the property (magnitudes only) that shows an opposite trend in comparison to other
properties across a period is atomic radius. Explanation: The periodic table shows that while
electronegativity, electron gain enthalpy, and ionisation enthalpy rise over time, atomic radius
decreases.
34.

35.

Bond order of Li+2 = Bond order of Li−2

Lesser the no. of antibonding e− (na) greater the stability
(na)Li2+ < (na)Li2− ⇒ Li2+ is stable and Li2− is unstable.

36. Hence, For the emission line of atomic hydrogen from ni=8 to nf- the plot of wavenumber (v) against
(1/n2) will be Linear with slope

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
37. (7)
Given, n > 3  Integer
1 1 1
and  
  2   3 
sin   sin   sin  
n  n   n 
1 1 1
  
 3 2
sin sin sin
n n n
3 
sin  sin
 n n  1
 3 2
sin .sin sin
n n n
 3
sin .sin
 2   n n
 2 cos   .sin 
 n  n 2
sin
n
2 2 3
 2sin .cos  sin
n n n
4 3 4 3
 sin  sin   
n n n n
7
 n 7
n
38. (100)
Let s = (10)9 + 2(11)1 (10)8 + 3 (11)2(10)7 +......................+10(11)9
 11
s = (11)1 (10)8 + 2(11)2 (10)7 + .................+9(11)9 + (11)10
10
substract
 11 
1 –  s = (10) + (11) (10) + (11) (10) + ................+(11) – (11)
9 1 8 2 7 9 10
 10 
  11 10 
9 
10 1 –   
1   10  
 s= – (11)10
10 11
1–
10
1
 s =10 9
 10 –1110  10
10

 –(11)10
10 1010 –1
1
 s = –1010 + 1110 – 1110
10

s = 1011

given 1011 = k(10)9

k = 100

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
39. (5)
 3x  7 y  11 sec   5 x  3 y  11 cos ec  0  B  1, 2 
PA  PB  AB  62  22  2 10
40. (6)
y  0  6 x 2  24 x    0   0    24
By condition of pair of lines   3 / 2

41. (2)
From figure

RS RS
tan    ........  i 
PR 2r
  PQ PQ
tan       ........  ii 
2  PR 2r
Multiplying Eqs. (i) and (ii),
RS .PQ
tan  cot  
 2r 
2

 2r   RS  PQ 
42. (2)
The given point (-a, 2a) lies on the directrix x= –a of the parabola y2 = 4ax.
Thus, the tangents are at right angle.
43. (7)
p2
Sub x = 4 in first then p = -7 and q 
4
4 4 p2
q  7
7 7 4
x y
44. Asymptotes are 
5 3
x 2 y2
Equation of hyperbola   1;
25 9
b2
LLR  2
a
L 18
  L-2M=18-10  8
M 5

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
45. (B, C)

1 1
x =  cos 2n  = = ,
n 0 1  cos  sin 2 
2


1 1
y =  sin 2n  = =
n0 1  sin  cos 2 
2


1
z =  cos 2n  sin2n =
n 0 1  cos  sin 2 
2

1 xy
z=  z=  xyz – z = xy
 1 1 xy  1
1  x . y 
 
 xyz = xy + z
Since xy = x + y  xyz = x + y + z
46. (AD)
x1 y1 1
x2 y2 1  0
x3 y3 1
47. (B, C, D)
(3x  4 y  5)( x  2 y  3)  0
3 1 3
m1  , m2    m1m2 
4 2 8
P  (1, 2)
1 3
 
2
tan   2 4 
3 11
1
8
2
 sin  
5 5
48. (B, C)
1
Any tangent to y2 = 4x is o the form y  mx  ,  a  1 and this touches the circle
m
1
m  3  0
 x  3  y 2  9. m 3
2
if
m2  1

[Centre of the circle is (3, 0) and radius is 3].

3m2  1
  3 m2  1  3m2  1  3m m2  1
m
 9m 4  1  6m 2  9m 2  m 2  1  9m4  1  6m2  9m4  9m2

1
 3m2  1  m  
3

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
49. (A, C)
4 15 2a  5 4
5 21 3a  8 5

x2 x 1
 
84  75 45a  120  42a  105 10a  25  12a  32

9 3a  15
x , x=
3a  15 2a  7

3 3a  15
 ; 6a-21=3  5  a 
2

a  5 2a  7

6a  21  3  25  a 2  10a  

2a  7  a 2  10a  25; a 2  12a  32  0

 a  4  a  8   0; a=4, 8
50. (A, B)
3  cos 4 x  sin 4 x   2  cos6 x  sin 6 x   1
  y  1  9  y  2 or -4
2

51. (D)
|X| + |Y| = 2
 |X|, |Y|  [0, 2]

 x 2 
Also sin   1
 3 
x 2 
  (4n  1)
3 2
3
 x 2  (4n  1)
2
3
| x | [0, 2] , then only possible value of x2 is
2
3 3
 | x | ,| y | 2 
2 2
Hence, total number of ordered pairs is 4.
52. (B)
225a2 + 9b2 + 25c2 – 75ac – 45ab – 15bc = 0
(15a)2 + (3b)2 + (5c)2 – (15a)(3b) – (3b)(5c) – (15a) (5c) = 0
1
[(15a – 3b)2 + (3b – 5c)2 + (5c – 15a)2] = 0
2
15a = 3b , 3b = 5c , 5c = 15a

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 XII-STU-IC_IIT_REG_CTA–02_2022-P2- EX. DT: 18-09-2023
5a = b , 3b = 5c , c = 3a
a b c
  
1 5 3
a = , b = 5, c = 3
a, c, b are in AP
b, c, a are in AP
a = , b = 5, c = 3
a, c, b are in AP
b, c, a are in AP

53. (D)
Let mid-point of
AB   x1 , y1   M
A   2x1 , 0  , B  0, 2y1 

x y
Equation of line AB is   1,
2x1 2y1
And it passes through (6, 4)
6 4 3 2
  1   1
2x1 2y1 x1 y1
Locus of M is 3x-1+2y-1=1
54. (A)
x 2 y3
The given ellipse is  1
4 3

 a  2, b= 3  3  4 1  e2   e 
1
2
So that ae  1 Hence the eccentricity e1 , of the hyperbola is given by

1  e1 sin   e1  cos ec

 b2  sin 2   cos ec2  1  cos 2 

x2 y2
Hence the Hyperbola is   1 or
sin 2  cos2 
x 2 cos ec2  y2 sec2   1

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