Alcohols, Phenols and Ethers Camhrni pc Date

mechao'Sm f hyolation of alkenes

LExplalo the
Lalcohola.
hyclratton f alltenestavolues
mechaniSmn tha
The
ollawtog thae&tapai
allkene to Germ Carhocatlon
Step1: Prstonatton
electrpbtl attack g Heo

C
H
Hyclren um Carboaton
Atlene

skep-& Alucleophilie attacte oatx on Carbootoo.

H

Carbooattoo ONOnforo fon

Step-9
Deprotonatlon bo form an aleobol
H H

O2Conom forn Aleahol

albat is hycroboraton - iclottorn haaslton? Gttue an e

Aleoes Sheact cotth llborene to gve trolagl boane
alcool. shs Jecetion tS hplhohoraton- erlatoe
CHCH-CHa
Propene Dhorane BHa
 Comiin ?g

CHg-cH=CHa
c-ce-cBH ott

3cHR -CHCHH
Boric akd Propan--oL

B. Ezplatn tha mechanlSm f cahycdration f ethanol to etheoe.

Step-1 Formatton prokorated alcaßol
fast :
H-¢b
H

thant Protoratec alcobo!

Step-T
Formatton Cerbo atton t--t

4-

CarboCation..
-step-I
Elrnioatten of probon

Ethene
Carbocatton

4-arite tie euatons inuolueo entte preparatioOg Phnsl

Pumene?
CH3
Hae--0-0-H
Hgc
Acetone
tumene Phnel
Cumere hydroperoride
 Camnin|Page
Date

Ecplain koibes eactioo.

Phenol on eatoaent wt Nlaot gived Soclr

5
eseh on healtng cott Co, at 42kancl G- af
Soalium Salicylott eohich on acfor: catton Bodlmphen
Phono) ocharephenastDHT
101
SodorÓphenalo 2-hytroybenoto
(salrcylbc acia)
B.Eplotn RefmerTemann reaatfon
onbeatng with ehloroform fotho presehce
15
Phono)onhegu lotlooecl bing grolysis
Socdion hydrociolo
qives o-hyclroxy benzalalebelo Csaliclolld hyde)
Refmeseann Reache
Neot H
20

Pheno) Tnternacaco
CHO

25
Saltoylald.
OH Na Cmetae)X
X +CoH Br Casilttor 30eactton Y, wat are xand y.
CHO Ala CSodtom etfoxllo
30
Het etsoxy ettene )
8-H-Cto O) RNgx, etrer

Yhlbat are x. andY

As! X R CH OH

q.Among al cabola and phenols whchonelnore

la ldie
5
and chy ?
Phenols are more acice beCaube phenoíke lonfs
staslfs ecl by esonnce but alkoelle os arenot

Co) O-nitrephenol anc p-nltro phenol can be eparatrd

by steamostillatron
lCbTore is large ditterence inîn bofling peint
al coto ols ond ethers.
Cas
Ans O-nitrophonol s Bteam Volabile but p-nitrophenol 1s not
C82Noteculeg alobo! are
aBBociated through H- bondig
J-albat fs tho organtc campoond formed inthe folleroing'
So H
20
A
C27) Ht
OH
Na, Cr, B
H2Soy

330

Phenol Br
P-Brpmo anîle
Benoquin one
 lcamlin Page
Date

12 Complete the followlng

O+Zo haat,
2Pono PhoneL
scCHcH= CH-CHo

10
+3HBr

Y
Re, bTAbromopheno)

151

(i3)Complete te follocolng 2
5 73}

20

AnsL)RCHo
aldehycde
E) CH
Arranqe the
he gollouaing io the iocrasing order g aaicds
and Ojusbify the same

As
number
Lolecrenses.
 Camtiraea

/5- albtstke eg ect g

C) electronwthclracolnq grocyp on aciety Phenels.
ch) Electron donatting roy RCidity zalcabol s
| ( ) Bot ling polnt ofalcobol s Prcrea sing DUmber
Carbon atom
Ans increases

(6Ca which class lcotolA do not heaolily form torbidity

coith uas Reayet
(C Name tho organte procluat formed when an)sole is
reacted o HT
Co rite tto TUPA C name g ma)or praluet in F edel
Crafts acylaon aniSole
As | a naralco

(e -metsoxy cCetephonona ors-methoxy Denyl

)Ia Eplain alilleamSoe etfor Syothess cofth eame
AHyl hallla_ beatog coit alloride fo alcoboliC
medium gives R~o-R alax
R-oNa
Su
CHgO-CH AaT
SN
How does QnSole Jroact ewtts bromine in efanstc
GLtve equnt'oo.
Anisot e neact& ewtÔ bromnfoe in ethanotCald giUe&
pbromO and O b r o o aoisAe
OCHs OCHs
&r
Ethanotcacd
AnlSoe
 Camin Page
Date

Howdoes phono Jroaeteote

Pheno}
2,,b-Tioirophene)
picre acid)
Drepare etfanol by Lstg tÊo Gignand R
Hoo o you
A dditton Com pound
formaldahg ae