UALITATIVE ANALYSIS

• TeSr FoR ANIDNS :

ANION

r
Shecifit Grou

Si
Sat + Dil. H,504 Salt t Cone. H,Soy # In sheciie grou we
confirmat
perforwm diredh
Pungau s melling got CHce)
eRkervenSLence fest for-few anib,

ey
qire wkie fumes
0 hay be NHy oH SO,-2
comay be with a rod dipped fu Test for
nd Salt sel"++ Ball, saln
Gas Smeling lPke Reddish brown vabours o - ahite ppt s Basoy
formed which ib insolube
s may be oMC.
Cone. Hce aud
in
Pa
Deep velet vabons o a gos HNG, -
Sou confirmod

90, I may be Test for Ca 0,2

So° may be soy
Brown vaboun erolved
Saltse + Cat,
ntensifiswkite yetalline ppt
ag

Reddish Bown (ND, ga) wkich

formed
on adding paper pallets of lal,a, is
and heatg No,
Gas is confiued.
NO may be Ng mgy be
|Tat
Test for Po
ur

Vinega IPke
Salt sel"+ CoMc. HNg
then ce, + tmmonium
An

evolved Bu, I
may be and hat
CHy C0
and No, OHe abseut 5"
mOVe to
A canasy yelpw pt
Now we will
PO s Confirmed
No vabar
is evolved theu wiove
to Cone s0u grau
Hg
 Confhimabry Test fer Auionic Radials
|ON TEST O BSER AT ION

Satt sel"+ Mg 804

Se/4 wite ppt

r
Si
So,2
t
ahite ppe. o Ba

ey
Salt sel"
+ Bacl, Se"

to precipitat formad above ado

dal. Ha evoluhiu g so,
nd
S0,+ Bacl,
Ba s0, t+2C0

Baso, taHCe bacl, +

sa, + H,o
Pa

Purple coloMY is
Salt sol"+ Sodiam rnffoprusside solutioy
obtjned.
t Na,[F (CN), NoJ NOS
Na, [Fe (es
ag

Salt sa" Load acetath so" (Pblgto), ) Black ppt oB

+CH, CoO N Pbs
Na,s + Pb (CHg
Coo),
Abs
ur

Bloud ed
NO, Colourahion
An

HSCN+ yo
HND,+ NHS-NH, N+
Pe HsCN fe sc +H°
 CH, coo B lopd Red Colour

r
Se
wkite ppt

Si
Solube Tn NHy DH

ey
Ligbt yellod ppt
nd
Salt ser" + ty NDg
pertiay..
NHy0H
Soluble i
Pa
Pale yello Ppt
H
I Salt so"+
usoluble
ulich a
Ag No, NHy H Se
I+ iu
ag

at
RPua Teat :-
Salt se+ esoya
teut tube unceua
along the wala of two
ur

taND+4,0
NO, +fesly
t Hy sly
3e, (Sbuy
e(Brouin
So, NO
An

A soy
t NO
ring)

so!* + Di pheuyl aume Blue tolour

Salt
(GHg),NH ), NN B).
CoJ + + Hyo
 r
Test for CatHon

Si
in dPl. Hce plaed near
Yes A Tad dipped
Gatt tNaoH Smell af AmMonina white
'Dense
mouth af Test tube
Gr-Zeno fumes & NHyc confirms NHy.

ey
NO
+ Ness lers Regqent
Salt + Na DH Cke Hg Ty)N
A brown ppt Confira NHy lon

nd
Groub- I Saltset^+ d' Hce

Dissolve PPt. in Boiling water and

Pa
Yes
wlite ppt e PLe. drvide f+ Pn too pahls.
To
fist part add kI sel"- Yelow
% PbI Confirms Pb2
Ppt
- yelow
ag
No To Becond part add K, Cr Oy
con
Pht of Pbroy firL Pb2
Saltsel"+ H,s tdil. HL
Groub -I
ur

HNO conc
Dssolve baek ppb. fn
and divide i7atotuwo park.
Deep blue
NHyoH-
To
fist part add
An

ColouY
Ye
Blak ppt Tosecond part add cH,CoOH
+ K4LFe
ll;1
Chocolat Brown colour -ut contrm
 r
NO
Groub- IUL
Dßssolve
te reddiehky broon ppt.seluhion
fn

Si
del. He and add [Fe GN]
Saltset t di]. HCet NHy0HexLes) t NHy CQ
- russian blue colour abber which
to Pt
Yes Confira presenue
o Pe*t3

ey
Reddish brouon ppt.

nd
Gelatintous uhte pt ppt iuto dPl. HL aud add few
Dissolve

drops blue litmus se!" to

P
then
ex ess
tur ther add NHy 0H se! y
Groub \NO

Pa
colourlesc med.
Salt sel^+ dil. HL +
NH,
lt NH, oHeeyt Hys
- Blue ppt. Susbended M
Confirus presne ef Ae3.
Blockoot Ly ppt in Aqua veaia and dvide fF fnto&arfs
Dssolve ppt
Dissolve in quaY Serond partadd dimehyl
ag
To first pdrt add amyloho To Setond part add
and NHySCN –Blue louy 2yoxime and NHy oH.,!
Buty Lolured pp. ppt Lonfirm Ni2
my
in Amyl ohelål Contir Cotpink
es Dissole PPt. fu dil. He and add NaoH and B8,
ur

watr to t – Greytsh Brown ppt Confirmd

|Drtyuokte ppt Mut2 io

Mn
An

wkle ppt in dl. HCe and add potasium

Disso lve
ferrocyanide doluhion to - Bluish whte pt
Con firu
ft
No
Ant ion.
 Note:
Test for Ba* S, t2 To first pant add Ka Oy
C

r
|No be doMe ppt ef Bacroy Confirms

Si
Catmwt Yello
Groub-V and
Ba+2
0H + NHl fu
Pu corct sequeule
balk se" + dl. He+NH,
Salt
+(NHu),cos

ey
To second part add Qwmonium
Dissolve ppt înto Suls hat wlite ppt of
wle ppt Acette Actd and soy Confir mu S +2

nd
Sr
dfufde i futo
No
Groub-VI three pans

Pa
To third part add Qm MOniuM
Sat +
dil. HO + NHycl t Oxalat a" yhite ppt e
NHy0r + NH),co, t La t2
bisodium Hydrngeu phoxphat. (alg Dy Confirmd
ag
t NHyot (exces) tond.

Flame Tet
ur

wite ppt on tirwa +2 ion.

Mg* Bat2 pple gnee.
Crimsou Rad
And confir Mabony.: Syt2
An

Saltsel"+dil. Hcl NHycl++ NHyoH +(NH40 tMagnesoy Bhek Red

late
Rageut Nabt t +
Sky blue/bluichgreu ppt
+
Mgt2 CDn rm.
 CHEMICAL fORMULA Of SoME IMBRTANT REAGENTS

1. Nesslers Negyu
Na, CFe (en), No]
2. Sodium Nio pru sside

r
- kyCPe Cn)]

Si
3.
Pota ssiuwm ferosanide
ferrosyaude
Tesorciuel
- p-ubo benzcae azo
4. He soM
agnesou Keageut

ey
OH
N=N
Ho

5. Diphayl aine
nd
Pa
6
Tio urea
- (NH), Mo O4

1. Awmoniua Moly bdate

ag

CH,- C =N-0H

CH-C NoH
ur

-OH
CH,-CH,- CH-CH,
An

alteluot
9.
Ayl CHs

I6. Aansoniuwt thiouynat NH,SCN

 12. Pheneph thaleiu HO. OH

r
Si
13 Seki Reagat NH SO, H

ey
nd so, H
Pa

H
NHS,
ag
ur
An