Supporting Information

Solvent- and Catalyst-Free Aza-Michael Addition of

Imidazoles and Related Heterocycles
Katharina Kodolitsch, Florian Gobec, and Christian Slugovc*
Content

1
H and 13C{1H}NMR spectra of compounds 1A-D page 2-5
1
H and 13C{1H}NMR spectra of compounds 2A-D page 6-9
1
H and 13C{1H}NMR spectra of compounds 3B-6B page 10-13
1
H and 13C{1H}NMR spectrum of compounds 2E page 14
NMR spectra recorded during the unstirred preparation
of 2B showing the conversion over time page 15-16

1
Fig. S1. 1H- and 13C{1H}-NMR spectra of 1A

2
Fig. S2. 1H- and 13C{1H}-NMR spectra of 1B

3
Fig. S3. 1H- and 13C{1H}-NMR spectra of 1C

4
Fig. S4. 1H- and 13C{1H}-NMR spectra of 1D
5
Fig. S5. 1H- and 13C{1H}-NMR spectra of 2A

6
Fig. S6. 1H- and 13C{1H}-NMR spectra of 2B

7
Fig. S7. 1H- and 13C{1H}-NMR spectra of 2C

8
Fig. S8. 1H- and 13C{1H}-NMR spectra of 2D

9
Fig. S9. 1H- and 13C{1H}-NMR spectra of 3B

10
Fig. S10. 1H- and 13C{1H}-NMR spectra of 4B

11
Fig. S11. 1H- and 13C{1H}-NMR spectra of 5B

12
Fig. S12. 1H- and 13C{1H}-NMR spectra of 6B

13
Fig. S13. 1H- and 13C{1H}-NMR spectra of 2E

14
Fig. S14. Monitoring the reaction of 2 and B performed without stirring at 80°C. Conversions at

given time noted next to the corresponding 1H-NMR spectrum. Values retrieved as can be seen

in Fig. S15.

15
Fig. S15. Integrated versions of the spectrum 1 (after 6 min reaction time) and 5 (after 3 h 36

min) from Fig. S14.

16