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Bom 2675 6950 MidtermRevisionWorksheet2withMS
Bom 2675 6950 MidtermRevisionWorksheet2withMS
Q1.
Which one of the displayed formulae below does not represent an isomer of heptane?
(ii) Complete the following diagram to show the structural formula of heptene (C 7H14) by inserting lines to
(d) When heptene is added to bromine water, and the mixture is shaken, a reaction occurs.
State the type of reaction and give the colour of the bromine water before and after the reaction with heptene.
(3)
Type of reaction
...........................................................................................................................................................................
Colour before
...............................................................................................................................................................................
Colour after
................................................................................................................................................................................
.
(e) Explain, in terms of the bonds present, why heptane is described as saturated and heptene as unsaturated.
(2)
..............................................................................................................................................
..............................................................................................................................................
..............................................................................................................................................
..............................................................................................................................................
(Total for Question = 11 marks)
Page 2 of 72
Q2.
The tables give the names and molecular formulae of the first three members of each series.
(a) One feature of a homologous series is that each member has the same general formula.
(i) What is the general formula for the homologous series of alkanes?
(1)
A CnHn
B CnH2n–2
C CnH2n
D CnH2n+2
(ii) What is the general formula for the homologous series of cycloalkanes?
Use the information from the cycloalkane table to help you answer the question.
(1)
A CnHn
B CnH2n–2
C CnH2n
D CnH2n+2
Page 3 of 72
(iii) State two other features of a homologous series of compounds.
(2)
1 ..........................................................................................................................................
.............................................................................................................................................
2 ..........................................................................................................................................
.............................................................................................................................................
One product of the reaction between cyclopropane and bromine is hydrogen bromide, HBr.
Page 4 of 72
(ii) Complete the displayed formula for the other product of this reaction.
(1)
Page 5 of 72
Q3.
A teacher explained the different types of formula used in organic chemistry, using ethene as an example.
(a) Use this example to help you write the formulae described below.
Page 6 of 72
(b) All the compounds in part (a) belong to the same homologous series and have the same general formula.
(iii) State two characteristics of the compounds in a homologous series, other than having the same general
formula.
(2)
1
..............................................................................................................................................
..............................................................................................................................................
2
..............................................................................................................................................
..............................................................................................................................................
(c) All the compounds in part (a) are hydrocarbons. They can undergo complete combustion when burned in
(i) Write a chemical equation for the complete combustion of propane (C3H8).
(2)
..............................................................................................................................................
(ii) Identify one solid product and one gaseous product that could form during the incomplete combustion of
propane.
(2)
Solid product
..............................................................................................................................................
Gaseous product
..............................................................................................................................................
Page 7 of 72
Draw a displayed formula for each of the two isomers of pentane.
(2)
(e) When methane reacts with bromine, one of the products is hydrogen bromide.
Page 8 of 72
Q4.
The table gives some data about the first six members of a homologous series of compounds called the
alkanes.
(b) What does the data show about the relationship between boiling point and relative formula mass?
(1)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
Explain how the formulae of these compounds show that they are in different series.
(1)
.............................................................................................................................................
.............................................................................................................................................
Page 9 of 72
(d) (i) In the table, draw displayed formulae for the two alkanes with the molecular formula C 4H10
(2)
(ii) What is the name given to compounds that have the same molecular formula but different displayed
formulae?
(1)
.............................................................................................................................................
(e) The reaction between ethane and bromine (Br2) is similar to the reaction between methane and bromine.
(i) Write a chemical equation for the reaction between ethane and bromine.
(2)
.............................................................................................................................................
(ii) What is the name given to the type of reaction that occurs when ethane reacts with bromine?
(1)
.............................................................................................................................................
.............................................................................................................................................
Page 10 of 72
Q5.
(c) Compounds A, B and C belong to the same homologous series. One characteristic of the compounds in a
Page 11 of 72
(d) Compound C has several isomers.
(i) Complete the sentence to show the colour change when compound A is bubbled through bromine water.
(1)
Bromine water changes from orange to .............................................................. .
(ii) Complete the chemical equation for the reaction between compound A and bromine water.
(1)
C2H4 + Br2 → ...........................................
(Total for Question = 14 marks)
Page 12 of 72
Q6.
(a) Describe what is done to the crude oil before it enters the fractionating column.
(2)
.............................................................................................................................................
.............................................................................................................................................
(b) State how the temperature changes from the top of the column to the bottom.
(1)
.............................................................................................................................................
.............................................................................................................................................
bitumen
.............................................................................................................................................
Page 13 of 72
(d) Name the fraction that contains the largest molecules.
(1)
.............................................................................................................................................
(e) State the physical property that allows the different fractions to be collected at different heights in the
column.
(1)
.............................................................................................................................................
.............................................................................................................................................
Page 14 of 72
bitumen
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(iii) In a possible reaction for the cracking of eicosane, the products are three molecules of C 4H8 and one
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
Page 15 of 72
(iii) Describe a chemical test used to distinguish between unsaturated and saturated hydrocarbons.
(3)
test
.............................................................................................................................................
results
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
Page 16 of 72
Q8.
(b) Give a chemical test to show that the gas collected is unsaturated.
(2)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
temperature
.............................................................................................................................................
Page 17 of 72
Q9.
The diagram shows a typical fractionating column used to separate crude oil into fractions.
fraction F .................................................................................................................................
Page 18 of 72
(c) Describe how the boiling point, colour and viscosity of the fuel oil fraction differ from those of the gasoline
fraction.
(3)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(d) Some fuel oil undergoes catalytic cracking. This involves the conversion of long-chain alkanes into alkenes
and short-chain alkanes.
(i) A temperature of about 650°C is used in this process.
(ii) The alkane tridecane can be cracked to produce octane and two different alkenes.
(e) When hydrocarbons undergo incomplete combustion, a poisonous gas can form.
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(iii) Explain why this gas is poisonous.
(1)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(f) Another problem with using hydrocarbon fuels is the formation of substances that cause an environmental
problem. This sequence of equations shows how one of these substances forms.
S + O2 → SO2
2SO2 + O2 → 2SO3
SO3 ........................................................................................................................................
H2SO4 ........................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
Page 20 of 72
Q10.
(b) Complete the table by giving the correct fraction, A, B, C, D, E or F, for each description.
You may use each letter once, more than once or not at all.
(3)
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(c) State the relationship between the number of carbon atoms per molecule and the boiling point of the
fraction.
(1)
.............................................................................................................................................
.............................................................................................................................................
(a) The letter of the compound in the table that is not shown as a displayed formula is ..............................
(1)
(b) (i) State what is meant by the term hydrocarbon, and give the letter of one compound in the table that is not
a hydrocarbon.
(3)
Hydrocarbon
................................................................................................................................................................................
..............................................................................................................................................
Letter
................................................................................................................................................................................
...........
Page 22 of 72
(ii) State what is meant by the term unsaturated, and give the letter of one compound in the table that is
unsaturated.
(2)
Unsaturated
................................................................................................................................................................................
.
..............................................................................................................................................
Letter
................................................................................................................................................................................
...........
(iii) State what is meant by the term isomers, and give the letters of two compounds in the table that are
................................................................................................................................................................................
......................................................................................................................................................
.........................................................................................
(c) Some of the compounds in the table are members of the same homologous series.
(i) One feature of a homologous series is that adjacent members have formulae that differ by CH2
.....................................................................................................................................................................
2..............................................................................................................................................................................
.....................................................................................................................................................................
Page 23 of 72
(ii) Give the letters of two adjacent members of the same homologous series shown in the table.
(1)
Letters ......................................................................................... and
.........................................................................................
It can be made from a compound in the table by a reaction that does not need UV light.
(ii) Compound H reacts with bromine to form one of the compounds in the table.
Page 24 of 72
Q12.
(c) Which letter represents the first member of the homologous series of alkanes?
(1)
.............................................................................................................................................
Page 25 of 72
(d) Which letters represent compounds that have the empirical formula CH 2?
(2)
.............................................................................................................................................
(f) One of the compounds in the table reacts with bromine to form G, a compound with the composition by
Page 26 of 72
Q13.
You may use each letter once, more than once or not at all.
(ii) Which other hydrocarbon is produced, together with D, when pentane (C 5H12) is cracked?
(1)
.............................................................................................................................................
(iii) Which hydrocarbon can undergo an addition reaction with hydrogen to form B?
(1)
.............................................................................................................................................
Page 27 of 72
(b) Give the molecular formula and the empirical formula of E.
(2)
molecular formula
.............................................................................................................................................
empirical formula
.............................................................................................................................................
(i) Give the name and the general formula of this homologous series.
(2)
name
.............................................................................................................................................
general formula
.............................................................................................................................................
Page 28 of 72
(d) Two reactions that can occur when hydrocarbon A is burned in air are represented by these equations.
Explain why a different product is formed in reaction 2 and why this product is dangerous.
(3)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
Page 29 of 72
Q14.
(b) Describe a test that will distinguish between compounds Q and T, and state the observation made with
compound T.
(2)
Test
................................................................................................................................................................................
............................................................................................................................................................
Page 30 of 72
Observation with compound
T....................................................................................................................................................
..............................................................................................................................................
(c) Draw the displayed formula of an alkene containing four carbon atoms.
(1)
All the alkanes in this homologous series have the same general formula.
Page 31 of 72
Explain what isomers are.
(2)
..............................................................................................................................................
..............................................................................................................................................
..............................................................................................................................................
..............................................................................................................................................
Page 32 of 72
Q15.
Page 33 of 72
(d) Which two hydrocarbons have the empirical formula CH 2?
(1)
A R and V
B Q and S
C R and S
D T and U
(e) The substitution reaction between hydrocarbon T and bromine is similar to the reaction between methane
and bromine.
(i) State a condition, other than temperature, that is required for this reaction to take place.
(1)
.............................................................................................................................................
.............................................................................................................................................
(ii) Suggest a displayed formula for a possible organic product of the reaction between hydrocarbon T and
bromine.
(1)
Page 34 of 72
Q16.
(c) Which of the hydrocarbons belong to the same homologous series of compounds?
(1)
.............................................................................................................................................
Page 35 of 72
(e) Z is an unsaturated hydrocarbon.
.............................................................................................................................................
hydrocarbon
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(f) (i) The substitution reaction between W and bromine is similar to the reaction between methane and
bromine.
Suggest the displayed formula for a possible product of the reaction between W and bromine.
(1)
.............................................................................................................................................
(ii) State the condition required for this reaction to take place.
(1)
.............................................................................................................................................
Page 36 of 72
Q17.
(b) Which two letters represent compounds that are members of the same homologous series?
(1)
............................................................ and ............................................................
(c) Which letter represents a compound that is formed from methane by a substitution reaction?
(1)
.............................................................................................................................................
Page 37 of 72
(ii) State why the carbon monoxide formed from compound W is poisonous.
(1)
.............................................................................................................................................
.............................................................................................................................................
step 2 nitrogen oxides react with water in the atmosphere to form an acid
(i) Name the two gases that react to form nitrogen oxides.
(1)
............................................................ and ............................................................
Page 38 of 72
(b) This apparatus can be used to separate the substances present in a sample of crude oil into several
fractions.
These sentences describe the steps in the method for separating the substances into fractions, but the steps
are in the wrong order.
Put a letter in each box to show the correct order. One has been done for you.
(2)
Page 39 of 72
Q19.
Alkanes are saturated hydrocarbons that can be obtained from crude oil.
The general formula of the homologous series of alkanes is C nH2n+2
(a) (i) What is the meaning of the term saturated?
(1)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
(ii) Give the name of a toxic gas that may be produced by the incomplete combustion of octane.
(1)
.............................................................................................................................................
Page 40 of 72
(c) Dodecane (C12H26) is another alkane. When heated and passed over a suitable catalyst, it decomposes to
form octane and one other hydrocarbon.
(i) State how a catalyst increases the rate of this decomposition.
(1)
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
Page 41 of 72
Mark Scheme
Q1.
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Q2.
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Q3.
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Q4.
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Q5.
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Q6.
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Q7.
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Q8.
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Q9.
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Q10.
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Q11.
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Q12.
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(Total for question = 12 marks)
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Q13.
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Q14.
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Q15.
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Q16.
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(Total for question = 9 marks)
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Q17.
Q18.
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Q19.
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