CHAPTER 11: ALKANE CHAPTER 12: ALKENE & ALKYNE

1. Write IUPAC Name of the alkane: 1. The IUPAC name of CH3=CHCH3 is 1, 2

dimethylethene?
- False
2, 2-dimethylpropane 2. Which of the following does not show cis-trans
isomerism?
2. Constitutional isomers have the same - 1-hexane
molecular formulas and same connectivity of 3. Ethylene and acetylene are constitutional
their atoms? isomers?
- False - False
3. Which of the following is not constitutional 4. What reagent and/or catalyst are necessary to
isomer? bring about the conversion?

4. Boiling point among alkenes with unbranched Br2

chains increase as the number of carbon in the 5. Benzene does not undergo addition reactions
chains increases: that are characteristic of alkanes.
- True - True
5. Give the IUPAC Name for all possible 6. Aromatic compounds were so named because
monochlorination products that might be many of them have pleasant odor.
formed in the reaction: cl -> heat - True
7. Alkenes and alkynes are nonpolar molecules.
- True
- Chlorocyclohexane 8. Addition reaction of alkenes involve breaking
6. What is the correct Line-angle formula of one of the bond of the carbon-carbon double
(CH3)2CHCH(CH3)2? bond and formation of two new single bonds in
its place.
- True
9. The following name is incorrect. Give its correct
7. Halogenation of an alkane converts it to a name. 2-ethyl 1-propene
haloalkane. -
- True 10. Give the name of the compound. NO2 Cl
8. What is the molecular formula of: - 1-chloro-4-nitrobenzene

C10H22
9. Cis-and trans-cycloalkanes have same
molecular formula but a different connectivity
of their atoms.
- False
10. Give the IUPAC Name for all possible
monochlorination products that might be
formed in the reaction:
- 2-chlorohexane
CHAPTER 13: ALCOHOL, ETHERS, & THIOLS CHAPTER 15: AMINES

1. In the IUPAC system, the presence of three -OH 1. Hydrogen bonding between 2 amines is
groups is shown by the ending –triol. stronger than that between 2 alcohols?
- True - False
2. Arrange these compounds in order of increasing 2. Tert-butylamine is a 3 amine
boiling point. Use the boiling point values of -42 - False
C, 78 C, 138 C, 198 C. 3. Name the amine salt CH3CH2NH3+Cl-
- dbac - Ethylammonium chloride
3. Write the common name of the following ether: 4. Name the structure:

dicyclopentyl ether
4-methyl-2-pentanamine
4. Select the compound that is more soluble in
5. Metformin was introduced into clinical practice
water:
in the United States in 1995 for the treatment
- CH3OH
of type 2 diabetes. Complete the following for
5. Write the IUPAC Name of the following
metformin: which nitrogen is the most likely
compound:
site of protonation?
- 4
1-pentanol
6. Complete the equation for the following acid-
6. Classify the following alcohol:
base reaction:

Tertiary
7. The functional group of a thiol is the –SH same – NH3+Cl-
(sulfhydryl) group. 7. Aqueous solutions of amines are basic
- True - True
8. The two most important reaction alcohols are 8. Select the stronger base:
their acid-catalyzed dehydration to give alkenes - N-H
and their oxidation to aldehydes, ketones, and 9. Many tumors of the breast are correlated with
carboxylic acids. estrogen levels in the body. Drugs that interfere
- False with estrogen binding have antitumor activity
9. Ethanol & dimethyl ether are constitutional and may even help prevent tumor occurrence.
isomers? A widely used anti-estrogen drug is tamoxifen.
- False / What are the functional groups present in the
10. The functional group of an alcohol is the –OH compound? Select one or more:
(hydroxyl) group. - Select all – one ether, one amine
- True 10. In the IUPAC system, primary aliphatic amines
are names as alkanamines.
- True
CHAPTER 16: ALDEHYDES & KETONES CHAPTER 17: CARBOXYLIC ACID

1. Write the corrent IUPAC name for the intended 1. Write the IUPAC name for the carboxylic acid:
compound 3-butanone.
- 2-butanone
2. Pentane, 1-butanol and butanal all have 2-hydroxybutanedioic acid
approximately the same molecular weight but 2. Carboxylic acids are weak acids, compared to
different boiling points. Arrange them in order mineral acids such as HCl, H2O4, and HNO3?
of increasing boiling points. (1) Pentene, (2) 1- - True
butanol, (3) butanal. 3. From what carboxylic acid and alcohol is ester
- 1, 3, 2 derived?
3. Give the IUPAC name for the principal organic - Acetic acid
product formed by treating 2-butanone with - 1, 4 - cyclohexanediol
H2/ transition metal catalyst. 4. Arrange these compounds in order of increasing
- 2-butanol acidity: (1) benzoic acid, (2) benzyl alcohol, (3)
4. Give the IUPAC name for the principal organic phenol.
compound formed when butanal is treated - 2, 3, 1
with K2CR2O7/ H2SO4+. 5. The structure below is a major component of
- Butanoic acid kidney stones. Give the IUPAC Name:
5. Which compound contain carbonyl group:
- Select all
6. Aldehydes and ketones are polar compounds?
Calcium oxalate
- True
6. Carboxylic acids are polar compounds?
7. Name the aldehyde:
- True
7. The functional groups of a carboxyl held are a
carbonyl group bonded to a hydroxyl group.
formaldehyde
- True
8. (CHSCH2CH2)2C=O name?
8. Fatty acids are long-chain carboxyl acids, with
- 4-heptanone
most consisting of bet. 12-20 carbons in an
9. Which of these compounds undergo keto-enol
unbranched chain.
tautomerism?
- True
- Select all
9. Propanoic acid and methyl acetate are
10. The one aldehyde and the one ketone with a
constitutional isomers, and both are liquids at
molecular formula of C3H6O are the
room temperature. One of these compounds
constitutional isomers.
has a boiling point of 14 C, the other has a
- True
boiling point of 57 C. Which compound has the
boiling point of 141 C.

10. Complete the equation for this acid-base

reaction.

- CH3 + H2O
CHAPTER 18: CARBOXYLIC ANHYDRIDES, ESTERS,
AMIDES

1. Give the IUPAC Name:

- Ethyl-3-hydroxybutaneoate
2. Which of the following is the structural formula
of monoethyl esters of phosphoric acid?

-
3. Complete equations for this reaction:

-
4. IUPAC Name:

- Dimethyl carbonate
5. What product forms when benzamide,
C6H5CONH2, is treated with H20, NaOH heat?

-
6. Phenobarbital is a long-acting sedative,
hypnotic, and anticonvulsant. How many amide
groups are present in the compound?
- 4
7. Amide bonds link monomer units in nylon-66
and Kevlar polymers?
- True
8. Ester bonds link monomer units in Dacron and
mylar polyesters?
- True
9. Give the IUPAC Name:

- P-nitrobenzamide
10. Give the IUPAC Name:

- Butanoic anhydride
CHAPTER 19: CARBOHYDRATES CHAPTER 20: LIPIDS

1. Which of the following compounds are enantiomers? 1. The characteristic that all lipids have in common is…
- C and D - Do not dissolve in water
2. Identify the sugar: 2. Saturated fats have... select one or more
- a-D-Galactose - Straight structure, single bonds, solidity at room
3. Which of the following statement is not correct. temperature
- A tetrose is a sugar with a three-carbon backbone. 3. Name the structure:
4. Which of the following is an l-sugar? - Triglyceride / glycerol tristearate
4. Monomers of lipids include…
- Glycerol and fatty acids
5. Which type of molecule is shown?
- Polyunsaturated fatty acid
6. Which of the following molecules make up the basic
- structure of a cell membrane?
5. The following statements are correct on disaccharides,
- Phospholipids
except:
7. Lipids are classified by their
- Samples are cellulose and starch
- Structure
6. The major physiological purpose of glycogen is to serve as
a storage molecule for… 8. Palmitic acid and palmitoleic acid both have 16
- glucose carbons. Which molecule would have the lower
7. Which of the following would give a positive Benedict’s melting point and why?
test? - Palmitoleic acid has the lower melting point due
- Glycogen and sucrose to its double bond
8. What is the major form of sugar in a plant? 9. This is a ----. The fatty acid present is a/an ----.
- starch - Spingholipid and oleic
9. Maltose or malt sugar is one of the intermediates in the 10. What are the different examples of lipids?
hydrolysis of starch. - Triglycerides, waxes, steroids, phospholipids
- a-D-glucose & d-D-glucose 11. How do lipids function for cells?
10. What is the major biological source of lactose? - Store energy
- Milk 12. This structure is an example of lipid. This is a ---.
11. They are found in a wide variety of naturally occurring
- Glycerophospholipid
substances and serves as principal energy sources for the
13. Carbon chains are principal features of both
body.
- Carbohydrates carbohydrates and lipids. What is the primary
12. It is a simple carbohydrate composed of two difference between these two types of
monosaccharide. macromolecules?
- Disaccharide - Carbohydrates form ring structures, lipids form
13. Sorbitol is a six-carbon sugar alcohols commonly used as long chains
sugar substitutes because they have fewer calories than 14. What is the simple designation giving the number of
sucrose, indicate the chiral carbons in these molecules. carbons and degree of saturation for the following
- 2, 3, 4, 5 molecule?
14. Draw a Fishcer Projection formula for the compound. - 18:3 9,12, 15
Indicate each of the chiral carbons with an asterisk (*). 15. Which of these are examples of lipids?
- Fats, oils, waxes

-
15. Draw the Haworth projection of B-d galactose.

-
CHAPTER 21: PROTEINS CHAPTRER 22: ENZYMES

1. How many amino acids are there 1. What is structure D?

– 20 - Active site
2. Which of the following amino acids have polar, 2. What is structure A?
neutral side chains? - Substrate
3. Which of following conclusions can be drawn from
–STYCNQ
this graph?
3. The structure of proteins can be changed by
- The optimum pH of the enzyme if 6.6
environmental factors such as temperature of 4. What is the purpose of an enzyme?
pH? - Speed up reactions
– True 5. An enzyme speeds up a reaction by…
4. Which macromolecule is this? - Lowering the activation energy
– Protein 6. A __ blocks the substrate so it can’t attach/
5. What is the monomer of proteins? catalyze.
– Amino acids - Competitive inhibitor
6. Identify the name of following peptide at pH 7. 7. How does an enzymes shape relate to its function?
– tyrosyl-seryl-histidine - The enzyme is shaped specially for certain
7. Amino acids that must be supplied by foods in substrates to perform a specific reaction
8. Where do substrates bind on an enzyme?
the diet.
- Active site
– Essential amino acids
9. Enzymes are considered to be…
8. What is a peptide bond? - Protein
– Bond that holds two amino acids together 10. What is structure E, F, G?
9. What elements make up amino acids? - Enzyme
– Carbon hydrogen nitrogen oxygen and 11. Enzymes can be affected by…
sometimes sulfur - Temperature, pH, amount of substrate
10. Match the structures with their names. 12. A __ changes the shape of the enzyme so the
– CH2-C—O-NH2 – Asn & benzene – Phe substrate can’t attach/ catalyze.
11. When proteins unfolds, it is? - Non-competitive inhibitor
– denatured 13. Amylase is an enzyme found in saliva that helps
break down starch in your mouth. In this chemical
12. The diagram shows a bond forming between
reaction, starch would be an example of a…
two amino acids. What is the name of this
- Substrate
reaction? 14. The graph shows how enzymes affect reaction in
– Dehydration synthesis cells. Which statement best summarizes the
13. What does an amino acid look like? information shown in the graph?
– It’s the central carbon with four different - Enzyme decrease the activation energy of the
carbon groups attached. reaction.
14. This is one job proteins do not have in the body. 15. Enzymes need certain environmental conditions in
– Strong genetic information order to function properly. What happens when
15. What is a protein? enzymes are heated to a high temperature?
– A polymer composed of many amino acids - They denature
16. Lipase is produced by the pancreas to help digest
fat. Lipase breaks down the fats into fatty acids.
What role does the lipase play in this reaction?
- Enzyme
CHAPTER 23: MOLECULAR GENETICS - The Human Genome Project
22. The two strands in a DNA molecule are held together
1. Mrna (B) is considered the __ strand because it
by?
builds continuously.
- Hydrogen bonds
- Leading strand
23. DNA making RNA is called?
2. Discovered that A and T bond together and C and G
- Transcription
bond together.
24. DNA replication is when?
- Watson and Crick
- DNA makes DNA
3. The five-carbon sugar found in DNA.
25. The long strand of RNA nucleotides that are formed
- Deoxyribose
complementary to one strand of DNA. They also
4. An enzyme that regulates RNA synthesis.
travel from the nucleus to the ribosome to direct the
- RNA polymerase
making of the specific protein.
5. According to base pair rules, guanine always pairs
- mRNA
with...
26. What nitrogenous base does RNA contain that DNA
- Cytosine
does not?
6. RNA is similar to DNA in that…
- Uracil
- it is a polymer of nucleotides.
27. Built the first correct model of DNA
7. One difference between RNA and DNA is…
- Watson and Crick
- RNA is single stranded where DNA is double
stranded.
8. Based on these results whose blood was found in the
blood stain at the crime scene?
- Bob
9. The 4 nitrogen bases in DNA?
- Adenine, thymine, guanine, cytosine
10. Why is DNA important?
- It serves as the blueprint for traits of all living
things.
11. What is made during transition?
- Proteins
12. A codon is to mRNA as an anti-codon is to…
- tRNA
13. What determines the order of amino acids in a
protein?
- DNA
14. A type of RNA that associates with proteins to form
ribosomes in the cytoplasm.
- rRNA ribosomal RNA
15. Nucleotides monomers are made up of a sugar, a
phosphate, and a…
- Nitrogenous base
16. The __ represents the shape of the DNA molecule
- Double helix
17. DNA replication is when…
- DNA makes protein
18. What determines the order of amino acids in a
protein?
- DNA
19. The enzyme that catalyzes the addition of
appropriate nucleotides to the new DNA strand?
- DNA polymerase
20. Coding sequences that are NOT in the final mRNA?
- Okazaki fragments
21. The work down to map out the entire genomic
sequence in humans was called?