INTERNAL TEST

IIT – JEE 2025

PHASE – II
(2014)_PAPER – II
DATE: 09.10.2023
SET-A
Time: 3 hours Maximum Marks: 180

INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 60 questions.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
3. Fill in the boxes provided for Name and Enrolment No.
4. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
5. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format:
7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part
consists of three sections.
8. Section I contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE is correct.
9. Section II contains 3 paragraphs. Each describing theory, experiment, data etc., Six questions
related to three paragraphs with two questions on each paragraph. Each question to a particular
passage should have ONLY ONE correct answer among the four given choices (A), (B), (C) and (D).
10. Section III contains 4 Multiple choice questions. Each question has two lists (List–1: P, Q, R and S;
List–2: 1, 2, 3 and 4). The options for the correct match are provided as (A), (B), (C) and (D) out of
which ONLY ONE is correct.
D. Marking Scheme
11. For each question in Section 1, 2 and 3 you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases,
minus one (–1) mark will be awarded.

Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

ENROLLMENT NO.:

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PH-II-2025-P(II)_PCM-2

SECTION – I: Single Correct Answer Type

The section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. A man is crossing a river flowing with velocity of 5 m/s. He reaches a point directly across at a
distance of 60 m in 5 sec. His velocity in still water should be

(A) 12 m/s (B) 13 m/s (C) 5 m/s (D) 10 m/s

2. Wind is blowing in the north direction at speed of 2 m/s which causes the rain to fall at some angle
with the vertical. With what velocity should a cyclist drive so that the rain appears vertical to him
(A) 2 m/s south (B) 2 m/s north (C) 4 m/s west (D) 4 m/s south
O
3. A block of mass 2 kg slides down on an incline plane of inclination 30 . The coefficient of friction
between block and plane is 0.5. The contact force between block and plank is
(A) 20 N (B) 10 3 N (C) 5 7 N (D) 5 15 N

4. When a conservative force does positive work on a body

(A) the potential energy increases (B) the potential energy decreases
(C) total energy increases (D) total energy decreases

5. A body with mass 2 kg moves in one direction in the presence of a force which is described by the
potential energy graph. If the body is released from rest at x = 2m, then its speed when it crosses
x = 5 m is

–1 –1 –1
(A) zero (B) 1 ms (C) 2 ms (D) 3 ms

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6. The blocks are in equilibrium. The friction force acting on 10 kg block is

(A) 10 N down the plane (B) 40 N up the plane

(C) 10 N up the plane (D) None of these

7. A small block of mass m is projected horizontally with speed u where friction coefficient between block
and plane is given by μ = cx, where x is displacement of the block on plane. Find maximum distance
covered by the block
u u 2u u
(A) (B) (C) (D)
cg 2cg cg 2 cg

8. Two bodies A & B rotate about an axis, such that angle θA (in radians) covered by first body is
proportional to square of time, & θB (in radians) covered by second body varies linearly. At t = 0,
θA = θB = 0. If A completes its first revolution in  sec & B needs 4π sec. to complete half revolution
then; angular velocity A : B at t = 5 sec. are in the ratio
(A) 4 : 1 (B) 20 : 1 (C) 80 : 1 (D) 20 : 4

9. A body of mass 1 kg starts moving from rest at t = 0, in a circular path of radius 8 m. Its kinetic energy
2
varies as a function of time as : K.E. = 2t Joules, where t is in seconds. Then
2
(A) tangential acceleration = 4 m/s (B) power of all forces at t = 2 sec is 8 watt
(C) first round is completed in 2 sec. (D) tangential force at t = 2 sec is 4 Newton.

10. A uniform rod of length L and mass M has been placed on a rough horizontal surface. The horizontal
force F applied on the rod is such that the rod is just in the state of rest. If the coefficient of friction
varies according to the relation μ = Kx where K is a +ve constant. Then the tension at mid point of rod
is

(A) F/2 (B) F/4 (C) F/8 (D) None of these

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PH-II-2025-P(II)_PCM-4

SECTION – II: Paragraph Type

This section contains 3 paragraphs each describing theory, experiment, data etc., Six questions relate to
three paragraphs with two question on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).

Paragraph For Questions 11 & 12

A uniform chain of length 2L is hanging in equilibrium position, if end B is given a slightly downward
displacement the imbalance causes an acceleration. Here pulley is small and smooth & string is
inextensible

11. The acceleration of end B when it has been displaced by distance x, is

x 2x x
(A) g (B) g (C) g (D) g
L L 2
12. The velocity v of the string when it slips out of the pulley (height of pulley from floor > 2L)
gL
(A) (B) 2gL (C) gL (D) none of these
2

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Paragraph For Questions 13 & 14

13. When F = 2N, the frictional force between 5 kg block and ground is
(A) 2N (B) 0 (C) 8 N (D) 10 N

14. When F = 2N, the frictional force between 10 kg block and 5 kg block is
(A) 2N (B)15 N (C) 10 N (D) None of these

Paragraph For Questions 15 & 16

A particle undergoes uniform circular motion. The velocity and angular velocity of the particle at an
 
instant of time is v  3iˆ  4ˆj m/s and   xiˆ  6ˆj rad/sec

15. The value of x in rad/s is

(A) 8 (B) –8 (C) 6 (D) can't be calculated

16. The radius of circle in metres is

(A) 1/2 m (B) 1 m (C) 2 m (D) can't be calculated

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SECTION – III: (Matching List Type)

This section contains 4 questions, each having two matching lists. Choices for the correct combination of
elements from List–I and List–II are given as option (A), (B), (C) and (D) out of which ONLY ONE is correct.

17. Each situation in column – I gives graph of a particle moving in circular path. The variables ,  and t
represent angular speed (at any time t) , angular displacement (in time t) and time respectively.
Column – II gives certain resulting interpretation. Match the graphs in column–I with statements in
column–II

Column – I Column – II

(P) (1) Angular acceleration of particle is uniform

(Q) (2) Angular acceleration of particle is non-uniform

(R) (3) Angular acceleration of particle is directly proportional to t.

(S) (4) Angular acceleration of particle is directly proportional to 

Code:
P Q R S
(A) 2 1 1 3
(B) 2, 1 1 2 3
(C) 2, 4 1 1 2, 3
(D) 2, 3 2 1 2, 4

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18. A ball is thrown vertically upward in the air by a passenger (relative to himself) from a train that is
 
moving as given in column–I v ball  v escape . Correctly match the situation as described in the
column I, moving as given in column–II

Column – I Column – II
Train moving with constant acceleration on a slope then
(P) (1) Straight line
path of the ball as seen by the passenger.
Train moving with constant acceleration on a slope then
(Q) (2) Parabolic
path of the ball as seen by a stationary observer outside.
Train moving with constant acceleration on horizontal ground
(R) (3) Elliptical
then the path on the ball as seen by the passenger
Train moving with constant acceleration on horizontal ground
(S) (4) hyperbolic
then the path of the ball as seen by a stationary observer outside

Code:
P Q R S
(A) 2 2 2 2
(B) 1 2 3 2
(C) 1 3 1 4
(D) 4 1 3 2
2
19. In the given figure find the accelerations of blocks A and B for the following cases (g = 10 m/s )

Column – I Column – II
(P) 1  0 and 2  0  1 (1) a A  aB  9  5m / s2
(Q)  2  0 and 1  0  1 (2) a A  9m / s2 ,aB  10m / s2
(R) 1  0  1 and 2  1 0 (3) a A  aB  g  10m / s2
(S) 1  1 0 and 2  0  1 (4) a A  1,aB  9ms / 2

Code:
P Q R S
(A) 2 3 1 4
(B) 3 2 1 4
(C) 1 2 3 4
(D) 4 3 2 1

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20. A block A of mass m kg lies on block B of mass m kg. B in turn lies on smooth horizontal plane. The
coefficient of friction between A and B is . Both the blocks are initially at rest. A horizontal force F is
applied to lower block B at t = 0 such that there is relative motion between A and B. In the duration
from t = 0 second till the lower block B undergoes a displacement of magnitude L, match the
statements in column-I with results in column-II. Column-I

Column – I Column – II
(P) Work done by friction force on block A is (1) Positive

(Q) Work done by friction force on block B is (2) Negative

(R) Work done by friction on block A plus (3) less than  mgL in magnitude
(S) Work done by force F on block B is (4) Equal to  mgL in magnitude

Code:
P Q R S
(A) 1, 3 2, 4 2, 1 1
(B) 2, 3 1, 4 3, 4 2
(C) 1, 2 2, 3 2, 1 4
(D) 1, 3 2, 4 2, 3 1

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SECTION – I: Single Correct Answer Type

The section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

21. For the reaction

11
2FeS2  O 2 
 Fe 2 O3  4SO 2
2
What will be the equivalent weight of FeS2, if the molecular weight of FeS2 is M?
M M
(A) (B) M (C) (D) Can’t be calculated
8 11

22. The chloride of a metal contains 71 % chlorine by weight and the vapour density of it is 50. The
atomic weight of the metal will be:
(A) 29 (B) 58 (C) 35.5 (D) 71

23. What is the concentration of H  in a solution that is prepared by mixing 50.0 mL of 0.50 M HCl
with 200.0 mL of 0.25 M HCl ?
(A) 0.30 M (B) 0.35 M (C) 0.40 M (D) 0.45 M

24. Which of the following possess two lone pair of electrons on the central atom and square planar in
shape?
(I) SF4 (II) XeO4 (III) XeF4 (IV) ICl4
(A) I, III (B) II, IV (C) III, IV (D) All of these

25. Number of hybrid orbitals present in all atoms of benzene (C6H6) is x and number of unhybrid
orbitals in all atoms of benzene is y then x  y is ________
(A) 3 (B) 6 (C) 8 (D) 9

26. Based on VSEPR theory, the number of 90 Cl  P  Cl angles in PCl5 is X and the number of
120 Cl  P  Cl angles in PCl5 is Y then X  Y is ________ .
(A) 2 (B) 3 (C) 6 (D) 0

27. Among the following the molecule with the highest dipole moment is
(A) CH3 Cl (B) CH2Cl2 (C) CHCl3 (D) CCl4

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28. The equivalent weight of H2SO4 in the following reaction is

Na2 Cr2O7  3SO2  H2 SO 4  3Na2 SO 4  Cr2  SO 4 3  H2O
98 98 98 98
(A) (B) (C) (D)
1 2 6 8

29. 20 ml of a 20%  w / w  solution of density 1.1 gm/ml is diluted until its strength becomes 4% (w/w),
Then the mass of water to be added is
(A) 68g (B) 78g (C) 88g (D) 48g

30. Two ice cubes are pressed over each other and unite to form one cube. Which force is responsible for
holding them together.
(A) Vander waal’s forces (B) Covalent attraction
(C) Dipole–Dipole attraction (D) Ion–dipole attraction

SECTION – II: Paragraph Type

This section contains 3 paragraphs each describing theory, experiment, data etc., Six questions relate to
three paragraphs with two question on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).

Paragraph For Questions 31 & 32

The number of moles of solute present in 1 litre of solution is known as molarity.

31. The weight of solute present in 200 ml of 0.1 M H 2 SO 4

(A) 2.45 g (B) 4.9 g (C) 1.96 g (D) 3.92 g

32. The number of moles present in 2 litre of 0.5 M NaOH is

(A) 2 (B) 1 (C) 0.1 (D) 0.5

Paragraph For Questions 33 & 34

KMnO4 can be decolourised by SO2 in acidic medium as

2K MnO 4  5SO2  2H2 O  K 2SO4  2MnSO4  2H2 SO 4

33. Which is oxidizing agent?

(A) KMnO4 (B) SO2 (C) H2O (D) K2SO4

34. Which ion is spectator ion?

(C) MnO4
+ 2 2+
(A) K (B) SO4 (D) Mn

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Paragraph For Questions 35 & 36

VSEPR theory predicts the shapes of the molecules. The other methods of determining the shapes of the
molecules are by hybridizations technique and dipole moment of the molecules.

If Q represents the total number of hybrid orbitals, P represents total number of valence electrons, then Q = P
–3
(number of atoms surrounding the central atom excluding H–atom)

The number of bond pairs (B) = number of atoms surrounding the central atom)
Then the total number of lone pairs of electrons n = Q – B
The VSEPR notations of a molecule can be written as AXbEn
Where A = Central atom; Xb = Number of bond pairs; En = Number of lone pairs

35. Hence a molecule of BrF3 can be represented as

(A) AXE (B) AX3E2 (C) AX2E3 (D) AX4E2

36. The increasing order of dipole moments for the following three compounds SO2 , H2O, CO2
 X Y  Z
(A) Z < X < Y (B) Z < Y < X (C) Y < Z < X (D) Z < Y ~ X

SECTION – III: (Matching List Type)

This section contains 4 questions, each having two matching lists. Choices for the correct combination of
elements from List–I and List–II are given as option (A), (B), (C) and (D) out of which ONLY ONE is correct.

37.
Column – I Column – II
(Molecule) (Bond angle)
0
(P) H2O (1) 120
0
(Q) OCl2 (2) 107
0
(R) BCl3 (3) 104.5
0
(S) NH3 (4) 111
Code :
P Q R S
(A) 3 4 1 2
(B) 1 2 3 4
(C) 3 4 1 1
(D) 4 3 1 2

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38. Match the following:

Column – I Column – II
(P) 52g of He (1) 13 atoms
(Q) 52 moles of He (2) 44.8 L
23
(R) 34 g of NH3 (3) 313.196 x 10 atoms
23
(S) 52 u of He (4) 78.299 x 10 atoms
Code :
P Q R S
(A) 4 1 2 3
(B) 1 4 2 3
(C) 3 2 4 1
(D) 4 3 2 1

39.
Column – I Column – II
(P) SF4 (1) L.P. present in axial position
(Q) PCl3 F2 (2) L.P. present in equatorial position
(R) XeF4 (3) F atoms are present in axial position
(S) XeF5 (4)  (dipole moment) = 0
(5) Non-polar
Code :
P Q R S
(A) 1, 3 4, 5 1,2,3 2,3
(B) 2,3 3,4,5 1,4,5 1,4,5
(C) 1,2 3,4,5 1,4,5 2,3,4
(D) 3,4 3,4,5 3,4,5 3,4,5

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40. Match column I compounds (underlined) with their equivalent weights (E) in column (II)
Column – I Column – II
Na2S2O3  4Cl2  5H2O  Na2SO4  H2SO4  8HCl 3M
(P) (1) E
4
3M
(Q) I2  I  IO3 (2) E
5
M
(R) P4  OH  H2O  H2PO 2  PH3 (3) E
3
H3PO2  PH3  H3PO3 M
(S) (4) E
8
Code :
P Q R S
(A) 1 2 3 4
(B) 2 3 1 4
(C) 4 2 3 1
(D) 4 3 2 1

SECTION – I: Single Correct Answer Type

The section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

41. If A and B be symmetric matrices of the same order, then AB  BA will be a

(A) Symmetric matrix (B) Skew symmetric matrix
(C) Null matrix (D) None of these

42. Which one of the following statements is true

(A) Non- singular square matrix does not have a unique inverse
(B) Determinant of a non-singular matrix is zero
(C) If A   A, then A is a square matrix
(D) If | A |  0 , then | A.adj A |  | A |(n1) , where A  [aij ]nn

3 2 1 3
43. If A    , then (A ) is equal to
 0 1
1  1 26  1  1 26  1  1 26  1  1 26 
(A)   (B)   (C)   (D)  
27  0 27  27  0 27  27  0 27  27  0 27 

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44. If the system of equations ax  y  z  0 , x  by  z  0 and x  y  cz  0 , where a,b,c  1, has a non

1 1 1
trivial solution, then the value of   is
1 a 1 b 1 c
(A) – 1 (B) 0 (C) 1 (D) None of these

sin x cos x cos x

 
45. The number of distinct real roots of cos x sin x cos x = 0 in the interval   x  is
4 4
cos x cos x sin x
(A) 0 (B) 2 (C) 1 (D) 3

x x 2 2
46. The equation 2 sin .cos2 x  2sin .sin2 x = cos x – sin x has a root for which
2 2
 1
(A) sin 2x = 1 (B) sin 2x = –1 (C) cos x = (D) cos 2x = 
2 2

47. The smallest positive root of the equation sin(1  x)  cos x is

1 7 1 5 1 3
(A)  (B)  (C)  (D) none of these
2 4 2 4 2 4

  
48. The largest interval lying in   ,  for which the function
 2 2
 x 
f  x   4 x  cos1   1  log  cos x  is defined, is
2

2 
       
(A) 0, (B)   ,  (C)   ,  (D) 0, 
 2 2   4 2  2
1
49. If f(x) = 4  x 2  , then the domain of f(x) is
sin x  sin x
(A) [2, 0] (B) (0, 2] (C) [2, 2} (D) [2, 0)

 2 x 
50. If f(x) = sec 1  , then the domain of f(x) is
 4 
 
(A) [2, 2] (B) [6, 6] (C) (, 6] U [6, ) (D) [6, 2] U [2, 6]

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 PH-II-2025-P(II)_PCM-15

SECTION – II: Paragraph Type

This section contains 3 paragraphs each describing theory, experiment, data etc., Six questions relate to
three paragraphs with two question on each paragraph. Each question of a paragraph has only one correct
answer among the four choices (A), (B), (C) and (D).

Paragraph for Questions 51 & 52

 1 3   2 3 2 4
   
Let A and B are two matrices of same order 3  3, where A =  2 4 8 , B   3 2 5 
 3 5 10  2 1 4
   
51. If A is singular matrix, then tr(A + B) is equal to
(A) 6 (B) 12 (C) 24 (D) None of these

52. If matrix 2A + 3B is singular, then the value of 2 is

(A) 11 (B) 13 (C) 17 (D) None of these
Paragraph for Questions 53 & 54
2
 is a root of the equation (2 sin x – cos x)(1 + cos x) = sin x  is root of the equation
2
3 cos x – 10 cos x + 3 = 0 and  is root of the equation 1 – sin 2x = cos x – sin x, 0  , ,   /2.

53. cos  + cos  + cos  can be equal to

3 6 2 26 3 3 8 3 3 2
(A) (B) (C) (D) None of these
6 2 6 6

54. sin ( – ) is equal to

1 2 6
(A) 1 (B) 0 (C) (D) None of these
6

Paragraph for Questions 55 & 56

Two adjacent sides of a parallelogram OABC are 4x + 5y = 0 and 7x + 2y = 0, where O is the origin.

55. If an equation to the diagonal AC is 11x + 7y – 9 = 0, then equation of the diagonal OB is

(A) x + y = 0 (B) 7x – 11y = 0 (C) x – y = 0 (D) None of these

56. Midpoints of AC is
(A) (0, 0) (B) (1/2, 1/2) (C) (5/6, –4/6) (D) None of these

Space for rough work

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PH-II-2025-P(II)_PCM-16

SECTION – III: (Matching List Type)

This section contains 4 questions, each having two matching lists. Choices for the correct combination of
elements from List–I and List–II are given as option (A), (B), (C) and (D) out of which ONLY ONE is correct.

57. Match the following

Column – I Column – II
2 1
(P) (2 sin x – cos x)(1 + cos x) = sin x (1) sin x =
2
(Q) 1 + sin 2x = cos x + sin x (2) tan x = –1
4 6 2
(R) 4x + x + sin 5x = 0 (3) x=0
1 19 
(S) tan x = (4) x=
3 6
Code :
P Q R S
(A) 1 2 3 4
(B) 1 3 2 4
(C) 1 2 4 3
(D) 1 4 2 3

58. Value of . Which satisfies the equation. (n  I)

Column – I Column – II
(P) 1  cos2   1  sin2  is / are (1) (2n + 1)

(Q) 1  sin2   2 (2) 2n 
4

(R) tan  = cot  (3) n +
4

(S) sec  tan  + 2 = sec + 2 tan  (4) n –
4

(5) n 
2
Code :
P Q R S
(A) 3, 4 5 3, 4 2, 3
(B) 3, 4 5 3 2, 4
(C) 3 5 4 1
(D) 4 5 3 4

Space for rough work

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 PH-II-2025-P(II)_PCM-17

59.
Column – I Column – II
4 4 2 2/3 2 2/3
The locus of the point (acos t, bsin t) is (x y) + (xy ) = 1
(P) (1)
2 2 2 2
The locus of the point (tant+ sint, tant– x /a – y /b = 1
(Q) sint) is (2)

The locus of the point (asect, btant) is x/a  y/b 1

(R) (3)

The locus of the point (cosect–sint, sect– x /a  y /b  1

(S) cost) is (4)
2 2
(x – y ) = 16xy

Code :
P Q R S
(A) 4 5 2 1
(B) 4 2 1 5
(C) 2 5 1 4
(D) 5 4 2 1

60. To remove the first degree terms in the following equations origin should be shifted to the another
point then calculate the new origins for

Column – I Column – II
2 2
x – y + 2x + 4y = 0 (5, –7)
(P) (1)
2 2
4x + 9y – 8x + 36y + 4=0 (1, –2)
(Q) (2)
2 2
x + 3y – 2x + 12y + 1= 0 (–1, 2)
(R) (3)
2 2
2(x –5) + 3(y + 7) = 10 (–1, – 2)
(S) (4)
(–5, 7)
(5)
Code :
P Q R S
(A) 3 2 2 1
(B) 3 2 4 1
(C) 3 4 2 1
(D) 3 1 4 2

Space for rough work

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