화공입문설계[CHE1100]_문제풀이 Chapter 4,5

(Creative Engineering Design)

- Chater 4 물리량 표현
- Chater 5 물질수지
익힘문제 4.7
Using water and air as examples, what is an approximate ratio of the
densities of liquids to gases?

익힘문제 4.8
Two compounds, one with a high molecular weight and one
with a low molecular weight, are flowing at the same mass flow
rate. Which has the greater molar flow rate?
익힘문제 4.9
Two compounds, one with a high density and one with a
low density, are flowing at the same mass flow rate. Which has
the greater volumetric flow rate?

익힘문제 4.10
Two compounds, one with a high molecular weight and
one with a low molecular weight, each comprise 50 mole% of
the same mixture. Which has the greater mass fraction in the
mixture?
익힘문제 4.11
Solution 1 has a greater density than does solution 2, and
solution 1 also has a greater concentration of species A than
does solution 2. For these solutions, answer each of the following
questions and support your answer:

a. Which will occupy greater volume: 1 kg of solution 1,

or 1 kg of solution 2?

b. Which will contain more molecules of species A: 1 gallon

of solution 1, or 1 gallon of solution 2?

c. If the two solutions flow with equal volumetric flow

rate, which stream will have

i. the greater mass flow rate for the entire stream?

ii. the greater molar flow rate of species A?
iii. the greater mass flow rate of species A?
익힘문제 4.12
A solution of salt dissolved in water is diluted with additional
water. With each of the following variables, indicate
whether the dilution process will cause the value of the variable
to increase, decrease, or stay the same. Support your answer.

익힘문제 4.13
A solution of NaOH in water flows in a stream, and the
mass flow rate of the stream is suddenly increased. For each of
the following properties of the stream, indicate whether the increase
in flow rate will cause the property to increase, decrease,
or remain the same. In each case, explain your answer.
연습문제 4.1
Perform the following conversions by determining the equivalent
value of the given number in the new units indicated:
연습문제 4.2
Water at 4◦C has a density of 1000 kg/m3. What is the equivalent value in units of

연습문제 4.3
A gas mixture has the following percentages by mass:
N2: 70%
O2: 14%
CO: 4%
CO2: 12%
What are the mole percentages of the gases in the mixture?
연습문제 4.4
A 6M sulfuric acid solution (H2SO4 in water) is flowing into a tank at the rate of 100
liters/min (also can be written 100 L/min). The density of the solution is 1.34 g/cm3.
Determine the value of the items requested below (show your work). For parts (b) - (d),
first write out the equation using symbols for the appropriate variables, then
algebraically solve for the unknown variables, and finally substitute in the numerical
values and calculate the values for the unknown variables.
연습문제 4.5
A stream consisting of two organic chemicals: (1) benzene (C6H6) and (2) toluene (C7H8),
enters a separation column. The total mass flow rate of the stream is 10,000 lbm/hr. The
mass percent of benzene in the stream is 40%. Determine the following for the stream:
연습문제 4.6
The exhaust gas coming from a coal-burning furnace (flue gas) usually contains sulfur in
the form of SO2, and when the gas is discharged into the atmosphere (which sometimes
happens), the SO2 can eventually react with oxygen and water to form sulfuric acid
(H2SO4), hence, acid rain. The reaction is SO2 +(1/2)O2 + H2O → H2SO4
The air around an old power plant has the following average composition:

H2SO4: 0.1 mole%

O2: 20.2 mole%
N2: 77.9 mole%
H2O: 1.8 mole%

What is the number of grams of sulfuric acid per ton (2000 lbm) of this air? (Note: the
molecular weight of this humid and polluted air cannot simply be assumed to be 29.)
연습문제 4.7
The following variables are given in the following units:

x: g/s
y: cm
z: g/cm s
a: g/s
b: cm

In terms of these variables, which of the following obey the laws

of dimensional consistency? (Support your answers)